A NEW ROHM & HAAS CHEMICAL CH,—-N % C SH CHL—NH
CH,—NH
ETHYLENE THIOUREA
CS CH,—NH
/
/
(2-mercaptoimidazoIine)
(2-imidazolidinethione) Melting point: Solubility in water:
AVAILABLE IN COMMERCIAL QUANTITIES
PROPERTIES I99-204°C Solubility in organic solvents: 2 % a t 30°C Moderately soluble in methanol, ethanol, 9 % a t 60°C ethylene glycol, pyridine, acetic acid. 4 4 % a t 90°C Relatively insoluble in most other solvents.
TYPICAL REACTIONSNaOH
CH2-N χ
Salt formation:
••
Χ—SH CH,-NH^
CH2-N ^ I )C-$Na + H20 CH,-NH^
Forms insoluble salts with heavy metals.
CH 7 0H
CHoOH
CH20
CH2-NH I CH 2 -NH'
Methyl ο I
x=s
derivatives:
> ι
H+
ll\
Ml C-SH-
!
CH 2 0
X
;c=s •
CH2-NH/
CH20
CH2-N
CH2-N
H+
CH2-Nx
• ι
CH2-N
X C-SCH,OH
"C-SCH,OK OH-
CH,-NH
0H-
;c=$
CH2-N/ I CHoOH CH,0 CH,-N CH2-N
CH20H
Alkvlation: l
CH,-N
1
CH3CI
%,
>-SH
U
CH2-NH^
CH,-N ν
y, N - C H 2
nu
NaOH KMn04
I >-S-S-Cf ' i < CH2-NH^ NHN-CH2
CH,-N
• 1
V; C - $ C H
CH2-NHX
CH2-N
V
3
HOBr
I >-SH CH2-NH/ ;H2O2
ArNH2 CH2-N V. — • ΐ' 2 >C-NHAr CH2-NH/ N-CH, CH2—Ν %, • 1 ; c - s — cS: CH2-NH/ \HN-CH3
CH2-N v I /C-S02H CH2-NH/
Oxidation:
Λ Please address your inquiries for samples and literature to Department SP
\^Mmm^m^mm:^^m^m£m^m^mm.WMmmvMmm^m^mi &, ,*.«
