1010 The Journal of Physical Chemistry, Vol. 96, No. 2, 1992
Additions and Corrections
ADDITIONS AND CORRECTIONS 1991. Volume 95
Martin J. Rabinowitz, James W. Sutberland, Patricia M. Patterson, and R. Bruce Memm*: Direct Rate Constant Measurements for H + CHI CH3 + H2, 897-1 729 K, Using the Flash
-
Photolysis-Shock Tube Technique. Page 680. Equilibrium constant expressions, eq VI and eq IX, have errors in the signs of some coefficients. The following expressions give corrected values that now fit JANAF (1985) data for the H + CH4 CH3 H2 reaction: 800 K I T 5 1800 K:
-
K l ( T ) = -9.202
+
+ (5.095 X
+
10-2)T- (2.530 X 10-5)p (4.154 x 10-9)~3(VI)
298 K 5 T I800 K: K , ( T ) = 1.239
+ (1.024 X 10-2)T + (2.847 X 10-5)P (1.983
X
10-*)T3 (IX)
We thank Dr. Norman Cohen for bringing this error to our attention.
