Vol. I , No. 3, August, 1962
BOOKREVIEW 723
expect that (CzH&Rh&12 will be found to be structurally similar to (C0)aRhzClz. p-Dichlorotetraethylenedirhodium is only sparingly soluble in such solvents as ethanol, acetone, dioxane, chloroform, or methylene chloride and generally cannot be recovered pure from these solvents. The solid is moderately stable. Samples occasionally darken after storage for several days a t room temperature but are unaltered for months a t 5 ” . Upon slow heating in an evacuated tube there is little change below lOO”, but a t 115” the surface of the crystals becomes black, and further heating causes rapid destruction without evidence of melting. The coordinated ethylene of I is displaced by a number of ligands. For example, when suspensions in methanol were treated with cyclooctadiene, ethylene was displaced within 2 min., and the yellow p-dichlorobis-(cyc1ooctadiene)-dirhodium(1) described by Chatts precipitated. A similar displacement of ethylene occurred when I was treated with triphenylphosphine, hydrogen cyanide, acrylonitrile, or pyridine. A propylene analog of I has been prepared from propylene and hydrated rhodium(II1) chloride. I t is more soluble and dissociates more readily (6) J. Cbatt and L. M. Venanzi, J. Chem. Soc., 4736 (1957).
than the ethylene complex in solution or when heated. CONTRIBUTION Xo. 782 RICHARD CRAMER CENTRALRESEARCHDEPARTMENT EXPERIMENTAL STATION E. I. DU PONTDE NEMOURS AND COMPANY WILMINGTON, DELAWARE RECEIVED JUNE 15, 1962
A Correction for the Lattice Constants of Mixed Metal Oxides of Rhenium and Osmium with the Hexagonal Barium Titanate Structure Sir: The correct lattice constants for the following compounds erroneously reported in Inorganic Chemistry, 1, 245 (1962) are a,
BaaFezReOp BasCrzReOs BalMnOsOs BazFeOsOs
A.
5.81 5.70 5.82 5.76
c,
A.
14 10 13.8 14.2 14.1
DEPARTMENT OF CHEMISTRY ROLANDWARD UNIVERSITY OF CONNECTICUT STORRS,CONNECTICUT RECEIVED JUNE21, 1962
Book Review A Text-Book of Quantitative Inorganic Analysis Including Elementary Instrumental Analysis. Third Enlarged Edition. By ARTHUR I. VOGEL, Woolwich Polytechnic, London. John Wiley and Sons, Inc., 440 Park Avenue South, New York 16, N. Y. (and Longmans, Green and Co., Ltd.), 1961. xxx 1216 pp. 16 X 23 cm. Price, $12.00.
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Here, indeed, is a book! The comprehensive versatility of this author, whose texts on practical organic chemistry
and qualitative analysis are equally well known, is admirably demonstrated in this expanded version of his work on quantitative inorganic analysis. One cannot resist the temptation to compare this work with another having similar aims and scope (though, only 700 pp.), namely, Charlot and Bezier’s “Quantitative Inorganic Analysis.” I t is the latter work which tends to suffer by the comparison. The less critical choice of some procedures and their abbreviated descriptions, and the superficiality with which the theory and practice of some techniques are outlined, comprise possible objections to any such ambitious a coverage in a one-volume treatise. Though using 1246 pages in the process, Dr. Vogel has, by and large, succeeded in avoiding both criticisms, Represented as being a student text suitable for his
entire training in this area and a5 being of value to practicing analytical chemists, this book is fairly described as being all of that. The theory and practice of classical gravimetric and titrimetric methods are adequately treated. Advantageous and proven newer reagents and techniques applicable to “wet chemical” procedures are described for use, and not merely added as a weak appendage indiscriminately enumerating all that is new, A siniilar comment applies with respect to the inclusion of good methods for such elements as molybdenum, zirconium, uranium, etc. .In excellent chapter on complexometric titrations is largely devoted to the applications of ethylenediaminetetraacetic acid (EDTA). The practical and theoretical coverage of “instrumental” measuring techniques is very good and embraces most of the more familiar and consequential electrical dnd optical themes. Certain specialized techniques (such as the use of X-rays, Ranian spectroscopy, radiocheniical methods, nuclear magnetic resonance spectroscopy, etc.) are, understandably, not treated. Details on separations vta distillation and gds (adsorption) chromatography are not given, on the grounds that these are of inore general value in organic work. Gas-evolution tecliniques are concisely treated, however, and a detailed chap-
724 BOOKSRECEIVED
Inorganic Chemistry
ter on gas analysis logically includes the handling of organic gases and vapors. American readers may be interested to know that the author describes the use of as much, or more, apparatus of American, as of British, manufacture. A feature which should merit the commendation of most readers is the inclusion of realistic chapters on the theory and practice of such important separation techniques as ion exchange, chromatography, and solvent extraction. An excellent short chapter on inorganic microgravimetric and microtitrimetric analysis is frosting on the cake. As with the book of Charlot and Bezier, a very brief chapter on errors in quantitative analysis “exists”; in a minimal sense it is acceptable, but unexceptional. In a work of this magnitude, the inclusion of an extensive and well organized table of contents, appendix, and index are worthwhile features. Objection may be raised to the author’s conservation of space by omitting specific literature references throughout the text, though selected bibliographies follow each chapter. A more serious objection, related to use as a textbook, concerns the absence of any numerical problems. But some instructors prefer to dispense their own problem material, and the textual exposition of theory often does include typical calculations, A good treatment of procedures for the analysis of complex materials (ferrous and non-ferrous alloys, limestone, silicate mineral, etc.) is included. The procedure given for the analysis of a silicate mineral provides one example of the struggle between modernism and classicism. Classicists may resent the abbreviated description given the old approach to this analysis and the greater attention given a streamlined substitute. Neither the NaOH fusion nor the Berzelius (HF H2S04) decompostion specified have quite the universality of applicability of the corresponding PiazCOj fusion or J. L. Smith method. But the use 01 a Berzelius dissolution with the EDTA determinations of Ca and Mg and flame photometry for Na and K must certainly conform with more typical modern practice. This reviewer is conservative enough, however, to join the classicists’ club in bemoaning the use of a silica assay in a silicate mineral via a low temperature drying form of quinoline siliconiolybdate. But the majority of Dr. Vogel’s innovations are not this drastic. Anyone concerned with quantitative inorganic analyscs should be interested in this book. Those concerned with the teaching of this subject could seriously consider this text as a worthy guide for two semesters of work. Dr. Vogel is to be congratulated on his uniquely “modern” approarb with due regard to the basic and the “classic.”
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DEPARTMENT OF CHEMISTKY OF MICHIGAN UNIVERSITY ANX &OR, MICHIGAN
CHARLES L. RULFS
Stuttgart W. Hasenbergsteige 3, Germany.
GEORG BRAUER. “Handbuch der priiparativen anorganischen Chemie.” Vol. 11. Ferdinand Enke Verlag, Stuttgart W. Haseiibergsteige 3, Germany. 1962. 726 PP . P. BAUMAN.“Absorption Spectroscopy.” John Wiley and Sons, Inc., 440 Park Avenue South, Sew York 16, N.Y. 1962. 602pp. A. F. CLIFFORD. “Inorganic Chemistry of Qualitative Analysis.” Prentice-Hall, Inc., Englewood Cliffs, N. J. 1961. 499pp. A. COOK,Editor. “Argon Helium and the Rare Gases.” Vol. I. Interscience Publishers, Inc., 250 Fifth Avenue, New York 1, N. Y. 1961. 394 pp. A. COOK,Editor. “Argon Helium and the Rare Gases.” Vol. 11. Interscience Publishers, Inc., 250 Fifth Avenue, New York 1,N. Y. 1961. 391 pp. F. A. COTTON AND G. WILKINSON.“Advanced Inorganic Chemistry.” Interscience Publishers, John Wiley and Sons, Inc., 440 Park Avenue South, Sew York 16, N. Y. 1962. 942pp. P. J. DURRANT AND B. DURRANT. “Introduction to Advanced Inorganic Chemistry.’’ John Wiley and Sons, Inc., 440 Park Avenue South, New York 16, N. Y. 1962. 1147 pp. J. 0. EDWARDS, Edited by. “Peroxide Reaction Mechanisms.” Interscience Publishers, John Wiley and Sons, Inc., 440 Park Avenue South, New York 16, N. Y. 1962. 225pp. A. A. FROST AKD R. G. PEARSON.“Kinetics and Mechanism.” John Wiley and Sons, Inc., 440 Park Avenue South, New York 16, N. Y. 1961. 387 pp. J. H. HILDEBRAND AND R. L. SCOTT. “Regular Solutions ” Prentice-Hall, Inc., Englewood Cliffs, N. J. 1962. 17’3pp. I. M. KOLTHOFF AND P. J. ELVIS, Edited by. “Treatise on Analytical Chemistry.” Part 11, “Analytical Chemistry of the Elements.” Vol. 7. ‘‘S, Se, Te, F, Halogens, Mil, Re.” Interscience Publishers, John Wiley and Sons, Inc., 440 Park Avenue South, New York 16, S.Y. 1961. 632pp. A. STREITWIESER, JR. “Molecular Orbital Theory for Organic Chemists.” John Wiley arid Sons, lnc,, 410 Park Avenue South, X c w York 16, N.Y. 1961. 460 PP. I?, G. A. STONE. “Hydrogen Coinpr,unds of the Group IV Elements. Silicon, Germanium, Stannum, I’lumbuni.” Prentice-Hall, Inc., Etiglewood Cliffs, N.J. 1962. 11 1 PP. P. ZUMAN,Edited by. With the collaboration of I. M. KOLTHOFD.“Progress in Polarography.” Vol. 11. I n terscience Publishers, John Wiley and Soils, Inc., 440 Park Avenue South, Kcw York 16, K, 71’. 1962. 725 PP SEVENTH INTERSATIONAL CONFERENCE ON COORDINATIOS CHEMISTRY.Proceedings. Program for Seventh International Conference. Held in Stockholm and UppSILLSN,Chairman, Execusala, Sweden. LARSGUNNAR tive Committee of 7th ICCC. 387 pp. EDWINS. GOULD. “Inorganic Reactions and Structure.” Revised Edition. Holt, Rinehart, and Winston, Inc., 383 Madison Avenue, New York 17, K. Y. 1962. 4% PP
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BOOKS RECEIVED March 1, 1962-July 1, 1962 W. E. ADDISOX. “Structural Principles in Inorganic Compounds.” John Wiley and Sons, Inc., 440 Park AvenueSouth, New York 16, h’.Y. 1961. 166 pp. GEORGBRAUER. “Handbuch der praparativen anorganischen Chemie.” Vol. I. Ferdinand Enke Verlag,
1962.
885 pp.
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