Aqueous Phase Organometallic Catalysis: Development and

Aqueous Phase Organometallic Catalysis: Development and Mechanism Brian J. Frost, Department of Chemistry, University of Nevada, Reno

Chiral Ligand Design:

Coordination Chemistry of PTA:

Inorg. Chem. 2006, 45, 6748-6755.

Inorg. Chem. 2007, 46, 7115-7120.

Inorg. Chem. submitted 2007.

Atom Transfer Radical Addition Reactions: Manuscript in preparation Styrene/CCl4 = 1:4 60° C 1 mol % cat 5 mol % AIBN toluene

N

N

N

N

N N

P P

H

Ru

H

P P N

N N

N

N N N

N N

P D2O

D

25 °C

D

P Ru P P

N N

N N

N

N N N N