A comparison of theoretical and experimental limiting slopes for the

Phillip A. Wilmarth, and Arthur D. Payton. J. Phys. Chem. , 1981, 85 (25), pp 3950–3952 ... Analytical Chemistry. Dean and Harris. 1968 40 (8), pp 1...
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J. Phys. Chem. 1981, 85, 3950-3952

A Comparison of Theoretical and Experimental Limiting Slopes for the Concentratlon Dependence of Thermoelectric Powers in Dilute Aqueous Hydrochloric Acid and Hydrobromic Acid Phillip A. Wllmarth' and Arthur D. Payton' Chemlstry Department, Wlllemette University, Salem, Oregon 97301 (Recelved: Aprll22, 1981; In Fhal Form: August 28, 1981)

For hydrogen-electrode thermocells with a 10 "C temperature difference,initial thermoelectric powers (tep) in dilute (