CHP unique solvet - C&EN Global Enterprise (ACS Publications)

DOI: 10.1021/cen-v059n050.obc. Publication Date: December 14, 1981. Copyright © 1981 AMERICAN CHEMICAL SOCIETY. ACS Chem. Eng. News Archives...
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CHP unique solvent

Here's a reaction solvent with a difference—and it's a difference that can save you money by saving energy and processing steps. Below50°C, CHP" N-cyclohexyl2-pyrrolidone is miscible in water at all concentrations. At higher temperatures, the miscibility is a function of concentration. For instance, a 25% concentration of CHP sol vent in water is not miscible at temperatures above 50°C; a 10% concentration is not miscible at temperatures above 60°C. (See Figure 1.) Figure 2 shows the effect of adding 2% NaCI to the mixture: it g Two-Phaee increases the range of tern- ï peratures and concentraI tions where CHP solvent I is immiscible with water. Ont P h — This means you can create a 2-phase system— 30 or an "insolubility zone"CHP° « /obyWe(ght » simply by adjusting the Figure 1. The effect of temperature on solubility of CHP in water.

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temperature or adding salts. And that's an energy saver, because it lets you separate water from a system without distillation. Moreover CHP N-cyclohexyl-2pyrrolidone is an excellent solvent for a wide range of hydrocarbons, polar compounds and polymers. And its high boiling point (284°C at 760 mm) gives it a distinct advantage over such conventional solvents as DMF- DMAC, DMSO, THF; acetonithle and sulfolane. Information and free samples. CHP solvent is available TWo-Phaee in commercial quantities for immediate delivery. Call (212) 621-5900 or write to GAF Corporation, Commercial Development OfM-PttM· , Department, 90 140 West 51st Street, New York, N.Y 10020. Figure 2. The effect of temperature on solubility of CHP in 2.0% NaCI solution.

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