Appendix C

6; it will also be necessary to call the two carenes 3- ... 7 carbon atom; (2) the bridge in pinane is evi- ... cyclic terpenes resulting from the ope...
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Appendix C

Proposals on Consistent Numbering of Bicyclics and Menthane-Type Monocyclics Several reviewers of the June 1950 version of this report suggested, in the in­ terest of homogeneity, that: (1) the bicyclic fundamental parent structures should be numbered so that a return to the monocyclic forms would not change that number­ ing; (2) the actual or potential isopropyl group should always be attached to the No. 1 ring carbon in both the bicyclic structures and the menthane-type monocyclic structures. The American committees decided this was not feasible (see report proper). A summary of the specific proposals made by reviewers follows. 1. B y Georges Dupont Professor Dupont, in a letter of March 5, 1952, expressed the opinion that the numbering in going from bicyclics to monocyclics should be preserved as much as possible — for example, for the transformation pinene --> limonene, it would be useful to preserve the numbering. This would be obtained if α-pinene retained its classical formula (I) and if for limonene (II) the numbering corresponded to that re­ quired for menthene on the basis of the Chemical Abstracts alphabetic order of prec­ edence of the names of the substituents — i.e., isopropyl methyl — thus: