Analysis of the Paramagnetic Copper (II) Site of Amicyanin by 1H NMR

Analysis of the Paramagnetic Copper(II) Site of Amicyanin by 1H NMR Spectroscopy. Arnout P. Kalverda ... Publication Date (Web): August 13, 1996. Copy...
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10586

Biochemistry 1996, 35, 10586

Corrections Analysis of the Paramagnetic Copper(II) Site of Amicyanin by 1H NMR Spectroscopy, by Arnout P. Kalverda, Jesu´s Salgado, Christopher Dennison, and Gerard W. Canters*, Volume 35, Number 9, March 5, 1996, pages 3085-3092. Page 3088. The hyperfine coupling constants (aH) listed in Table 1 are incorrect and should read as follows: H54 Cδ2H, 0.50; H54 N2H, 0.21; H54 Cβ2H, -0.12; H54 Cβ3H, -0.05; C93 CRH, 0.15; M99 CγH, 0.10; M99 CγH, 0.09; H96 Cδ2H, 0.60. Page 3090. As a consequence of the above corrections the π-system of the imidazole ring of His54 possesses approximately 5% spin density. BI965008T

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© 1996 American Chemical Society