Base-Promoted Ammonia Borane Hydrogen-Release - American

May 5, 2010 - Martin E. Bluhm, Patrick J. Carroll, and Larry G. Sneddon*. Supporting Information. The Cartesian coordinates in the supplemental tables...
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Base-Promoted Ammonia Borane Hydrogen-Release [J. Am. Chem. Soc. 2009, 131, 14101–14110]. Daniel W. Himmelberger, Chang Won Yoon, Martin E. Bluhm, Patrick J. Carroll, and Larry G. Sneddon* Supporting Information. The Cartesian coordinates in the supplemental tables for the optimized geometries of model anionic polymers shown in Figure 2S were entered incorrectly. The supplemental tables in the corrected Supporting Information now have coordinates that correspond to the structures in Figure 2S and likewise now correctly correspond to the structures discussed in the article text on page 14110. Supporting Information Available: Diagram of the Toepler pump apparatus used for some H2-release measurements; tables listing the Cartesian coordinates for all DFT-optimized geometries (corrected); X-ray crystallographic data for the structure determination of [Et3BNH2BH3]-K+ · 18-crown-6 (CIF); complete ref 36. This material is available free of charge via the Internet at http://pubs.acs.org. JA103189E 10.1021/ja103189e Published on Web 05/05/2010

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10.1021/ja103189e  2010 American Chemical Society