analytical chemistry - American Chemical Society

WALTER J. MURPHY. Executive Editor ... E. L. Saier, Abbot Pozefsky, and N. D. Coggeshall. Accurate ... B. F. Dudenbostel, Jr., and William Priestley, ...
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ANALYTICAL CHEMISTRY Volume 2 6 , N o . 8

EDITOR WALTER J. MURPHY

Issued August 16, 1954

Copyright 1954 by the American Chemical Society

EDITORIALS

1257

Determination of Olefin Group Types E. L. Saier, Abbot Pozefsky, and N . D. Coggeshall

1258

James M. Crowe

Accurate Analysis with Infrared Double-Beam Spectrophotometer Robert Schnurmann and Fdward Kendrick

1263

Science Editor

Graphical Absorbance-Ratio Method for Rapid Two-Component Spectrophotometry Analysis R. C. Hirt, F. T. King, and R. G. Schmitt

1270

Lawrence T. Hallett Production

Detection and Estimation of Melamine in Wet-Strength Paper by Ultraviolet Spectrophotometry R. C. Hirt, F. T. King, and R. G. Schmitt

Executive Editor

Manager

. . . .

1273

Joseph H. Kuney

Automatic Mass Speetrometric Analysis B. F. Dudenbostel, Jr., and William Priestley, Jr.

1275

Associate Editors Stella Anderson G . Gladys Gordon Bertha Reynolds Charlotte C. Sayre Ruth Cornette

Spectrophotometry and Polarographîc Determinations of Soluble Silicate M. A. DeSesa and L. B. Rogers

1278

Thiocyanate Spectrophotometric Determination of Molybdenum and Tungsten C. E. Crouthamel and C. E. Johnson

1284

Polarographîc Determination of Maleate Unsaturation in Polyesters

1291

E. W. Hobart Assistant Editor Katherine I. Biggs Editorial Assistants Betty V. Kieffer Sue R. Peter Ruth C. Laubach Veronica O'Keefe Dolores M. Federico Fern S. Jackson Ruth M . Howorth

Polarographîc Determination of Molybdenum(VI) E. P. Parry and M. B. Yakubik

1294

Polarographîc Determination of Dissolved Oxygen in Dilute Sulfite Waste Liquor H. S. Levine and O . J. Williams

1297

Polarographîc Determination of Tungsten in Rocks L. E. Reichen

1 30Î

Radioactivity Assay of Water and Industrial Wastes with Internal Proportional Counter L R. Setter, A. 5. Goldin, and J. S. Nader

1 304

Quantitative Radiochemical Method for Determination of Major Sources of Natural Radioactivity in Ores and Minerals * , , , . , . , , , , , , , . J. N. Rosholt, Jr.

1307

Continuous Recording of Concentration of Organic Matter in Waste Water Richard Ki'eselbach

1312

R. H. Müller

Studies with N-Halo Reagents P. F. Kruse, Jr., K. L. Grist, and T. A . McCoy

1319

Advisory Board S. E. Q. Ashley H. F. Beeghly G . E. Boyd A. Q . Butler N . H. Furman W . W . Hilty D. N. Hume Robert Kunin S. S. Kurtz, Jr. J. J. Lingane Gordon MacKinney V. A. Stenger Grant Wernimont P. W . West J. H. Yoe

Titration of Bismuth with Ethylenediaminetetraacetic Acid A. L. Underwood

1322

Estimation of Rubber in Asphalt Geert Salomon, Elizabeth Pezarro-Van Brussel, and A, C. van der Schee

1325

Determination of Germanium in Coal, Coal Ash, and Flue Dust. W. J. Frederick, J. A. White, and H. E. Biber

1 328

Anthrone in Estimation of Hexose Sugars with Special Reference to Pentose Interference Ronould Johanson

1331

Determination of Diphenylmercury Alone in Presence of Phenyl Mercuric Compounds V . L. Miller and Dorothy Polley

1333

Contributing Editor

This Month's Cover.

The

mountain states area and Kennecott copper can be justifiably proud this month as the company's new research center is dedicated. Located on the University of Utah's campus at Salt Lake City, these facilities will be an important addition to the research facilities of the area. The company apparently has spared no effort or expense to provide excellent housing and equipment for the technical staff. The principal objectives of this research center appropriately will be the effective coordination and expansion of the research activities of Kennecott Js four western mining divisions. At the same time it is reasonable to assume that the university and the community will benefit greatly by having the research center and its staff in their midst. For further details of the laboratory see pages 29 A and 31 A

Separation of Platinum and Palladium and Their Subsequent Colorimetric Determination with p-Nitrosodimethylaniline J. H. Yoe and J. J. Kirkland

1 335

Spectrophotometric Study of p-Nitrosodimethylaniline as Sensitive Colorimetric Reagent for Platinum . . . J. J. Kirkland and J. H. Yoe

1 340

Colorimetric Determination of Zinc and Copper with 2-Carboxy-2'-hydroxy-5'-sulfoformaiylbenzene R. M. Rush and J. H. Yoe

1345

. .

Automatic Differential Potenti ο metric Titrator H. V . Malmstadt and E. R. Fett

1348

Automatic Recorder for Continuous Determination of Oxygen in Gases Using Dropping Mercury Electrode Τ. Β. Larchar, Sr., and Michael Czuha, Jr.

1351

Testing Cationic Surface Active Germicides for Use in Industrial Water Systems C. H. Bollenback and G. A. Cruickshank

1 355

Miniature Mixer Settler for Continuous Countercurrent Solvent Extraction H. W. Alter, J. W. Codding, and A. S. Jennings

1 357

Anodic Polarographîc Wave of Vanadium(IV) Aged in Alkaline Solution I. M. KolthoFf and P. T. Toren

1361

New Solvent System for Separation of Amino Acids by Paper Chromatography R. A . Clayton and F. M . Strong

1 362

Calculation of Integral Attenuation Index between 400 and 700 Millimicrons and of Corresponding Wave Length for Filtered Raw Sugar Solutions F. W. Zerban and Louis Sattler

1 363

Hydrolysis of Polysaccharides by Cation Exchange Resin and Identification of Monosaccharide Components by Paper Chromatography R. E. Glegg and David Eidinger

1 365

(Continued on page 4 A)