A N O T H E R ACETYLENE
DERIVATIVE
FROM
AI-.RCO
asssesfas^a «s«a.
H'CsCH
M e l t i n g Point — 8 8 . 5 - 8 9 ° C
DIMETHYL HEXANEDIOL
Boiling Point — 2 1 4 - 2 1 5 ° C
For A l k y l a t i o n — DIMETHYL HEXANEDIOL W i t h phenol, the product is
will
alkylate
many
aromatic
is f o r m e d by d e h y d r a t i o n . Diazoacetic ester reacts at one d o u b l e bond t o give the interesting substituted cyclopropane c a r b o x y l i c ester. The m e t h y l a l l y l c y c l o p e n t e n o n e ester of this acid is a l l e t h r i n .
rings.
For P o l y m e r s — The above diene a n d t h e 1,5 isomer are promising for c o p o l y m e r ization.
OH
CH„
For Direct U s e Few solid diols have been made a v a i l a b l e commercially. The high b o i l i n g point a n d g o o d t e m p e r a t u r e stability suggests the use of DIMETHYL HEXANEDIOL a s a component of lubricants, cutting oils a n d similar formulations, where high temperature properties a r e i m p o r t a n t . The d i t e r t i a r y structure gives i m p r o v e d surface activity.
CH.>
A l k y l a t i o n is accomplished using the diol or the dichloro Tetramethyltetrahydronapthalene derivatives have been t i g a t e d . Evaluation as antioxidants of aromatic h y d r o x y a l k y l a t e d with DIMETHYL HEXANEDIOL is p a r t i c u l a r l y
derivative. little invescompounds suggested.
DIMETHYL HEXANEDIOL is a v a i l a b l e in d r u m quantities at a price lower than for other solid s a t u r a t e d diols. Use the c o u p o n below t o o b t a i n the technical bulletin a n d a sample. O t h e r acetylene d e r i v a tives a v a i l a b l e f r o m A i r c o i n c l u d e DIMETHYL H E X Y N E D I O L , DIMETHYL O C T Y N E D I O L , METHYL BUTYNOL, METHYL PENTYNOL, METHYL ACETYLENE.
For Allethrin— DIMETHYL HEXANEDIOL is used industrially for the synthesis of the new insecticide, a l l e t h r i n . A diene CH.{ CH., I I CH.,—C:_CH—CH C—CH .
Air Reduction Chemical Company A Division of Air Reduction Company, Inc. 60 East 42nd Street, New York 17, N. Y.
AIRCO
Please send me the bulletin {] DIMETHYL HEXANEDIOL.
N O .
4 8 .
N O V E M B E R
3 0,
i
Company Address . . .
Represented I n t e r n a t i o n a l l y b y Airco C o m p a n y I n t e r n a t i o n a ! Divisions of Air Reduction C o m p a n y , I n c o r p o r a t e d 6 0 East 4 2 n d S t r e e t , N e w Y o r k 1 7 , N . Y . 3 1,
D of
Title .
Name
A I R REDUCTION CHEMICAL C O M P A N Y
V O L U M E
and a sample
1 9 5 3
City
. Zone . .
State
4975
