Alkylation of Hydrochlorosilanes - Journal of the American Chemical

J. Am. Chem. Soc. , 1947, 69 (11), pp 2687–2689. DOI: 10.1021/ja01203a039. Publication Date: November 1947. ACS Legacy Archive. Cite this:J. Am. Che...
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ALKYLATION OF HYDROCHLOROSILANES

Nov., l!M7

7

-X

-

TABLEI (Continued) Ar- N (R)-CO-CH2-S-X Found

20a210 23 1 245 251 259 202h 246 260 268 256-258"

52.3 52.3 52.3 50.4 50.1 44.9 47.7 -17.7 48.7 48.3

52.2 51.9 52.3 50.2 50.2 44.7 47.3 47.4 47.9 47.6

2156 23S6 2406 202hm 11 249 243 284" 274 276 268 23 1 265

51.9 51.9 51.9 50.1 50.1 48.4 48.4 45.3 46.8 44.5 37.9 37.5

...

(R-NH-CO-CH-S)I-----

7

Au

Calcd.

Dec.. T . 1 1

8687

..

M . p., OC.11

82' 17lC 1869 185 235 150 2131 2091 184 176"' 198" 51.1 213 50.8 166 51.1 202 50.0 126 49.9 1919 47.7 220-222 (dec.) 47.6 281 (dec.) 44.6 146 15.3 218.5-220.5 43.5 246 (dec.) 37.9 226-228 (dec.) 36.