The benzilic acid rearrangement of alloxan (I) to alloxanic acid1 (II) has been the subject of a recent2 kinetic study, on the basis ofwhich it was suggested.
EVIDENCE FOR NITROGEN MIGRATION IN THE BENZILIC ACID REARRANGEMENT OF ALLOXAN AND DERIVATIVES. Harold Kwart, Richard W. Spayd, and ...
EVIDENCE FOR NITROGEN MIGRATION IN THE BENZILIC ACID REARRANGEMENT OF ALLOXAN AND DERIVATIVES. Harold Kwart, Richard W. Spayd, and ...
Feb 3, 2006 - ... in Organic Chemistry, 5th ed.; Longman Group Ltd.: London and New York, 1981; Chapter 8.4.10. ..... Craig M. Comisar and Phillip E. Savage.
However, LUMOs of the 1,2-diketones have large and nodeless lobes at the reaction center, the. C(1)-C(2) bond. The specific LUMO character is reflected both ...
Department of Chemistry, Nara University of Education, Takabatake-cho, Nara .... Macrolactams from an Eastern Kentucky Abandoned Coal Mine Microbe.
Feb 3, 2006 - Reaction paths for the title rearrangement along with its methyl analogue were investigated by density functional theory calculations.
May 1, 2002 - Determination of scandium by precipitation with benzilic acid. Michael H. Mullin ... Inorganic Gravimetric and Volumetric Analysis. F. E. Beamish ...
THE BENZILIC ACID REARRANGEMENT. Theodore W. Evans, and William M. Dehn. J. Am. Chem. Soc. , 1930, 52 (1), pp 252â254. DOI: 10.1021/ja01364a037.
Introduction. What appears to be the essence of a proposal by .... 96.4°) whose purity did not appear to beaffected by a repeti- tion of the procedure. Dioxane ...
2580
LUMMUNlCAllVNb
R’
IIIa, x
+
c0 2
P‘
Ir
0
Ib R2N Shift
R*
R‘
I
TABLE I RADIOCHEMICAL RESULTSO F THE REARRANGEMEST OF ALLOXAS-4-C’4A S D DERIVATIVES [Ib] PH ca. 13
