1-BROMO-3-NITROBENZENE NEW INTERMEDIATE BY DOW

Nov 5, 2010 - Publication Date: May 11, 1953. Copyright © 1953 AMERICAN CHEMICAL SOCIETY. ACS Chem. Eng. News Archives. Cite this:Chem...
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1-BROMO-3-NITROBENZENE NEW INTERMEDIATE BY DOW Now available in pilot plant quantities, this product of DOW research is the key to a number of reactions

properties: Br

Boilmg Range Freezing Point

>

52.CFC»

Solubility (approxiamate grams)

pet100gramssolvent$i 25 w Acetone

.

.......

Benzene-...

232 178

Carbon Tetrachloride

50

Ethyl E t h e r . . . . . . . . . . . . .

....96

n--Heptane.......

...................

N02

11

Methanol.................................................23

Water

10

MW=202.0

THE DOW CHEMICAL COMPANY Dept. TS 3-4, Midland, Michigan Please send an experimental sample of 1 -bromo-3-nitrobenzene.

Name

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Bromination of l-bromo-3-nitrobenzene yields l,4-dibromo-2nitrobenzene while nitration yields 4-bromo-l,2-dinitrobenzene.

Title Company Address City

l-Bromo-3-nitrobenzene exhibits the chemical properties of both an aromatic nitro compound and an aromatic halide . . . two groups with meta positioning that provide an interesting basis for a number of chemical reactions. A variety of reducing agents may be employed to produce respectively m-bromoaniline, 2-bromo-4-aminophenol, 3,3-dibromoazobenzene, or cyclohexylamine.

State-

An experimental sample of l-bromo-3-nitrobenzene is available, at no charge, for your evaluation as a chemical intermediate. Write to THE DOW CHEMICAL COMPANY, Midland, Michigan, Dept. TS 3-4.

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