Charge Transport Limitations in Perovskite Solar ... - ACS Publications

Oct 11, 2017 - electron and hole transport layers, we identify the charge extraction layers and ..... School of Electrical and Electronic Engineering,...
0 downloads 0 Views 2MB Size
Subscriber access provided by LAURENTIAN UNIV

Article

Charge transport limitations in perovskite solar cells: The effect of charge extraction layers Irene Grill, Meltem Fatma Aygüler, Thomas Bein, Pablo Docampo, Nicolai F. Hartmann, Matthias Handloser, and Achim Hartschuh ACS Appl. Mater. Interfaces, Just Accepted Manuscript • DOI: 10.1021/acsami.7b09567 • Publication Date (Web): 11 Oct 2017 Downloaded from http://pubs.acs.org on October 12, 2017

Just Accepted “Just Accepted” manuscripts have been peer-reviewed and accepted for publication. They are posted online prior to technical editing, formatting for publication and author proofing. The American Chemical Society provides “Just Accepted” as a free service to the research community to expedite the dissemination of scientific material as soon as possible after acceptance. “Just Accepted” manuscripts appear in full in PDF format accompanied by an HTML abstract. “Just Accepted” manuscripts have been fully peer reviewed, but should not be considered the official version of record. They are accessible to all readers and citable by the Digital Object Identifier (DOI®). “Just Accepted” is an optional service offered to authors. Therefore, the “Just Accepted” Web site may not include all articles that will be published in the journal. After a manuscript is technically edited and formatted, it will be removed from the “Just Accepted” Web site and published as an ASAP article. Note that technical editing may introduce minor changes to the manuscript text and/or graphics which could affect content, and all legal disclaimers and ethical guidelines that apply to the journal pertain. ACS cannot be held responsible for errors or consequences arising from the use of information contained in these “Just Accepted” manuscripts.

ACS Applied Materials & Interfaces is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Published by American Chemical Society. Copyright © American Chemical Society. However, no copyright claim is made to original U.S. Government works, or works produced by employees of any Commonwealth realm Crown government in the course of their duties.

Page 1 of 22

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

                     †

 



  

 



  



 

†¶



  

†‡

    



∗†

                 ! "# $%& '%&((    )*   +      +       !   # , '-(..    ) ‡  /   0   0   0       1  0% (2    3   4   ¶  / 3563+ 7 6    7)      %. '8%99 )! : †

        

                                                                                 333 !"#   $                      $ %   & '  (  $      ) 2 *+       !"   $(       ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

                      '                      (    (                                  ,                      

                           

       

             !

           "                   



 #

     $   !

        %          #      

$               # #       "     & '    !       #         $    ()   % *     $            



  ! $! !   $   !!

       

       !+ *,            +x         %



 #            !

          %   !+ *, $      #      -  $           

;
.&/  *%J ,   %J    % %J ,  %J )   I% %J   % %J  % %J    ;%J 4  %J ,   %J   ,%J   C% %J    $  !  $ 3 73 .(3−x 4x /3 #  +  4  %

# #

;# 6 #

 $ & !&< %


!

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 16 of 22

.=/ L  %J 

 %!M%J N  7   %J 7  4%J    %J 7  %J 4 M%J K M%!%J , D $ %J 4$ %J +!(    !

 2     !        %

6 #

6 # # #

 %( 1 G! 1&G%

.
 

 &,$ 8% . @/   %J   M% %J 4  % C% %J +AC  4% %J D  *%J (  %%J (        (         % ?=G?% ?

ACS Paragon Plus Environment

# #

 9

ACS Applied Materials & Interfaces

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 18 of 22

. G/   D%J   7%J   %J P  % %J 76  % I%J )R6  %J ;    C ,  

;G!&1 G% &>

ACS Paragon Plus Environment

Page 21 of 22

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

.= /   )%J I %J   %J 7   %J (  %J (  %J ;  %J * "         $  + $           %

;# 6   

 &-( @G !@G?%

&

ACS Paragon Plus Environment

ACS Applied Materials & Interfaces

"# $%   1.8 Ubias = 2 V

170 nm spiro-OMeTAD

370 nm

740 nm

perovskite TiO2 FTO 500 nm

500 nm

500 nm

increasing thickness of spiro-OMeTAD layer

Transit time (µs)

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 22 of 22

1.6 1.4 1.2 1.0 exp. data lin. regression

0.8 0.6 100

200 300

400

500

600

700

Thickness of spiro-OMeTAD layer (nm)

&&

ACS Paragon Plus Environment

800