Al2O3 Encapsulated Teflon Nanostructures with High Thermal

Sep 28, 2017 - The State Key Laboratory for New Ceramics & Fine Processing, School of Materials Science & Engineering, Tsinghua University,. Beijing, ...
2 downloads 9 Views 2MB Size
Subscriber access provided by LONDON METROPOLITAN UNIV

Article

Al2O3 Encapsulated Teflon Nanostructures with High Thermal Stability and Efficient Antireflective Performance Sadaf Bashir Khan, Hui Wu, Zheng Xie, Weipeng Wang, and Zhengjun Zhang ACS Appl. Mater. Interfaces, Just Accepted Manuscript • DOI: 10.1021/acsami.7b12903 • Publication Date (Web): 28 Sep 2017 Downloaded from http://pubs.acs.org on September 30, 2017

Just Accepted “Just Accepted” manuscripts have been peer-reviewed and accepted for publication. They are posted online prior to technical editing, formatting for publication and author proofing. The American Chemical Society provides “Just Accepted” as a free service to the research community to expedite the dissemination of scientific material as soon as possible after acceptance. “Just Accepted” manuscripts appear in full in PDF format accompanied by an HTML abstract. “Just Accepted” manuscripts have been fully peer reviewed, but should not be considered the official version of record. They are accessible to all readers and citable by the Digital Object Identifier (DOI®). “Just Accepted” is an optional service offered to authors. Therefore, the “Just Accepted” Web site may not include all articles that will be published in the journal. After a manuscript is technically edited and formatted, it will be removed from the “Just Accepted” Web site and published as an ASAP article. Note that technical editing may introduce minor changes to the manuscript text and/or graphics which could affect content, and all legal disclaimers and ethical guidelines that apply to the journal pertain. ACS cannot be held responsible for errors or consequences arising from the use of information contained in these “Just Accepted” manuscripts.

ACS Applied Materials & Interfaces is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Published by American Chemical Society. Copyright © American Chemical Society. However, no copyright claim is made to original U.S. Government works, or works produced by employees of any Commonwealth realm Crown government in the course of their duties.

Page 1 of 31

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

Al2O3 Encapsulated Teflon Nanostructures with High Thermal Stability and Efficient Antireflective Performance Sadaf Bashir Khan ỻ, Hui Wu ỻ, Zheng Xie ỻ, †, Weipeng Wangϔ, Zhengjun Zhang,$,* ỻ

The State Key Laboratory for New Ceramics & Fine Processing, School of Materials Science

& Engineering, Tsinghua University, Beijing, China, 100084. †

High-Tech Institute of Xi’an, Xi’an 710025, China

ϔ

Department of Material science and nano engineering, Rice University, Houston, TX77005,

United States. $

Key Laboratory of Advanced Materials (MOE), School of Materials Science & Engineering,

Tsinghua University, Beijing, China, 100084. * Email: [email protected] KEYWORDS: Hydrophobic surface, Polymer optical coating, Water contact angle, Broadband Antireflectance, Mechanical resilience

ACS Paragon Plus Environment

1

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 2 of 31

ABSTRACT

Scientific advancement is highly inspired and imitative of natural phenomenon’s, which exhibits extremely developed and well-organised nanostructures to cope with challenges under different environmental circumstances, such as moth eyes protuberances for efficient antireflective (AR) performance. Innovative researches have been performed in the past to exterminate the undesirable reflectance in common optical components and optoelectronic industrial applications by biomimetic and replicating moth eye nanostructures creating gradient effect using metal oxides, composites or polymers in multilayer AR coatings. However, in few multilayer AR designs, the properties mismatch at interfaces, high cost, low mechanical durability, wetting issues or thermal stability bounds their practical applicability. Herein, we develop an approach for fabricating efficient, high-performance Teflon (polytetrafluoroethylene [PTFE]) AR nanostructures for glass-based supporting materials. Nanotailoring, the morphology and structure of PTFE, have been efficaciously carried out for fabricating high-performance AR coatings according to predicted optical simulation.

The total reflectance from polymer AR coating

lessens to