The Journal of Physical Chemistry, Vol. 89, No. 11, 1985
2436
Additions and Corrections
ADDITIONS AND CORRECTIONS 1984, Volume 88
T. R. Tuttle, Jr.,* Sidney Colden, Salia Lwenje, and Catherine M. Stupak: The Shape as a Characteristic Property of Solvated Electron Optical Absorption Bands. Page 3812. Replace the section of Table IV headed with the chemical formula of 1-propanol with 298 299
0
RT 300
h h h h
300 300 300
0.79 1.55 2.41
227 2108 233 -683 -1414 -2018
1.000 0.999 1.156 1.001 1.001 1.009 1.003
0.007f 0.014 0.118 0.009 0.010 0.010
0.5447
4.756
0.983
0.016
0.047
0.007
respectively. Replace Figure 6 with I .o
25 30 28 21 21 21 21
0.008
and
0.8 0.6
F 0.4
Page 3813. Replace Figure 4 and its caption with I
'
I
I
I
I
I
1
0.2
I
0 01 12
0
+
I
IO
6
I
14
IO
18 v*
22
26
30
34
38
(crn-lx 1 0 3 )
Page 3815. In the next to last line of the caption of Figure 7 the materialf; 1.015, v* = 0.4493 1 . 0 2 0 ~should be replaced by f = 1.015, v* = 0 . 4 4 9 3 ~+ 1.020. In the last line of the caption of Figure 9 the material v* = 0 . 4 1 5 5 ~+ 1.369 should be replaced by v* = 0 . 4 4 6 7 ~+ 1.118. In line 4 of column 1 replace the material 0.440 f 0.012 with 0.466 f 0.027. Replace Figure 10 with
08
+
fF 0 6
04
02
I.o 0
8
12
16
20 w*
24
28
32
36
40
Figure 4. Plot of height-adjusted relative absorption, fF,vs. reference frequency, v* = v + Av, for solvated electron spectra in 1-propanol. Values off and Av and references to data are given in Table IV. The rms deviations of all the data used in constructing the average spectral profile are given on a tenfold expanded absorbance scale in the histogram above the plot of the data themselves: V, 298 K; c], 299 K; 4 , 300 K; X, 300 K, 0.79 kbar; 0, 300 K, 1.55 kbar; A, 300 K, 2.41 kbar; +, RT. Note that the data set represented by the symbol + has been excluded from calculation of the values of 6 plotted in the histogram. (See text for details.) Page 3814. Delete the text on 1-propanol extending from the sentence beginning on line 7 in column 1 through the sentence ending on line 12 and insert in its place: For propanol, as for ethanol, all the data except that from a single spectrum seems to fall on a single profile. The reason for this exception here is also not known. Replace the numerical entires in lines 4 and 10 of Table V with 0.5198
0.411
0.995
0.8
(crn-'xlo3)
0.016
0.008
0.007
-
fF
I
oc
t
0.6
0
.t
0.4
0
t
0.2
- 0
t 0
0 6
8
IO
12
14
16
18
20
u n ( c r n - l x 103)
Page 3817. Replace footnote g with footnote f in Table VII. Disregard footnote g.
Acknowledgment. We are indebted to Professor G. R. Freeman and Dr. F.-Y. Jou for bringing to our attention the inadvertent misrepresentation of some of their data in Figure 4 of our uncorrected paper, Le., that pertaining to different pressures at 300 K from F.-Y. Jou and G. R. Freeman, J . Phys. Chem., 81,909 (1977).
