Additions and Corrections-Kinetic Generation of cis-C5H5 (CO

vco infrared bands of ds-Cp(CO)2ReH2 (cis-1), frans-Cp(CO)2-. ReH2 (trans-1), cis-Cp*(CO)2ReH2 (cis-2), and irans-Cp*(CO)2-. ReH2 (trans-2) and the ...
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5978

Inorg. Chem. 1994,33, 5978

Additions and Corrections 1992, Volume 31

Charles P. Casey,f Robin S. Tanke, Paulette N. Hazin, Carl R. Kemnitz, and Robert J. McMahon: Kinetic Generation of cis-C5Hs(CO)zReH* from Reaction of C5H5(CO)zRe@-H)Pt(H)(PPh& with Diphenylacetylene. Pages 5474-5479. The relative integrated intensities of the vco infrared bands of cis-Cp(CO)zReH2 (ck-1), trans-Cp(C0)zReHz (trans-1),cis-Cp*(CO)zReH~(ciS-2), and truns-Cp*(C0)2ReHz (trans-2) and the calculated angle between the CO ligands of truns-2 were incorrectly reported. The vco infrared band positions, corrected relative integrated absorbances, and corrected bond angles (28) between the CO's calculated using the are as follows: cis-Cp(CO)zReHz formula cot2 8 = Isym/Zasym (cis-1), 1997 cm-I (0.81) and 1920 cm-' (l.O), 28 = 96"; trunsCp(CO)zReH2 (trans-1),201 1 cm-' (0.43) and 1936 cm-' (l.O), 28 = 113"; cis-Cp*(C0)2ReHz (cis-2), 1987 cm-' (0.92) and 1900 cm-' (l.O), 28 = 92"; truns-Cp*(C0)2ReH~(trans-2), 1996 cm-1 (0.57) and 1920 cm-' (l.O), 28 = 106".

0020-166919411333-5978$04.50/0 0 1994 American Chemical Society