Alkylidenecarbenes - Journal of the American Chemical Society (ACS

Masato. Tanabe, and Raymond A. Walsh. J. Am. Chem. Soc. , 1963, 85 (21), pp 3522–3523. DOI: 10.1021/ja00904a064. Publication Date: November 1963...
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3522

A Volatile Chelated-Nickel Dicarbonyl'

Sir. Chelation of nickel by bis-phosphines or bis-arsines, forming heterocyclonickel dicarbonyls, has been acconiplished by C h a t t and H a r t 2; however, no compound in this class was reported to be volatile without decomposition, whereas volatility often would be advantageous for the further study of such substances. Accordingly, we have used high-vacuum methods to make the study of a new volatile compound presumed t o have the structure 0%

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(CF,),P