Cleavage of a phosphorus-carbon double bond ... - ACS Publications

Alan H. Cowley, Bruno Pellerin, Jerry L. Atwood, and Simon G. Bott. J. Am. Chem. Soc. , 1990, 112 (18), pp 6734–6735. DOI: 10.1021/ja00174a056. Publ...
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J. Am. Chem. SOC.1990, 112, 6134-6135

6134

Table I. Crystallographically Observed Torsion Angles for Tetrathioethers 1-3 and for Their Ni(I1) Complexes' 1 +Ni 2 +Ni 3 +Ni S( I)-C(Z)-C(3)-S(4) -176 -61 58 -58 71 -60 c(2)-W)-S(4)-(25) -60 159 162 155 75 156 C(3)-S(4)-C(5)-C(6) - 6 2 -175 165 -178 -161 -178 S( 4)-C( 5)-C( 6)-C( 7) 178 71 -65 67 59 69 -60 -68 59 -69 C(5)-C(6)-C(7)-S(8) 177 -72 C(6)-C(7)-S(8)