Article pubs.acs.org/EF
Catalytic Hydroprocessing of Fast Pyrolysis Bio-oil from Pine Sawdust Douglas C. Elliott,*,† Todd R. Hart,† Gary G. Neuenschwander,† Leslie J. Rotness,† Mariefel V. Olarte,† Alan H. Zacher,† and Yrjö Solantausta‡ †
Pacific Northwest National Laboratory, Richland, Washington 99354, United States Technical Research Center of Finland (VTT), 02044 Espoo, Finland
‡
ABSTRACT: Catalytic hydroprocessing has been applied to the fast pyrolysis liquid product (bio-oil) from softwood biomass in a bench-scale continuous-flow fixed-bed reactor system. The intent of the research was to develop process technology to convert the bio-oil into a petroleum refinery feedstock to supplement fossil energy resources and to displace imported feedstock. This paper is focused on the process experimentation and product analysis. A range of operating parameters, including temperature from 170 or 250 to 400 °C in the two-stage reactor and flow rate of 0.19 liquid hourly space velocity, was tested with bio-oil derived from pine wood. Times on stream of up to 90 h were evaluated, and losses of catalyst activity were assessed. Product yields of 0.35−0.45 g of oil product/g of dry bio-oil feed with hydrogen consumptions from 342 to 669 L/L of bio-oil feed were measured. Analyses determined that product oils with densities of 0.82−0.92 g/mL had oxygen contents of 0.2−2.7 wt % and total acid number (TAN) of
