Basics and intermediates - C&EN Global Enterprise (ACS Publications)

Basics and intermediates. Chem. Eng. News , 1971, 49 (36), pp 12A–14A ... Tools & Sharing. Add to Favorites · Download Citation · Email a Colleague...
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Basics and intermediates SULFUR

PETROLEUM

Thousands of long tons

1960

1968

1969

1970

1971a

Millions of barrels

1960

1968

1969

1970

1971a

Production, native Production, recovered Shipments, native Imports

4943 769 5003 741

7458 1359 6648 1571

7146 1422 6551 1674

7082 1457 6419 1537

6900 1550 6700 1300

Production Crude oil Natural gas liquids

2575 340

3330 550

3372 580

3516 613

3620 620

Petroleum products output Gasoline 1510 Kerosine and jet fuel 224 Distillate fuel oil 667 Residual fuel oil 332 Lubricants 59

1940 417 841 276 66

2028 425 848 266 65

2105 398 897 258 66

2210 396 920 296 68

a C&EN estimates.

Source: Bureau of Mines

BITUMINOUS COAL Millions of short tons

Production Exports Consumption Electric utilities Industrial (including coke) Coke Retail a Preliminary.

1960

1968

1969

1970

415.5 36.5

545.2 50.6

560.5 56.2

602a 70.9

173.9

294.7

308.5

320.5

173.1 81.0 30.4

188.5 90.8 15.2

185.8 92.9 12.7

186.2 95.9 10.1

1969

1970

SALT Thousands of short tons

1960

1968

25,479 1,057 420

41,274 3,456 728

44,245 3,302 716

a

45,804 3,536a 423a

a Preliminary. Source: Bureau of Mines POTASH Thousands of short tons

1960

1968

1969

1970

Production, marketable Imports Exports

4472 415 833

4769 3658 1336

4918 3978 1259

4853 4418 1047

Source: Bureau of Mines PHOSPHATE ROCK

I960

1968

1969

1970

19,618 144 4,473

41,251 116 12,099

37,725 140 11,336

38,739 136 10,895

Thousands of short tons

Production, marketable Imports Exports Source: Bureau of Mines

NATURAL GAS Billions of ft*

I960

1968

1969

1970

Marketed production 12,771 19,322 20,698 21,921 398.2 95.5 116.9 Net stored underground 131.7 Imports 156 652 727 821 Consumption 4,837 3,101 4,450 4,728 Residential 2,057 1,801 1,955 1,020 Commercial 7,899 7,134 7,612 Industrial na 3,894 3,144 3,486 Electric utilities 1,725 na = not available

Source: Bureau of Mines

12A C&EN SEPT. 6, 1971

Source: Bureau of Mines

PRODUCTION OF ORGANIC INTERMEDIATES

Source: Bureau of Mines

Production Imports Exports

a C&EN estimates.

Annual change, Millions of pounds, unless otherwise noted

% 1960

1968

1969

1970*

1096 1664 1675 1700b 761 1361 1518 1598 229 1021 1157 1037 120 263 334 372

Acetic anhydride Acetone Acrylonitrile Aniline Benzene, millions of gallons 1,3-Butadiene Carbon disulfide Carbon tetrachloride Cyclohexane Dioctyl phthalates Dodecylbenzene Ethanol, synthetic Ethanolamines: mono, di, tri Ethylene

126 224 255 265 5448 13151 16436 18000b

Ethylene oxide Formaldehyde, 37% Maleic anhydride Methanol, synthetic Naphthalene

1475 2625 3408 3671 1872 4305 4398 4312 90 182 201 216 1966 3817 4206 4945 510 902 854 711

Perchloroethylene Phenol, synthetic Phthalic anhydride Propylene Propylene oxide

209 636 635 702 773 1513 1691 1710 401 744 760 714 2477 7025 7235 7200b 309. 958 1177 1121

457 1000 1185 1166 1883 2929 3123 3054 372 763 883 1011 564 2039 2232 1817 170 440 438 419 492 758 529 533 1695 2127 2361 2400b

1745 Styrene na TEL (tetraethyllead) TML (tetramethyllead) na Toluene, millions of gallons 274 Urea, total, 100% 1469 Vinyl acetate 251 Vinyl chloride 1037 Xylenes, millions of gallons p-xylene 139 o-xylene 210

3698 4648 4353 485 371 na

76

I96070

196970

1% 4% 5 8 16 -10 11 12

10 5

-2

11 12 9 1 4

14 -19 -4

8 13 10 9 9 10 3 13 8 6 11 14 10 na

4 10

-2

1 2

8 -2 7 18 -17 11 1 -6 0 -5 -6 na

na na

na -9

4871 5944 6430 718 729 799 2969 3736 4040

10 16 12 15

944 850 825 1316 1628 1588

19 23

-3 -2

116 695

759 694

a Preliminary figures, b C&EN estimates. Sources: Department of Commerce; Tariff Commission

8 10

PRODUCTION OF INORGANIC INTERMEDIATES Thousands of tons, unless otherwise noted

Acids Hydrochloric acid, 100% Hydrofluoric acid, total 100% Nitric acid, 100% Phosphoric acid, 100%, P 2 0 5 Sulfuric acid, 100% H2S(X millions of tons Chlorine and alkalies Chlorine, total Potassium hydroxide, 88 to 92% KOH Sodium carbonate Synthetic, 58% Na 2 0 Natural, 58% Na 2 0 Sodium hydroxide Total, 100% Dry Industrial gases Acetylene, billions of ft3 Argon, millions of ft3 Carbon dioxide Solid Liquid and gas Hydrogen High purity, billions of ft3 Lower purity, billions of ft8 Nitrogen, high purity, billion of ft3 Oxygen High purity, 99.5% Lower purity, 95% Inorganic fertilizer materials Ammonia, synthetic, anhydrous, 100% Ammonium nitrate, original solution Ammonium sulfate Synthetic and by-product Coke oven Other chemicals Aluminum chloride, anhydrous 100% Aluminum sulfate, commercial, 17%, A1203 Calcium carbide, commercial Calcium phosphate dibasic, anhydride 100% Carbon, activated Hydrogen peroxide, 100% by wt. Phosphorus, elemental, white, yellow, red Phosphorus, oxychloride 100% Phosphorus pentasulfide, 100% Potassium pyrophosphate, anhydrous 100% Sodium bichromate and chromate, hydrous Sodium chlorate, 100% NaC103 Sodium phosphate, tripoly 100% Sodium silicate, liquid and solid, anhydrous Sodium sulfate, total high and low purity Titanium dioxide a Preliminary figure,

b Excludes captive production In refineries.

1960

Annual change, % 1960-70 1960-70

1968

1969

1970^

970 118

1,748

1,911

1,918

302

327

317

3,315 2,087 17,883

6,362 5,268 28,544

6,443 5,373 29,537

6,460 5,471 29,146

4,637

8,444

9,414

9,755

103

179

177

175

8 5

4 -1

4,558

790

4,596 2,043

4,540 2,495

4,414 2,678

0 13

-3 7

4,972

8,868

9,917

10,074

545

545

457

488

7 -1

2 7

12,143

570

15,071 2,114

14,386 2,597

14,382 2,972

3 18

0 14

470 428

374 684

369 700

333 787

-3 6

-10 12

13,278 51,958 18,566

34,699 167,053 118,731

31,939 33,151b 130,956

28,407 30,193' 146,547

8 -5 23

-11 -9 12

2,400 1,479

10,264 2,174

11,428 2,055

11,564 1,505

17 0

1 -27

4,818 3,122

12,120 5,737

12,918 5,891

13,098 6,185

11 7

1 4

859 632

2,002

1,916

1,898

721

648

595

36

40

32

1,179

1,244

1,177

942 416 85 65 613 34 52 49 146 167

856 496 86 55 629 31 56 41 153 187

770 na 82 58 597 33 62 39 150 198

1,177

1,215

1,190

633

657

612

1,073

1,483

1,483

1,362

456

623

660

655

24 879 1,093

235 60 30 409 24 na 26 122 92 690 497

7% 10 7 10 5

0% -3 0 2 -1

-1

3 3 -3 na 3 7 4 3 na 4 2 8 6 2 2 4

-20 -5 -10 na -5 5 -5 6 11 -5 -2 6 -2 -7 -8 -1

na = not available. Sources: Departnnent of Connmerce; Tariff Commission SEPT. 6, 1971 C&HN 13A

BASICS AND INTERMEDIATES, continued PRODUCTION OF TOP 50 CHEMICALS Rank 1970

Sulfuric acid, total Ammonia, synthetic anhydrous Oxygen, high and low purity Sodium hydroxide, 100%, liquid Chlorine, gas 6 7 8 9 10

Ethylene Sodium carbonate, synthetic, natural Nitric acid, total Ammonium nitrate, original solution Phosphoric acid, total

11 12 13 14 15

1960

35.8

9.6 7.9 9.9 9.3

Billions of pounds 1968 1969

19691970"

70

Annual change, 1965-

70

3°b 8 7 8 8

% I960

70

49.7 17.7 18.6 13.7 13.0

59.1 25.4 26.0 19.2 18.8

58.3 26.2 26.1 20.2 19.5

-1% 1 0 5 4

18.0 14.0 12.9 12.4 10.9

9 0 0 5 2

13 2 6 6 7

10

5° i

11 13 T

8

5.4

9.6

10.8

12.8

6.6 6.2 4.2

9.8 9.3 7.8

16.4 14.1 12.9 11.8 10.7

Nitrogen, high purity Benzene b Propylene Ethylene dichloride Urea, primary solution

1.3 3.3 2.5 1.3 1.5

5.3 6.1 3.7 2.5 2.8

9.5 8.7 7.2 6.0 5.4

10.6

8.5 8.0 6.5 6.4

12 -2 0 8 19

15 7 14 18 18

2; 10 11 17 16

16 17 18 19 20

Polyethylene, high, low density Tolueneb Ammonium sulfate Methanol, synthetic Ethylbenzene

1.3 2.0 3.0 2.0 1.7

3.0 4.0 5.3 2.9 3.0

5.5 5.5 5.1 4.1 4.8

5.9 5.0 5.0 4.9 4.6

7 -9 -3 19 -5

14 5 -1 12 9

10 5 10 Id

21 22 23 24 25

Styrene Formaldehyde Vinyl chloride Hydrochloric acid, total Ethylene oxide

1.7 1.9 1.0 1.9 1.5

2.9 3.1 2.0 2.7 2.2

4.6 4.2 3.7 3.8 3.2

4.4 4.3 4.0 3.8 3.7

-5 3 8 0 15

9 7 15 7 11

26 27 28 29 30

Xylene, total b 1,3-Butadiene, rubber grade Polyvinyl chloride, copolymers Carbon black Sodium sulfate, high, low purity

2.0 1.9 1.2 2.1 2.2

2.5 2.7 1.8 2.4 2.8

2.8 3.1 3.0 3.0 3.0

3.3 3.1 3.1 2.9 2.7

19 -2 3 -2 -8

6 3 11 4 0

31 32 33 34 35

Ethylene glycol Aluminum sulfate, commercial Calcium chloride, solid, liquid Sodium tripolyphosphate Polystyrene, straight, rubber-modified

1.3 1.8 1.5 1.4 0.7

1.8 2.1 2.3 1.8 1.4

2.4 2.5 2.3 2.4 2.2

2.5 2.4 2.4 2.4 2.3

5 -5 3 -2 3

7 2 1 4 11

36 37 38 39 40

Carbon dioxide, all forms Ethanol, synthetic Isopropanol Acetic acid Cumene

1.9 1.7 1.2 0.7 0.2

2.2 2.0 1.5 1.3 0.7

2.1 2.1 2.1 1.9 1.6

2.2 2.2 2.1 2.0 1.8

5 3 0 5 4

1 2 7 9 22

41 42 43 44 45

Cyclohexane Phenol, total Acetaldehyde Acetic anhydride Dimethyl terephthalate

0.6 0.8 na 1.1 na

1.7 1.2 1.2 1.5 0.5

2.2 1.7 1.7 1.7 1.5

1.8 1.8 1.7 1.7 1.7

-17 3 2 0 10

1 7 7 3 25

12

46 47 48 49 50

Acetone Calcium carbide Titanium dioxide Sodium silicate Phosphorus, white, red

0.8 2.2 0.9 1.0 0.8

1.1 2.2 1.2 1.2 1.1

1.5 1.7 1.3 1.3 1.3

1.6 1.5 1.3 1.2 1.2

6 -10 -1 -7 -5

7 -7 3 1 1

8 _^ 4

a Preliminary figures, b Includes small amount of production from tar distillation, na = not available. 14A C&EN SEPT. 6, 1971

13 3 7 *7

If?

10 0

15 " 10 -; 5 }v

^ :

7 2

~ 0

13 -) _-) h

li 23

0

na 4 na

0

4

Sources: Department of Commerce; Tariff Commission; Department of Interior; Industry; C&EN estimates