Acrylic Manomers - C&EN Global Enterprise (ACS Publications)

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η-Butyl Acrylate Isobutyl Acrylate 2-EthyIhexyl Acrylate n-Octyl Acrylate Acrylic Acid Calcium Acrylate Methacrylic Acid—Glacial

Ethyl Methacrylate η-Butyl Methacrylate n-Hexyl Methacrylate n-Octyl Methacrylate n-Lauryl Methacrylate Methacrylic Acid—90%

Methyl Acrylate Ethyl Acrylate Methyl Methacrylate

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Typical Reactions ~»CH| CHCOOR II C H * I CH I CHa

CH 2 + Jf CH2

t CH

No/

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ArOH 4-CH 2 =CHCOOR

•*• ArOCHlaCHaCOOR

H2S + CH2 = CHC0OR -

-*- R0OCCH 2 CHa-S-CHaCHaCO0R

C i 2 H 2 3 N H 2 + CH 2 =CHCOOR

•*- CiaHasNHCHjCHaCOOR

(CHs)s'NH + CH*=CHCOOR C l f

0

-*- (CH3)aNCH2CHaCOOR CH 3 .

-

3 \

•*- CHs-C-CHaCHaCOOR

CHMOa + CHa= CHCOOR

CH3/

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-^CICHaCHaCOOR

HCI + CHa - CHCOOR

HSCH2CH2CO0R S03H CH2 = C - C 0 0 H

CH 2 = CHCO0C 2 H 5

ΟUses

KMn04

*» H0CHa-CHCO0CaH s CI NaOH -*• CICH2-CHCOOR -^ »- C H 2 = C - C O 0 R

CH 2 = CHCOOR+ C I 2

P o l y m e r i z a t i o n reactions w i t h o t h e r m o n o m e r s . Chemical intermediate in organic s y n t h e s i s .

FOR INDUSTRY

CHEMICALS

A v a i l a b l e now from two p l a n t s (Bristol, P a . a n d ICnoxville, T e r m . )

ROHM £- BMJ^S C O M

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WASHINGTON SQUARE, PHILADELPHIA 5, PA. Rtpmcnialivn



in principal

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W r i t e D e p t . S P for new booklet: T H E M O N O M E R I C ACRYLIC ESTERS