Atom models according to Stuart - Analytical Chemistry (ACS

May 16, 2012 - Atom models according to Stuart. Anal. Chem. , 1956, 28 (11), pp 43A–43A. DOI: 10.1021/ac60119a746. Publication Date: November 1956...
3 downloads 0 Views 165KB Size
ATOM MODELS according to STUART AND BRIEGLEB ALANINE CHAIN

A t o m models according to S t u a r t a n d Briegleb give an exact picture of t h e actual spatial arrangement of a chemical compound. T h e models are spheres or ο voids with cut sur­ faces which can be joined together b y m e a n s of quick fas­ teners. Lateral surfaces are arranged in such a manner t h a t internuclear distances and effective radii of constructed molecules are reproduced in an enlargement of 1.5 χ 10 s with t h e correct valence angles and spatial arrangement. Carbon models, for example, have various shapes with differently arranged lateral surfaces depending upon t h e t y p e of bond. T h i r t y different structural units are presently available. Different colors are assigned to t h e various elements, which in­ clude hydrogen, carbon, oxygen, nitrogen, sulfur, phosphorus, silicon, fluorine, chlorine, bromine, and iodine. Hydrogen and halogen models are fitted with permanent quick fasteners. Other models are joined by quick snap-on fasteners. Sets include a small ejector tool for separating a t o m s a n d removing quick fasteners. Spring metal wedges are pressed into t h e slots of models used in double bonds to prevent rotation. T h e "hydrogen-bridge" is effected b y a new hook-and-eye arrangement t h a t enables larger angle shifts and permits t h e construction of strongly bound, hydrogenbridged molecules. S t u a r t and Briegleb molecular models are invaluable aids in studying three-dimensional arrangements of macro-

molecules, various types of steric effects, biochemical specific­ ity, geometrical and optical isomerism, tautomerism, reso­ nance, and other chemical phenomena. More detailed information is given in an 8-page, 3-color booklet. A 16-page booklet on the School Set of Atom Models is also available. Inquiries for kits to cover specialized needs are welcomed. Requirements for a single molecule for a given area of interest, such as peptides, sterols, or dyes, will be con­ sidered. No. AG302-80, I n i t i a l Set of 84 Pieces of 11 T y p e s of Atom Models, each $90.60 No. AC302-81, S u p p l e m e n t a r y Set of 40 Pieces of 13 Dif­ ferent Types, each $48.50 No. AC302-88, School Set of 44 Pieces of 9 Types of A t o m Models, each $43.50 A new data sheet. Molecules of Current Interest has just been published. It includes caffeine, cedrol, β-erythroidine, fulvalene, morphine, reserpine, san­ tonin, terrein, tetracycline, and trilobine. Alongside of the graphic formula of each molecule is listed the catalog numbers and prices of the components re­ quired to construct the model.

PARTICLE SIZE APPARATUS FOR SUB-SIEVE RANGE This instrument was designed to determine particle size within t h e range from 75 to 5 microns. However, if t h e top size is not greater t h a n 20 microns, the lower limit can ordinarily be ex­ tended to a b o u t 2 microns. T h e Gallenkamp particle size a p p a r a t u s is self-contained and comprises a sedimentation system, a receiving tank, and a direct-reading torsion balance—all mounted on a levelling stand. A powder of t h e material being measured is uniformly dispersed in a suitable liquid, a n d the particles are allowed to settle on the pan of a special torsion balance. T h e pan is suspended in clear liquid, and the weight indicated by t h e balance is not affected b y changes in density of t h e suspension. Because it is not necessary to extract, dry, and weigh the settled powder, no " b l a n k s " are required, and higher concentrations of dispersing agents can be used without applying correc­ tion factors. T h e time required to estimate size distribution of any powder is little longer t h a n the t i m e of sedimentation. T h e balance is sufficiently sensitive to permit t h e use of a very low concentration of solids, so t h a t sedimentation can take place under practically free-falling conditions. Another ad­ v a n t a g e is t h a t interference with t h e settling particles is negligible. Write for Descriptive

Literature.

No. AC368-51, G a l l e n k a m p P a r t i c l e Size D e t e r m i n a t i o n A p p a r a t u s , c o m p l e t e w i t h glassB, l e a d s for c o n n e c t i n g t o a 6-volt s u p p l y , a n d i n s t r u c t i o n s , e a c h $850.00

ARTHUR S. LaPINE and COMPANY

LAPINE

LABORATORY SUPPLIES ·

6001 SOUTH KNOX AVENUE CHICAGO 29. ILLINOIS. U.S.A.

EQUIPMENT · REAGENT AND INDUSTRIAL CHEMICALS

For further information, circle numbers 43A-1, 43 A-2, 43 A-3 43 A-4, 43 A-5 on Readers' Service Card, page 79 A

VOLUME

2 8, N O .

11, N O V E M B E R

1956

43 A