Article pubs.acs.org/Organometallics
Alkyllithium Mixed Aggregates: Dynamic Behavior and Comprehensive Analysis of NMR 2J7Li−7Li Spin−Spin Coupling Ghanem Hamdoun, Muriel Sebban, Vincent Tognetti,* Anne Harrison-Marchand, Laurent Joubert, Jacques Maddaluno, and Hassan Oulyadi* Normandie Université, COBRA, UMR6014 & FR3038 CNRS, Université de Rouen, INSA de Rouen, 76821 Mont-Saint-Aignan Cedex, France S Supporting Information *
ABSTRACT: The measurement and assignment of scalar couplings in NMR spectra have, of course, been of interest to chemists for a long time because of the useful structural and dynamic information that can be provided. In the case of organolithium compounds, the magnitude of spin− spin coupling involving lithium strongly depends on the coupling partner, with fairly large values (>2 Hz) for 13C and 15N and small values (
