Addition of O (3P) to olefins. Nature of the intermediate

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COMMUNICATIONS TO THE EDITOR

2732

for trans- and cis-Zbutene are also applicable to other internal straight-chain olefins. l 2

Table I ----Addition

Temp, OK

298

77

Cyclopentene oxide

products, %--CyclobutaneCyclopencarboxtanone aldehyde

24 32

54 62

DIVISIONOF CHEMISTRY NATIOXAL RESEARCH COUNCIL O F OTTAWA, CANADA

PIF/totel

RECEIVED SEPTEMBER 3, 1969

reaction

22

0.26

6