Arsenic Removal with Composite Iron Matrix Filters in Bangladesh: A

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Arsenic Removal with Composite Iron Matrix Filters in Bangladesh: A Field and Laboratory Study Anke Neumann,*,†,§ Ralf Kaegi,† Andreas Voegelin,† Abul Hussam,‡ Abul K. M. Munir,∥ and Stephan J. Hug*,† †

Eawag, Swiss Federal Institute of Aquatic Science and Technology, Ueberlandstrasse 133, CH-8600 Duebendorf, Switzerland Center for Clean Water and Sustainable Technologies, George Mason University, Fairfax, Virginia 22030, United States ∥ Sono Technology and Research Inc., Courtpara, Kushtia, Bangladesh ‡

S Supporting Information *

ABSTRACT: The main arsenic mitigation measures in Bangladesh, wellswitching and deep tube wells, have reduced As exposure, but water treatment is important where As-free water is not available. Zero-valent iron (ZVI) based SONO household filters, developed in Bangladesh, remove As by corrosion of locally available inexpensive surplus iron and sand filtration in two buckets. We investigated As removal in SONO filters in the field and laboratory, covering a range of typical groundwater concentrations (in mg/L) of As (0.14−0.96), Fe (0−17), P (0−4.4), Ca (45−162), and Mn (0−2.8). Depending on influent Fe(II) concentrations, 20−80% As was removed in the top sand layer, but As removal to safe levels occurred in the ZVI-layer of the first bucket. Residual As, Fe, and Mn were removed after re-aeration in the sand of the second bucket. New and over 8-year-old filters removed As to 8 years >8.3 years 2 weeks−15 months/ >8 years 2 weeks−15 months/ >8 years 8−16 months/ >8 years 3 months 3 months

As (μg/L)

Mn (μg/L)

Fe (mg/L)

Ca (mg/L)

P (μg/L)

Cl (mg/L)

TOC (mg/L)

TN (mg/L)

385 152 394 423 172 135 428 963 873

2845 120 984 786 120 723 1773