18th ACS Northeast Regional Meeting - C&EN Global Enterprise (ACS

Jun 27, 1988 - The program includes symposia on Nonlinear Dynamics, High-Yield Pulping, Biological Applications of Mass Spectrometry, and Food Protein...
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18th ACS Northeast Regional Meeting The ACS 18th Northeast Regional Meeting will be held at the University of Maine, Orono, July 31-Aug. 3. About 185 pa­ pers will be presented. The program includes symposia on Nonlinear Dynamics, High-Yield Pulping, Biological Appli­ cations of Mass Spectrometry, and Food Proteins, as well as a special program for high school chemistry teachers. Special events include a white-water rafting trip on the West Branch of the Penobscot River, a lobster feast, and a bus tour of Acadia National Park. Places for the rafting trip must be reserved in advance; see registration form on page 52. No children under 12 are permitted on the rafting trip. The deadline for advance registration for NERM-18 is July 14. Mail the completed registration form to: NERM-18, Con­ ferences and Institutes Division, University of Maine, Orono, Me. 04469. Registration materials will not be mailed out, but will be available at the registration desk. On-site registration facilities will be located in the Hilltop Dormitory complex. Abstracts of the papers will be available at the meeting, and will be mailed to those who register but do not attend. Orders for abstracts only should be directed to the general chairman, Raymond Fort, Department of Chemistry, University of Maine, Orono, Me. 04469. For these abstracts, mailed after the meeting, the cost is $12.50. Requests for a full refund will be honored up to July 29. After that date 80% of the registration fee and 90% of meal and housing charges will be refunded. All housing arranged by NERM-18 is in on-campus dormi­ tories—modern, clean, but somewhat cramped. Reservations must be paid in advance. Rooms are available both before and after the meeting. Two local motels, Comfort Inn and Bangor Motor Inn, have agreed to provide special rates for NERM registrants (mention NERM and the University when mak­

AGRICULTURE & FOOD CHEMISTRY

2:10—β. NMR Imaging of Polysaccharides. J. Lelievre 3:00—7. NMR Study of Corn-Soy Protein Interactions. I. Baianu. 3:40—8. Overview of Theoretical and Prac­ tical Aspects of Food Polymer Science H. Levlne

Symposium on Food Polymers Peter Given, Program

MONDAY

Chair

MORNING

Aubert Hall Peter Given,

Presiding

9:00—1. Polymeric Properties of Polyvinyl Acetate (PVAC)—a Masticatory Food Polymer R. D'Amelia 9:40—2. X-Ray Study of Carageenan and Xanthan Gums. R. P. Millane 10:30—3. Hydration of Solid Lysozyme. R. B. Leslie 11:10—4. Relationship Between StructureDynamics of Proteins and Function. M. Le Meste MONDAY

AFTERNOON

Aubert Hall Harry Levi ne,

Presiding

1:30—5. Starch Functionality in Foods: a Physical/Chemical Viewpoint. H. Zoebel

50

June 27, 1988 C&EN

TUESDAY MORNING Aubert Hall

ing reservations). See the reservation form for location and rates. A list of additional motels is available by writing the general chairman. A real Down East lobster feast will be the feature of the banquet on Tuesday, Aug. 2. On-campus meals served cafete­ ria style may be reserved by using the reservation form or are available individually at serving time. The lobster banquet is an exception and must be reserved no later than noon, Aug. 1. Meal package A includes all meals from Monday breakfast and lobster feast: $41.80 per person. Package Β provides a regular meal instead of lobster: $31.55 per person. Individual breakfasts, lunches, and dinners may be reserved or pur­ chased on site for $3.50, $4.15, and $5.00, respectively. A list of local restaurants will be available in the registration area, or may be obtained by mail from the general chairman. Orono is about 10 miles from Bangor International Airport, and is served by Delta, United, and Eastern Express airlines. Most flights connect through Boston. National, Budget, Hertz, Avis, and Dollar car rentals are available at the airport. Taxis meet all flights (about $18 to Orono) and a NERM-18 van will meet all flights. By car, Orono is 250 miles northeast of Boston via interstate 1-95. The exhibition will be held in the Hilltop Commons. As of June 1, 12 exhibitors, including publishers and scientific equipment manufacturers, have agreed to provide displays. Admission to the exhibition room is by conference badge. The mixer will be Monday evening in the Hilltop Com­ plex. Coffee and other refreshments will be available in that area throughout the meeting. For more information, contact the general chairman, Raymond C. Fort Jr., Department of Chemistry, University of Maine, Orono, Me. 04469, phone (207)581-1169.

MONDAY AFTERNOON Bennet Hall

ANALYTICAL

Steven Carr, Presiding Gary A. Mabbott, Program

Chair

Symposium on Biomedical Applications of Mass Spectrometry Robert J. Anderegg, Steven Carr, Program Chairs

Michael Otterburn, Presiding 9:00—9. Chitin/Chitosan Functionality. M. Otterburn 9:40—10. Physical Chemical Properties of Pectin. M. S. B. Allvar 10:30—11. Physical-Chemical Behavior of Corn Meal in Twin Screw Extrusion Cooking. G. W. Halek

TUESDAY AFTERNOON Aubert Hall Peter Given, Presiding 1:30—12. Pectin Characterization via Size Exclusion Chromatography. N. Ahmad, J. E. Rollings 2:00—13. Some Food Applications of Powered Cellulose. J. F. Ang 2:30—14. Rheology of Gelatinized Corn Starch: Granule Size and Composition Ef­ fects. A. Corona, J. E. Rollings

MONDAY

MORNING

Bennet Hall Robert J. Anderegg,

Presiding

9:00-15. Solving Biopharmaceutical Prob­ lems Using Mass Spectrometry. M. E. Hemling 10:00—16. Mass Spectrometry in Human Cancer Epidemiology. J. S. Wishnok 11:00—17. Use of Enriched Isotope Label­ ing and ICP/MS To Trace Dietary Ele­ ments into Hair. M. Dover 11:20—18. Alkaline Earth Salts as Canoni­ zation Agents in Laser Desorption FTMS. D. E. Bracken, T. J. Nizolek 11:40—19. GC/MS Methodology for the Identification of Oxygen Radical-Induced DNA Base Damage. J. F. Belliveau, A. B. Weitberg, D. M. Corvese, J. van Ept, W. Wan

1:30—20. MS Techniques in Drug Metabo­ lism Studies, L. K. Wong 2:30—21. Structural Information from LC/ MS? J. D. Henion 3:30—22. New Reagents for Peptide Se­ quencing by NICI/MS. R. J. Anderegg 3:50—23. SFC/MS of Glycoconjugates. G. R. Her, D. M. Sheeley, V. N. Reinhold 4:10—24. Use of ICP/MS To Monitor Stable Isotope Abundances in Biological Fluids: Measurement of Chromium in Blood. M. Dever, D. W. Hausler, J. E. Smith 4:30—25. Comparison Between Nonradio­ active 50Cr and Radioactive 51Cr Labels for Determination of Erythrocyte Survival Studies Using ICP/MS. M. Dever, D. W. Hausler, J. E. Smith

TUESDAY MORNING Bennet Hall Clifford Carlin, Presiding 9:00—26. Metal Speciation by Ratio Fluo­ rescence. T. Taylor, Y. Khan, H. H. Patter­ son, C. Cronan 9:30—27. Remote Laser-Induced Fluores­ cence Analysis of Mixtures of Groundwa­ ter Constituents. G. B. Jarvis, J. E. Kenny 10:00—28. Determination of Volatile Amines in Air by On-Line Solid Phase Derivatization with HPLC-UV/FL Detection. C. X. Gao, I. S. Krull

10:30—29. Reversed-Phase High-Performance Liquid Chromatography Estimation of Octanol-Water Partition Coefficients: Chlorobiphenyls and Alkylbenzenes. P. M. Sherblom, R. P. Eganhouse 11:00—30. Solid-Phase Extraction: MultiModal Approaches to Multi-Component Environmental Analysis. P. R. Loconto 11:20—31. Analysis of Pesticide Residues by Immunoassay. R. J. Bushway TUESDAY AFTERNOON Bennett Hall Gary A. Mabbott,

Presiding

1:30—32. Cyclic Voltammetric Study of Two-Electron Transfer Processes in Bis(arene)ruthenium(ll) Systems. D. T. Pierce, W. E. Geiger 2:00—33. Modeling of the Metal Displace­ ment Reactions. T. Hepel 2:30—34. Customized Carbon Composite Electrodes. K. E. Creasy, B. R. Shaw 3:00—35. Differential Gas Chromatographic Mass Spectrometry. A. Gosh, R.J. Anderegg 3:30—36. Nonsize Effects in Aqueous Size Exclusion Chromatography. R. G. Beri, J. E. Rollings WEDNESDAY

MONDAY AFTERNOON Barrows Hall R. Daniel Libby, Presiding 1:30—49. Technetium-99m-Phenylbiguanide Complexes: Preparation and Chro­ matographic Characterization. C. C. Yu, D. E. Tow 1:55—50. Syntheses and Evaluation of Sim­ plified Thio Analogs Related to Bleomy­ cin. T. Lomis, B. McCloskey, B. Cheng, J. F. Suida, R. Shepard 2:20—51. Difluoromethylene Phosphonate Analogs of Guanine Nucleotides as Probes of the ras Oncogene Protein, P21. L. Arabshahi, G. E. Wright 2:45—52. Structural Modification and Deu­ terium Isotope Effects on AzidoalanineInduced Mutagenesis: Insight to Possible Bioactivation Mechanisms. J. B. Mangold, M. R. Mischke, J. M. LaVelle 3:10—53. Peptidyl Derivatives of Amefalone as Potential Antiarrhythmic Agents. M. Mokotoff, M. Zhao, L. K. Wong. Q. Jiang 3:35—54. Mechanism-Based Inhibitors of Pyrimidine De Novo Enzymes. S. Purkayastha, R. P. Panzica 4:00—55. Biological Activity of Mono- and Sesquiterpene Glycoside. M. Miyazawa, M. Sano, H. Kameoka

MORNING TUESDAY

Bennett Hall

9:50—70. Supplemental Choline Amelio­ rates Lithium Carbonate (Li2C03) Diabetes Insipidus. H. Clerk, S. Blau, D. Kanofsky, D. Kambosos, D. Greenwald, E. Seifter 10:15—71. Novel HPLC Phase for Direct Analyses of Drugs in Biological Fluids. T. L. Ascah, B. T. Hunter, D. J. Gisch, B. Feibush, R. Eksteen 10:40—72. Ultrastable Microbubbles for Im­ proved Ultrasonic Medical Imaging. J. S. D'Arrigo 11:05—73. Rapid Immunoturbidimetric Quantification of Apolipoprotein Ε in Nor­ mal and Hypertriglyceridemic Sera. D. M. Barrantes, T. B. Ledue, G. R. Irish, K. Steward 11:30-74. Development of HPLC Analysis for Pharmaceuticals, with Emphasis on Drugs Coming off Patent. T. L. Ascah, B. T. Hunter

CELLULOSE, PAPER & TEXTILE CHEMISTRY Symposium on the Chemistry of High-Yield Pulping

Barbara J. W. Cole, Wayne Robbins, Program Chairs

MORNING

WEDNESDAY MORNING Aubert Hall Robert M. Hawthorne, Presiding 9:00-85. Early Chemical Manufacturing in Maine: 1733-1900. R. M. Hawthorne 9:20—86. Rhetoric Between Chemists and Physicists at the Dawn of Atomic Theory. S. J. Weininger 9:40—87. Sigma Xi In Science, Mathemat­ ics, and Engineering Education. E. J. Poziomek 10:00—88. Classifying Natural Waters that Are Susceptible to Acid Precipitation. K. E. Borst 10:20—89. Study of a Hands-On General Chemistry Acid Base Experiment Using Computer Simulation and Instruction To Enhance Comprehension of Chemical Concepts. Student Perceptions and Com­ prehension. E. J. Miller, J. Abbale 10:40—90. Computer Courses for Chemis­ try Majors. M. Mandrioli 11:00—91. Teaching MRI Using Computer Animation. J. P. Hornak 11:20—92. New Approaches to Teaching and Learning in Introductory Chemistry Courses: Peers Helping Peers. S. D. Mar­ shall, W. E. Adams 11:40—93. Skills for Success in Introduc­ tory Chemistry Courses: Statistical Re­ sults of Supplemental Instruction. W. E. Adams, S. D. Marshall

Barrows Hall Gary A. Mabbott,

Presiding

9:00—37. Reactions of Coal with Oxidizing Agents. H. Beall, B. J. Howard 9:30—38. Initial Batch Sorption Rate Model for Prediction of Organics Removal by Water Treatment Beds. L. A. McCurry, G. A. Wilber, E. M. Moreau, T. W. Fitzpatrick, G. E.Janauer 10:00—39. Borohydride-Enhanced Photodehalogenation of Aroclor 1232, 1242, 1254, and 1260. G. A. Epling, W. M. McVicar, A. Kumar 10:30—40. Chemical Contamination in the Sediments of Several Southern New En­ gland Estuaries. R. J. Pruell 11:00—41. Binding and Removal of Alumi­ num Ions in Waters by an Algal Biomass. J. Sneddon, P. R. Zimnik

BIOLOGICAL & MEDICINAL CHEMISTRY Carol B. Libby, Program Chair

MONDAY MORNING Barrows Hall Carol B. Libby, Presiding 9:00—42. Supplemental Vitamin A Reduces Intestinal Epithelial Damage Due to Gam­ ma Irradiation. E. Seifter, J. Mendecki, E. Friedenthal, L. Davis, S. Blau 9:25—43. Comparative Study of the Effects of Quinine on the Calcium Dependent Po­ tassium Channels of the Human Erythro­ cyte. W. D. Hobey, D. W. Hanlon, M. P. Vincent 9:50—44. Synthesis and Anticancer Effects on Chemically Reactive Metabolites of Clomiphene. P. C. Ruenitz, Ν. Τ. Nanavati, R. F. Arrendale 10:15—45. β-Carotene: a Hormone or Hor­ mone-Modifier in Chickens? E. Seifter, J. Padawer, D. Greenwald, L. Sharzer 10:40—46. Specific Nuclear Uptake of Intracellularly Produced Estrogen by Ovari­ an Cells. A. J. Wolfson, J. S. Andrews 11:05—47. Effect of Charcoal on Dissocia­ tion Kinetics of Nuclear and Cytosolic Ste­ roid-Receptor Complexes. M. R. Hutchin­ son, A. J. Wolfson 11:30—48. [3H]Dexamethasone Binding to Plasma Membrane Enriched Fractions from Liver of Nonadrenalectomized Rats. C. A. Hrycyna, J. M. O'Brien

Symposium on Biologically Important Re­ active Intermediates R. Daniel Libby, Organizer,

Presiding

9:00—56. Oxalyl Thiolesters: Novel Inter­ mediates in Biological Systems. G. A. Hamilton 10:00—57. Methyl Mercapturate Episulfonium Ion: a Model Reactive Metabolite of Dihaloethanes. G. S. Amato, J. G. Henkel 10:30—58. Reactions of Phenothiazine Rad­ icals at Solid Electrodes. M. Hepel 11:00—59. Photofragmentation of Phototoxic Phenothiazine-Containing Drugs. G. A. Epling, A. Kumar 11:30—60. Vitamin D Precursors as Ultravi­ olet Sreens: a Hypothesis. E. Seifter, J Mendecki, N. Jacobson, J. Weinzweig

TUESDAY AFTERNOON Barrows Hall Adèle J. Wolfson, Presiding 1:30—61. Inactivation of Arylsulfotransferase by A/-Hydroxy-2-Acetylaminofluorene. B. L. K. Mangold, D. J. McCann, J. B. Mangold 1:55—62. Probes for the Mechanisms of Peroxidases: Chloride Effects in Halogenation and Nonhalogenation Reactions of Chloroperoxidases. T. C. White, J. T. Emerson, N. S. Rotberg, A. L. Shedd, W. E. Busineau, R. D. Libby 2:20—63. Sulfoxidase Activity of Hemoglobin. B. H. Magee, M. A. Marietta 2:45—64. Polysaccharide Branching Characteristics and their Effects on Kinetics of «-Amylase Catalyzed Polysaccharide Depolymerization. J. T. Park, J. E. Rollings 3:10—65. Structural Influences of the Retinal Chromophore on the Protein Bacteriorhodopsin. N. A. Swords, B. A Wallace 3:35—66. pH Dependence of the Conformation of δ-Endotoxin Is Correlated with its Functional Properties. M. Grover, M. G. Wolfersberger, B. A. Wallace 4:00—67. Identification of the Glycation of Albumin and Fibrinogen Using NCI-GCMS. O. S. Olufemi, D. Talwar, D A. Robb, D. A. Williams

TUESDAY MORNING Jenness Hall

INORGANIC

Barbara J. W. Cole, Presiding 9:00—75. Movement to Low-Chlorine Bleaching. N. Liebergott 9:50—76. D. Droisbach 10:40—77. T. Hazel 11:10—78. Brightening of High-Yield Pulps with Glucose Oxidase. L. Jurasek

Carol B. Libby, Presiding 9:00—68. Sepharose-lmmobilization of Rat Hepatic Arylsulfotransferase. A. Spina, J. B. Mangold 9:25—69. Gardos Effect in Erythrocytes from Normal and Hypertensive Humans. W. D. Hobey, T. Savickas, A. D. Pechulis

MONDAY MORNING Bennett Hall Mitchell Bruce, Presiding

TUESDAY

AFTERNOON

Jenness Hall Wayne Robbins,

Presiding

1:30—79. Light-Induced Yellowing of HighYield Pulps. C. Heltner, J. Schmidt 2:20—80. Photodegradation of Lignin: a Photochemical Study on Phenolic and Nonphenolic α-carbonyl β-0-4 Lignin Model Dimers. A. Castellan, N. Colombo, P. F. de Violet, H. B. Laurent 3:20—81. Thermodynamic of the Phenolic Hydroxide Group in Kraft Lignins. D. L. Woerner 3:50—82. Retardation of Photo-Induced Dis­ coloration by Sulfur-Containing Com­ pounds. K. Sarkanen

CHEMICAL EDUCATION & HISTORY OF CHEMISTRY Symposium on High School Chemistry Teaching Workshop Robert M. Hawthorne, Program

Chair

MONDAY AFTERNOON Aubert Hall 1:30—83. Computers in the Chemistry Classroom. P. Cauchon

WEDNESDAY MORNING Barrows Hall

Jeffrey Nagle, Program Chair

TUESDAY MORNING Aubert Hall Symposium on High School Chemistry Teaching Workshop 9:00—84. Laboratory Computer Interfacing. P. Cauchon

9:00—94. Applications of " T c NMR. A. M. Roseberry, A. Davison, R. M. Pearlstein, J. F. Kronauge, J. R. Thornback, A. G. Jones 9:25—95. Technetium (V) Nitrido Complex­ es with Thiolate and Amine Ligands. N. de Vries, A. Davidson, A. G. Jones 9:50—96. Low Oxidation State Technetium Complexes with Chloride, Phosphine, and Bipyridine Ligands. A. I. Breikss, T. L. Nicholson, A. Davison, A. G. Jones 10:15—97. Trihydrogen Complexes of Iridi­ um. N. G. Payne, D. M. Heinekey 10:40—98. Characterization of a Chromium(VI)-Glutathione Thioester. S. L. Brauer, K. E. Wetterhahn 11:05—99. Importance of Reaction Interme­ diates in DNA Damage Induced by the Carcinogen Chromium(VI). J. A. Aiyar, K. M. Borges, K. E. Wetterhahn

MONDAY MORNING Bennett Hall Alice Bruce, Presiding 1:30—100. Stoichiometry and Products of Oxidation of 2,6-Dimethylphenol by py4Cu4Cl402 and py3Cu3MCU02 Complex­ es (M=Co, Ni, Zn) in Nitrobenzene. A. Abu-Raqabah, G. Davies, M. A. El-Sayed, A. El-Toukhy 1:55—101. Oxidation of 2,4,6 Trimethylphenol by Molecular Oxygen Catalyzed by a Trinuclear Ruthenium Carboxylate Cata­ lyst. M. Zimmer, N. K. Kildahl 2:20—102. Stoichiometry of Transmetalation of py4Cu4CI4 by M(NS)n Reagents and the Kinetics of Reduction of Dioxygen by the Products in Nitrobenzene. A. Abu-Ra­ qabah, G. Davies, M. A. El-Sayed, A. ElToukhy 2:45—103. Novel Rearrangement of an η2Dihydrogen Ligand. M. S. Chinn, D. M. Heinekey 3:10—104. Facile Oxidation of Rhenium Alkyl, Acyl, and Alkoxide Complexes: Evi­ dence for Rearrangements Via One-Elec­ tron Pathways. G. L. Gould, D. M. Heinekey

June 27, 1988 C&EN

51

Meetings

ACS NORTHEAST REGIONAL MEETING July 31-Aug. 3 (Please print or type)

Name

-Phone-

(Title: Dr., etc.) First Name

Last Name

Address

_State_

City_

_ZIP_

Company. ACS Section.

Name of spouse/guest included with this application. Indicate category below. FEES: Category Advance On Site One Day ACS Member $50 $60 $30 Nonmember $60 $70 $35 ACS Member, retired $25 $15 $27.50 High School Teacher $25 $15 $27.50 Student $10 $11 $6.00 Spouse/Guest, if on campus

Other Rafting Trip, Th $70/person. St Write for infornr Total for

Registration $ $10 $11 $6.00 No Registration Foe Unless Participating in Meeting.

Kids here with parents

Meals on Campus8

Room Rates on Campus per Person per Day

Package A: Mon. breakfast—Wed. lunch

Sun.

incl. lobster/steakb banquet Tues. % $41.80 How many lobster?

Double (& $12.60

How many steaks?

Extra Cot $6.00

Mon.

Tues.

Wed.c

Single (& $15.75

Total $

Package B: Same as A with regular dinner instead of banquet % $31.55

If multiple occupancy, with whom are you sharing? Limit 3 occupants per room.

How many?.

Total $_ Individual Meal Tickets (indicate number for each meal)

Room assignments may be made at our convenience unless someone is specified.

Mon.

Tues.

Breakfast (a $3.50

Wed.

Total

Expected Arrival Day/Time

Lunch (& $4.15

Departure Day/Time If by air, give airline, flight no. & time if you wish to

Dinner (a, $5

be met by University limousine

Banquet $ 15b Lobster?

Limousine? Yes Steak?.

Total for Meals

No

_ (no. of each?)

_$

Total for Room(s)

$

a Sunday evening meal available on campus 5 to 6 PM. Meals also available on nonmeeting days. Inquire. All meals except banquet cafeteria style. Restaurants available nearby, b Steak available. Monday noon is deadline for banquet tickets and choice of lobster or steak, c Rooms available before or after meeting, including Wed. night, Aug. 3, but may be in other than conference dormitories. If you wish space before or after, please indicate exact times. Rates same as above. The following motels have guaranteed the rates listed. In making reservations, be sure to mention ACS NERM 18 meeting at the University of Maine in order to get rates quoted. Comfort Inn, Exit 49, I-95. (AAA). Restaurant, pool. Two double beds or one king size. Flat rate, $39, 1 to 4 persons. About 6 miles from meeting. At 750 Hogan Road, Bangor, Me. 04401. 1-800-228-5150 or (207) 942-7899. Bangor Motor Inn, same exit. Lounge, continental breakfast. Single $32, double $39, extra person $6.00. Roll-in cot $6.00. No charge for kids under 12. At 701 Hogan Road, Bangor, Me. 04401. (207) 947-0355. TOTAL AMOUNT ENCLOSED FOR REGISTRATION, ROOM(S), MEALS $ Please mail application and check, made out to UNIVERSITY OF MAINE—NERM 18, so as to arrive NOT LATER THAN JULY 14, to: NERM 18, Conferences and Institutes Division, Chadboume Hall, University of Maine, Orono, Me. 04469.

52 June 27, 1988 C&EN

3:35—105. Rhodium(l) Catalyzed Decarbonylations of Allylic Acyl Chlorides: 1,3Scrambling of Allylic Chlorine Without (3?7-allyl)Rh Intermediates. T. Z. Liu, J. A. Kampmeier 4:00—106. Cobalt Coordination Chemistry and Latent Epoxy Polymerization Cataly­ sis. R. E. Colborn

TUESDAY MORNING Bennett Hall Wayne L. Smith, Presiding 9:00—107. Synthesis and Organometallic Chemistry of Some New Borane, Metallaborane, and Metallaheteroborane Cluster Systems. R. W. Miller, K. J. Donaghy, Z. Zhang, C. Davis, T. Whelan, J. T. Spencer 9:25—108. Spectroscopic Study of the Re­ action of Tungsten Trioxide Films with Hy­ drogen Sulfide. H. H. Patterson, K. Voelkner, T. Taylor 9:50—109. Investigation of Cluster-Assisted Deposition of Transition and Rare Earth Metal Thin Films. Z. Zhang, J. T. Spencer 10:15—110. Photoluminescence of Polyaniline Films. Y. Son, C. Carlin, H. H. Patter­ son 10:40—111. Preparation, Characterization, and Electrochromism of Thin Film Lithium Cobalt Oxides. T. E. Haas, R. B. Goldner, G. Wei, E. Candela 11:05—112. Quenching of the Photolumi­ nescence of Layered Gold(l) Salts by Ex­ cited-State Energy Transfer. H. H. Patter­ son, F. DeStefano, C. Thompson 11:30—113. Structure, Luminescence Properties, and Reactivity of a CeriumTungsten Heterobimetallic Compound. J. W. Bruno, P. N. Hazin WEDNESDAY

MORNING

Bennett Hall Jeffrey Nag le,

10:15—124. Ultrasound Promoted Diels-AI- I 3:10—147. Structural Studies on the Mammalian Pigment—Eumelanin. T. M. der Reactions. Total Synthesis of TanshinSchultz, S. Kurtz one IIA, Nortanshinone, Methyltanshinquinone and Danshendiol. J. Lee, J. K. 3:35—148. NMR Analysis, MM2 CalculaSnyder tions and X-Ray Data on the Conformation of 2.3.5-triphenylvalero Lactone. J. A. 10:40—125. Synthesis of Nitrogen Contain­ Stanley, K. A. Bolin ing Analogs of Etoposide. J. Kadow, M. 4:00—149. Study of the Nuclear Magnetic Saulnier, T. Jenks, D. Vyas Resonance of A/-(2-phenoxyethyl), N, N11:05—126. Stereoselective Approach to dialkyl amine Towards Ortho-Substitution. Thrysiferol and Venustatriol. N. Savich, J. H. A. El-Wakil, A. Abdel-Baky S. Panek 11:30—127. Intramolecular Addition Reac­ tions of Photochemically Generated Ylide Intermediates. J. P. Dittami WEDNESDAY MORNING

Barrows Hall Raymond C. Fort,

Presiding

1:30—128. Cyclization of Alkynllithiums. W. F. Bailey, T. V. Ovaska 1:55—129. Stereoselective Synthesis of C/s-Pyrano[2,3-b]Pyranes. M. A. Sparks, J. S. Panek 2:20—130. Reactions of 1,2-Diaminobenzene with Ethyl 4-Pyrone-2-Carboxylate and Related Esters. D. G. Markees 2:35—131. Metalation of Aryl i-Butylsulfoxides. Sulfoxides as Ortho Directing Groups in Aromatic Metalations. P. K. Trumper, J. C. MacDonald, D G. Guterman 3:00—132. Cl-Oxygenated Allylsilanes: Useful Homoenolate Equivalents for the Stereoselective C-Glycosidation of Pyranoside Derivatives. M. A. Sparks, J. S. Panek 3:25—133. Chiral Siliconides in Asymmet­ ric Induction Reactions. K. Shanmuganathan, B. L. Jensen 3:50—134. Hexahydroisoquinoline Interme­ diates from the Inverse Electron Demand Diels-Alder Reaction of 1,2,4-triazines: New Methodology. B. L. Chenard, R. T. Ronau

9:00—114. Electrochemically Induced Carbon Monoxide Insertion in the Metallacycle Cp(CO)CoC12H8. B. T. Donovan, W. E. Geiger. 9:25 — 115. Redox-lnduced Hapticity Changes: Effect of Substituents on Arene Bending in a Series of Rhodium Complex­ es. W. J. Bowyer, J. Merkert, W. E. Gei­ ger. 9:50—116. Vibrational Spectral Study of Lead Zirconates and Lead Zirconotitanates Prepared by a Sol-Gel Process. S. Li, R. A. Condrate Sr 10:15—117. Raman and FTIR Measure­ ments of Copper Deficient YBa2_ Cu 3 O x (x=6-7). Z. Assefa, H. H. Patterson, C. Smith 10:40—118. Superconducting Pastes and Paints. R. C. Chan, D. D. L. Chung 11:05—119. Yttrium: Super-alloys to SuperConductors, a Super-Element. Β. Τ. Kilbourn 11:30—120. Metal Recovery from Electroless Plating Wastes. C. S. Brooks

TUESDAY

MORNING

Barrows Hall Bruce L. Jensen,

Presiding

9:00—136. Degenerate Rearrangements in Nortricyclyl Cation. R. M. Jarret, J C. Veniero, T. P. Byrne, M. Saunders, Κ. Ε. Laidig 9:25—137. Is the General Base-Nucleophilic Catalysis Dichotomy an Artifact 9 J. A. King Jr. 9:50—138. Non-Kekulé Molecules—Toward the Understanding and Synthesis of Paramagnetic Organic Species. P. M. Lahti, A. S. Ichimura, D. A. Modarelli, M. Kearley 10:15—139. Hydrogen Abstraction by Cyclopropylidene and Planar Triplet Aliène. W. C. Shakespeare, R. P. Johnson 10:40—140. Electron Transfer-Induced Photoreduction of Arènes. G. A. Epling, A. Kumar, E. Florio 11:05—141. A/-Methylpyrazole/N-Methylimidazole Phototransposition Chemistry. J. W. Pavlik, P. Techasauvapak 11:30—142. Photochemistry of Electron Rich Phenylazides in Aqueous Media. A. C. Chan, C. A. Blum

ORGANIC CHEMISTRY

MORNING

Barrows Hall Peter K. Trumper,

Presiding

9:00—121. Novel Spiro-Cyclopropanated Tricyclic Quinolone Antiinfectives. M. C. Schroeder, J. S. Kiely 9:25—122. Recent Progress Toward the Synthesis of Quinocarcin P. K. Trumper, M. H. J. Cordes 9:50—123. Total Syntheses of the Indole Alkaloids Iboxyphylline and Desethylibohyllidine by a Biometic Pathway. J. B. Piner, M. E. Kuehne

Presiding

1:30—166. Raman Study of Chemical Vapor Deposited Polyimide Films on Cu Sub­ strates. R. Mack, C. Carlin, M. Cook, H. H. Patterson 1:50—167. Vibrational Structure of Guaiazulene in Ground and Excited States. A. C. Bevilacqua, M. M. Carrabba, J. E. Kenny 2:10—168. Measurements on Free Metal Atoms in the Vapor Phase. S. Ramaswami, M. Rutten, R. R. Reeves 2:30—169. Role of Histidine in the Mecha­ nism of Iron Release from Human Serum Transferrin. D. M. Martin, N. D. Chasteen 2:50—170. Phase Diagram Studies of Dis­ persed Collagen Using NMR and DSC. G Maffia ' 3:10—171. EPR Study of UV-lrradiated KN0 3 . R. C. Plumb, W. Xu 3:30—172. Kinetics of the Dimerization of Cyanamide. R. J. Best 3:50—173. Construction of the Mechanism for Oscillating Chemical Systems. Y. Luo, I. R. Epstein 4:10—174. Statistical Mechanical Theory of Weak Acids, J. C. Rasaiah 4:30—175. Bifurcations in the BromateChlorite-lodide Reaction. R. J. Olsen, I. R. Epstein

AFTERNOON

Barrows Hall

MONDAY EVENING Presiding

1:30—157. Synthesis of 2-Monosubstituted 1,1'-Binaphthyls via Pd(O) Coupling. S. M. Julin, R. P. Johnson 1:55—158. Acetylenic Epichlorohydrins to Allyl Alcohols or Tellurophenes: Chalcogen Ions in Organic Chemistry. R. P. Discordia, A. L. Finocchio, D. C. Dittmer 2:20—159. Some New Reactions of Arylhydrazines with α,/3-Unsaturated Aldehydes and Ketones. M. J. Hearn, S. A. Lebold, J. Schulz, A. Sinha 2:35—160. Reduction of 7-Phenyl-3-Substituted-Pyrazolo[1,5-a]Pyrimidines and 4Phenyl-8-Substituted-lmidazo[1,5-a]Pyrimidines to Dihydro and Tetrahydro Deriva­ tives. S. S. Tseng, J. P. Dusza, G. D. Francisco, J. W. Epstein 3:00—161. Indole as a Dienophile in Inverse Electron Demand Diels-Alder Reactions. S. C. Benson, J. L. Gross, C. A. Palabrica, U. Rangan, J. K. Snyder 3:25—162. Reactions of Sulfoxylate Ion with Organic Halides. M. D. Hoey, A. L. Finocchio, W. F. Jarvis, D. C. Dittmer

Aubert Hall Joint Session of Nonlinear Dynamics 81 Physical Chemistry Division P. L. Goodfriend,

Presiding

8:00—176. Comparison of Internal Conver­ sion Rates in ST and S2 States of Azulene. J. E. Kenny, S. K. Kulkarni, T. M. Woudenberg 8:20—177. Bose-Einstein Statistics as a Nonlinear Kinetic Problem. L. Peusner Poster Session 8:40—178. Ab-initio Study of Vertical Sin­ glet Excited States of Cyclopropene. J. J. Diamond —179. Caging and Recombination of Br2 in ArN Clusters: the Effect of Electron Local­ ization. L. Perera, F. G. Amar —180. Finite Temperature Dynamics of Carbon Clusters, S. Weerasinghe, F. G. Amar —181. Effect of Reagent Rotation on the Reaction OH + H2 — H 2 0 + H. J. A. Harrison, H. R. Mayne —182. Transient Electric Dichroism and Bi­ refringence of Poly-(3-octylthiophene) in Solution. S. Krause, J. F. Curry, M. Rappon TUESDAY

AFTERNOON

Barrows Hall

James J. Diamond, Program Chair

Joint Session of New NMR Methods Symposium & Organic Chemistry Division MONDAY

Joint Session of Nonlinear Dynamics & Physical Chemistry Division

PHYSICAL TUESDAY

Chair

Presiding

9:00—150. Carbanionic Rearrangements of Halomethylenecycloalkanes. S. P. Samuel, T. Niu, K. L. Erickson 9:25—151. Saphonification Studies of Hindered Aliphatic Esters. W. B. Martin, G. Walrath, K. Watkins, B. Wolf 9:50—152. Oxygen Exchange as a Function of Epimerization of 1-Phenyl-1-Ethanol. Kinetic Evidence for Asymmetric Carbocations. M. V. Merritt, T. L. Dugger, E. V. Smith, H. J. Cheon, S. Y. Lee, G. L. Fairbrother, N. B. Elliott, J. A. Darlington 10:15—153. Studies on 2,2,6,6-Tetramethylpiperidine-1-oxonium Salts and Their Oxidizing Properties on Selected Indole Derivatives. M. C. L. Flores, J. M. Bobbitt 10:40—154. Steric Effects on Acetal Cleavage. W. F. Bailey, L. M. J. Zarcone 11:05—155. Steric and Electronic Effects in the Synthesis of 1-Benzyl-2-Benzazepinones. G. O. Omburo, B. L. Jensen 11:30—156. Cyclobutanone Dithiophenyl Ketals; Synthesis and Reactions. T. W. Kwon, M. B. Smith

Peter K. Trumper,

Presiding

Peter K. Trumper, Program

Peter K. Trumper,

WEDNESDAY

MONDAY AFTERNOON Aubert Hall

James J. Diamond,

Barrows Hall MONDAY AFTERNOON

9:50—164. Semiclassical Dynamics of Mol­ ecules from Vibrational Spectra. M. Kellman 11:00—165. Sub-Doppler IR Laser Studies of Nonlinear Vibrational Dynamics in JetCooled Molecules D. J. Nesbitt

Michael D. Bentley,

Symposium on Nonlinear Effects in Dynam­ ics and Kinetics

Joint Session of Nonlinear Dynamics & Physical Chemistry Division

Howard R. Mayne, Presiding

Presiding

1:30—143. Isolation and Structure of Molluscicidal Saponins from Allium vineale. S. Chen, J. K. Snyder 1:55—144. Revised Structure of the Robustadials. Q. Cheng, J. K. Snyder 2:20—145. Structure of Lenticellarine, New Homoerythrina Alkaloid from Dysoxylum lenticellare. X. Zhang, J. K. Snyder. C. J. Kelley, J. D. Leary, T. A. Bischoff. A. J. Aladesanmi, C. O. Adewunmi 2:45—146. Biosynthesis of Anisomycin. J. W. LeFevre, S. Maier, T. Boehm, P. Watson

MORNING

Aubert Hall

Francois G. Amar, Howard Mayne, Program Chairs

MONDAY

MORNING

Aubert Hall Francois Amar, Presiding 8:45—Welcome and Introductory Remarks 8:50—163. Statistical Spectroscopy: Insight or Nonsense? R. W. Field

8:50—183. Transient Behavior and Dynami­ cal Manifolds in Model Chemical Kinetic Systems. E. Celarier 9:50—184. Sensitivity of Intramolecular and Unimolecular Decay Dynamics to Poten­ tial Surface Properties. G. Ezra 11:00—185. Oscillations, Pattern Forma­ tion, and Chaos in Chemical Reactions. I. R. Epstein

June 27, 1988 C&EN

53