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May 22, 2012 - COLE-PARMER INSTRUMENT and EQUIPMENT CO. Anal. Chem. , 1968, 40 (3), pp 32A–32A. DOI: 10.1021/ac60259a724. Publication Date: ...
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REPORT FOR ANALYTICAL CHEMISTS

were reported generally favorable for most of the techniques. Gravimetry standards in organic chem­ icals for the concentration of 0.01 % and greater received unanimous ap­ proval. With respect to inorganic chemicals, approximately 85% re­ ported favorably ; a somewhat lower favorable percentage was noted for metals and alloys. Availability. For metals and alloys, about 60% of the reports were favorable over the entire con­ centration range, somewhat slightly less favorable with respect to in­ organic chemicals. For organic chemicals, the availability was re­ ported favorable in roughly 75% of the cases. Accuracy. In both organic chem­ icals and metals and alloys, the percentage of favorable replies was about 80 to 85%. Unanimous sat­ isfaction was noted for organic chemicals. Cost. In the three major cate­ gories of application, metals and alloys, inorganic chemicals, and or­ ganic chemicals, not a single un­ favorable reply was received con­ cerning the cost of standard refer­ ence materials. Indeed, this state­ ment applies to all reports received —all laboratories were satisfied as to cost. Summary. Since standards for gravimetric analysis have probably received attention over a longer period of time than for any other technique, it is not surprising that the standard reference materials status is in such excellent condition. Perhaps current attention with re­ spect to gravimetry standards should be directed toward metals and alloy analysis. The signifi­ cantly large number of replies in­ dicating usage of gravimetry is indicative of the high reliability of standards for this technique. INFRARED SPECTROMETRY

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INSTRUMENT and EQUIPMENT CO. 7330 North Clark Street Chicago. III. 60626 (AC 312) 3380420 Circle No. 24 on Readers' Service Card

32 A



ANALYTICAL CHEMISTRY

General Suitability. Approxi­ mately 75% of the replies for inor­ ganic chemicals over the entire con­ centration range were favorable. A somewhat smaller percentage of favorable replies was reported in organic chemicals. This decline was due primarily to only 56% fa­

vorable replies for the concentration range of 1-10 ppm. Standard refer­ ence materials for water analysis received high marks, particularly for the range of 1000 ppm and lower including the concentration range of < 1 ppm. Standards in petro­ leum analysis, however, were less satisfactory—about 60% favorable replies. For pharmaceuticals, in the concentration range of 10100%, 86% reported favorably. For metals and alloys, only about 50% of the replies were favorable over the entire concentration range. Availability. For most catego­ ries, there appears to be a need for improved availability of standards. This is demonstrated in particular for water analysis where only ap­ proximately 20% of the laborato­ ries reported adequate availability of standards. A somewhat larger percentage was noted for metals and alloys; an even larger percent­ age for organic and inorganic chem­ icals but only in rare cases did the percentage of favorable replies ap­ proach 70%. Accuracy. In most categories, the accuracy of standards for infrared spectrometry was reported unani­ mously as satisfactory. Notable exceptions, however, were found in organic chemicals—about 70%— and in pharmaceuticals where 67% reported favorably. Cost. Most of the replies with respect to cost were favorable, but not unanimous. About 85%, for example, of the replies for inorganic chemicals were favorable. The most striking example of dissatis­ faction was observed in water anal­ ysis where considerably less than 50% of the replies were favorable, particularly at the 10 ppm or lower concentration range. Summary. The number of lab­ oratories reporting usage of infra­ red spectrometry was quite large. In general, the suitability of stan­ dards appears to be rather good, but a considerable disapproval was evi­ denced with respect to availability and cost of standards in specific ap­ plications. Since these applications come in areas where infrared spec­ trometry is the widely used and im­ portant technique, the need for im­ proved standards is evident.