Atom Shaking Shows Structure - C&EN Global Enterprise (ACS

Nov 6, 2010 - NUCLEAR magnetic resonance continues to broaden its usefulness as a research tool. The latest variation is called NMR acoustic absorptio...
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RESEARCH 20 million times a second ~\v*»ll 1K»\OIU1 the limit of h u m a n hearing. They use a vibrating quartz crystal bonded to the crystal being studied. T h e acoustic absorption work at Westinghouse* was planned t o v e n h a theory b y Krench unci Russian researchers which predicted acoustic resonance nuclei. At the time. Westinghouse dkl not intend to develop a new technique lor crystal studies.

This model shows how nuclear magnetic resonance acoustic absorption works. T h e large coil generates a magnetic field around the small compasses—those on hlack tapes vibrate back and forth, compasses in between stand still. Vibration corresponds to the relative motion between nuclei caused by acoustic vibra­ tion of the crystal. T h e moving needles create a fluctuating magnetic field, causing resonance when the acoustic vibration settles on the right frequency

Atom Shaking Shows Structure Newly developed method extends use of nuclear magnetic resonance to metals and semiconductors NT iCLKvit magnetic resonance contin­ ues to broaden its usefulness as a re­ search tool. The latest variation is called Ν MR acoustic absorption. De­ veloped at Westinghouse, NMRAA probes the internal structure of crystal­ line materials by shaking atoms back and forth u p to 20 million times a sec­ ond. Westinghouse physicists believe the method is a major advance in studies of crystalline matter. They saxit opens a new field of research since it allows them to study crystals not studied before—particularly crystals of metals and semiconductor materials. Atomic nuclei resemble tiny spinning magnets. Such magnets have north a n d south poles which tend to line up parallel with one another when placed in a magnetic field. When these nuclei are shaken, enough energy is created to upset magnetic balance. XMR will detect this imbalance and show the in­ teraction between atomic nuclei and the electrons which swarm around them. • Differs from Straight NMR. West­ inghouse physicists D. I. Bolef and Meir Menés explain the difference between X\1R acoustic absorption and conventional XMR this way: A steady mag42

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m tic field will align nuclear magnets. But in so doing, the nuclear magnets start to wobble, or precess, somewhat the same way that a compass needle will oscillate when first placed in a strong magnetic field. In conventional XMR. a second magnetic field—pulsating instead of s t e a d y is applied at right angles to the steady field and the frequency is adjusted until it matches exactly the rate at which the nuclear magnets wobble. So adjusted, the nuclear magnets will absorb energy. This provides electrical signals to determine the internal structure of the material under question. However, Bolef and Menés point out this method does not work for crystal studies of metals and semiconductors. The pulsating magnetic field cannot penetrate such materials. But if a crystal is vibrated rapidly, magnetic and electrical fields are created which interact with nuclei. When the motion matches exactly· the frequency of wobble, the nuclei will behave exactly as they do when a pulsating external magnetic field is applied. Westinghouse creates nuclear shaking with sound waves that vibrate u p to

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