21 Idea Chemicals From MICHIGAN CHEMICAL - C&EN Global

Nov 6, 2010 - 21 Idea Chemicals From MICHIGAN CHEMICAL. Chem. Eng. News , 1962, 40 (14), p 24. DOI: 10.1021/cen-v040n014.p024. Publication Date: ...
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SSL EdLda (^htBinMLt&mM From MICHIGAN CHEMICAL Are you taking advantage of the idea chemicals listed below? Others have. One or more may help you solve that knotty synthesis problem, create a new, commercially important product or enhance the properties and value of an established product. Need more detailed technical information? Cost data? A sample? Write us. We will be happy to assist you. Consider

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H

y d r ° 9 e n Bromide, Anhydrous Phosphorus Tribromide

HBr PBr3

W h e n looking for ways to brominate, hydrobrominate or catalyze.

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Ethyl Bromide n-Butyl Bromide

CH3CH2Br CH3CH2CH2CH2Br

W h e n looking for a convenient route to introduce an alkyl, chloroalkyl, or alkanol

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Lauryl Bromide

CH3(CH2)10CH2Br

group

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Trimethylene Chlorobromide 2,3-Dibromopropanol

CICH2CH2CH2Br CH2BrCHBrCH2OH

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2 -Bromobutyric

Bromoacetic A c i d Acid

CH2BrC00H CH3CH2CHBrC00H.

W h e n looking for an intermediate for preparation of substituted acids or esters.

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beta-Diethylaminoethyl Chloride Hydrochloride (DEC)

C2H5 c2H5^

beta-Dimethylaminoethyl Chloride Hydrochloride (DMC)

CH3 ^ >NC 2 H 4 CI • HCI

W h e n looking for the best way to i n troduce a dialkylaminoalkyl group, p u t standing value in the preparation of antihistamines, antimalarials, antispasmodics, tranquilizers and cationic derivatives of natural products.

I I

beta-Diisopropylaminoethyl Chloride Hydrochloride (DIC)

(CH3)2CH2 s. (CH3)2CH2 ^ N °

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gamma-Dimethylaminopropyl Chloride Hydrochloride (DMPC)

CH3>NC3H6Cl.

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gamma-Diethylaminopropyl Chloride Hydrochloride (DEPC)

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gamma-Dimethylaminobeta-methylpropyl Chloride Hydrochloride (DMMPC)

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beta-Dimethylaminoisopropyl Chloride Hydrochloride (DMIC)

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Tris

(2. 3-dibromopropyl) Phosphate (Rremaster. T23p)

C H 3

2 4

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ur| 2 H 4 U

\MPun

'MU

uri HCI

C 2 H 5

svMrUri c2H5^NL3H