4 NEW STEROX® NONIONICS-ALKYL PHENOL CONDENSATES

Nov 6, 2010 - Publication Date: June 13, 1960. Copyright © 1960 AMERICAN CHEMICAL SOCIETY. ACS Chem. Eng. News Archives. First Page Image...
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For pinpoint properties in your products, consider Monsanto surface-active agents:

STEROX

®

4 NEW STEROX NONIONICS ALKYL PHENOL CONDENSATES

DF Ethylene oxide adduct of:

dodecyl phenol

Color, APHA (typical)

180

pH, 1 % solution (typical) Cloud Point, °C. ( 1 % solution) Foam, Ross Miles, cm.

(0.1% @ 50°C.) 25 ppm water, inst. after 5 min.

1.8

after 5 min.

1.7

Spreading Coefficient Draves Wetting Time, sec. (0.25% @ 25°C.)

New S T E R O X D F , D J , N J and N L were developed to give consistent performance and genuine economy. T h e y are stable in acidic and alkaline media, even a t elevated temperatures, and are effective in both hard and soft water. T h e y provide specific advantages where low odor, light color and good deter gency are wanted; and also where emulsification, wetting, foaming characteristics or liquid-solid contact is important.

) Technical Data Sheets on new STEROX D F , DJ, NJ and NL. ) Comparison Card describing 16 STEROX and SANTOMERSE surfactants.

Name Company Address City

Zone

2.3 —0.5 75

Solubility... Miscible with water in all proportions. Soluble in many nonpolar solvents. Functions well wherever a surfactant would be desirable in oils or aliphatic solvents.

T o discover the specific advantages to you, check the table shown here. Then use the convenient coupon to get more information, samples and technical help. Or simply call your nearby Monsanto representative or serviceminded distributor.

Please send me ( (

32.7

Interfacial Tension (0.25% @ 25°C.)

Monsanto

2.0 1.9

150 ppm water, inst. Surface Tension (0.25% @ 25°C.)

Now, in m a n y types of products, you can "zero i n " even closer on a number of properties to boost performance and sales appeal. Monsanto has added four new alkyl phenoltype nonionics to its S T E R O X line of surface-active agents.

MONSANTO CHEMICAL COMPANY Inorganic Chemicals Division Dept. 3029-X, St. Louis 66, Missouri

7.0 below 0



#

Other Promising Characteristics. . . Valuable intermediate for sulfation. Conversion produces high-foaming active ingredients especially suited for liquid detergents. Unreacted, it is a low-foaming surfaceactive agent for use per se and an excellent emulsifier. Typical u s e s . . . In liquid detergents, emulsifiable toxicant concentrates, metal cleaning and treating compounds; as a paper rewetting agent and an emulsifier in a v a r i e t y of applications.

STEROX

DJ

STEROX

NJ

Ethylene oxide adduct of:

dodecyl phenol

Ethylene oxide adduct of:

Color, APHA (typical)

100

Color, APHA (typical) pH, 1 % solution (typical)

pH, 1 % solution (typical) Cloud Point, °C. ( 1 % solution)

7.0 40

Foam, Ross Miles, cm. (0.1% @ 50°C.)

Cloud Point, °C. ( 1 % solution)

nonyl phenol

nonyl phenol

50

Color, APHA (typical)

100

7.0 54

pH, 1 % solution (typical)

Surface Tension (0.25% @ 25°C.)

Interfacial Tension (0.25% @ 25°C.)

1.9

Interfacial Tension (0.25% @ 25°C.)

2.9

-1.4

Spreading Coefficient

-3.2

Draves Wetting Time, sec. (0.25% @ 25°C.) Detergency, unbuilt @ 60°C, 0.2% in 150 ppm water, as % lauryl sulfate

12

102

25 ppm water, inst. after 5 min.

12.9

150 ppm water, inst. after 5 min.

12.7

Draves Wetting Time, sec. (0.25% @ 25°C.) Detergency, unbuilt @ 60°C, 0.2% in 150 ppm water, as % lauryl sulfate

Cloud Point, °C. ( 1 % solution)

7.0 76

Foam, Ross Miles, cm. (0.1% @ 50°C.)

2.9 2.5 150 ppm water, inst. 2.8 after 5 min. 2.5 Surface Tension (0.25% @ 25°C.) 34

Spreading Coefficient

NL Ethylene oxide adduct of:

Foam, Ross Miles, cm. (0.1% @ 50°C.)

25 ppm water, inst. after 5 min.

STEROX

8.3 8.0 34.8

5

102

25 ppm water, inst. after 5 min.

15.5

150 ppm water, inst. after 5 min.

15.6

Surface Tension (0.25% @ 25°C.) Interfacial Tension (0.25% @ 25°C.) Spreading Coefficient Draves Wetting Time, sec. (0.25% @ 25°C.) Detergency, unbuilt @ 60°C, 0.2% in 150 ppm water, as % lauryl sulfate

8.8 8.6 36.2

4.3 -6.0

7

103

Solubility* • • Soluble in water and most polar solvents, but generally insoluble in nonpolar solvents.

Solubility... Soluble in water and most polar solvents, but generally insoluble in nonpolar solvents.

Solubility . . More soluble than Sterox NJ. Especially useful in solutions containing inorganic s a l t s or S A N T O M E R S E ® alkyl aryl sulfonates.

Other Promising Characteristics. . . Low foam and high chemical stability are combined with effective functional properties and ease of use. Lack of odor typically associated with this type of surfaceactive material makes perfuming easier—helps build market appeal for your products.

Other Promising Characteristics. . . Exceptionally light colored, this "wheel horse" nonionic is effective per se as an emulsifier and as a lightduty detergent for hard surfaces. In combination with SANTOMERSE alkyl arylsulfonates, it exhibits foamstabilizing effects, and produces a denser foam than that obtained with alkyl aryl sulfonates alone.

Other Promising Characteristics,. . . Primarily designed for use in liquid detergents. Exceptionally valuable for this application in combination with Monsanto T K P P . Effective per se as an emulsifier and light-duty detergent for hard surfaces. In combination with S A N T O M E R S E alkyl aryl sulfonates, it exhibits foamstabilizing effects and produces a denser foam than that obtained with alkyl aryl sulfonates alone.

Typical uses- • . In liquid and powdered detergents, chemical processing, textile dyes and scouring agents, and numerous compounds for metal cleaning and treating, paper de-inking, felt washing and other wet processing operations.

Typical uses. . . In liquid and powdered detergents, insecticides, and in numerous compounds for textile, paper and leather processing, chemical processing, petroleum acidizing and secondary recovery.

Typical uses.. . In liquid detergents, industrial cleaners, textile scouring and soaping-off compounds, many specialty products; as a post-polymerization latex paint stabilizer.