Additions and Corrections-Synthesis and Reactions of Enantiopure

Reactions of Enantiopure (Neomenthylcyclopenta- dienyl)iridium(III) Halides with Silver Salts. A Dra- matic Steric Effect on the Competition between I...
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Organometallics 1994,13, 4648

4648

Additions and Corrections 1994,Volume 13 Yinong Ma and Robert G. Bergman.: Synthesis and Reactions of Enantiopure (Neomenthylcyclopentadienyl)iridium(III) Halides with Silver Salts. A Dramatic Steric Effect on the Competition between Interand Intramolecular C-H Activation. Page 2549. The regio- and stereochemistry of the complexes illustrated in Schemes 1 and 2 was incorrectly drawn. Corrected copies of the two illustrations are shown below. The regio- and stereochemistry in the ORTEP diagram (Figure 1)is correct, and the conclusions in the paper are unchanged. We are grateful to Dr. Andreas Heumann, Universith d’Aix Marseille, for calling our attention to this error. Scheme 1

AgSbFs CDzCI2 25 OC

(RMdiastereomer)

lla

Scheme 2

0276-7333/94/2313-4648$04.50/00 1994 American Chemical Society

Rh

PMe,