Chemical evidence for main-chain scission as a major decomposition

WARREN M. GARRISON , MICHAEL E. JAYKO , MICHAEL A. J. RODGERS , HARVEY A. SOKOL , and WINIFRED BENNETT-CORNIEA. 1968,384-396...
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phase reported for HCl and HBr,” but probably not the major portion. Aclcnouiledgment. We wish to thank Professor David A. Dows for a helpful discussion of the reflectance mirror system. Acknowledgment is made to the donors of The Petroleum Research Fund, administered by the American Chemical Society, for support of this research. (11) H. B. Friedrich and W. B. Person, J. Chem. Phya., 39, 811 (1963).

DEPARTMENT OF CHEMISTRY UNIVERSITY OF REDLANDS REDLANDS, CALIFORNIA92373

radation of acetylalanine cannot be represented simply in terms of the rearrangement H

RCONHCH(CH3)R

RCONHz

I + C-R

(1)

II

CH2 since we find G(acry1ic acid) that the N, 0 shift