Addition/Correction pubs.acs.org/JACS
A Palladium-Oxo Complex. Stabilization of This Proposed Catalytic Intermediate by an Encapsulating Polytungstate Ligand Travis M. Anderson, Rui Cao, Elena Slonkina, Britt Hedman, Keith O. Hodgson, Kenneth I. Hardcastle, Wade A. Neiwert, Shaoxiong Wu, Martin L. Kirk, Sushilla Knottenbelt, Ezra C. Depperman, Bineta Keita, Louis Nadjo, Djamaladdin G. Musaev, Keiji Morokuma, and Craig L. Hill* J. Am. Chem. Soc. 2005, 127, 11948−11949. DOI: 10.1021/ja054131h. he formulation “K 10 Na 3 [Pd IV (O)(OH)WO(OH 2 )(PW9O34)2]” for the complex described in this publication has been shown to be incorrect. The experimental data collected, including single crystal X-ray and neutron diffraction, 17 O and 31P NMR spectroscopy, extended X-ray absorption fine structure, and several other techniques, are correct. The interpretation and conclusion that a terminal palladium-oxo moiety was present in this complex is incorrect. As a result the authors withdraw this publication. See Craig Hill and co-workers, Inorg. Chem. 2012, DOI: 10.1021/ic2008914.
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Published: June 6, 2012 © 2012 American Chemical Society
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dx.doi.org/10.1021/ja207910h | J. Am. Chem.Soc. 2012, 134, 9533−9533
