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Figure 14.6 - Schematic of bolaform self assembly in solution. Figure 14.7 - X-ray crystal structures of compounds 3d (major and minor diastereomers) ...
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Downloaded by ST ANDREWS UNIV LIB on July 25, 2013 | http://pubs.acs.org Publication Date (Web): December 20, 2009 | doi: 10.1021/bk-2009-1017.ap001

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Figure 4.3. Aqueous suspensions of (A) cellulose nanocrystals (0.8 wt %) and (B) FITC-labeled cellulose nanocrystals (0.5 wt %). (Reprinted with permission from ref 12. Copyright 2007 American Chemical Society)

a)

b)

Figure 6.10. O2-saturated β-D-glucose/2,2'-azino-bis(3-ethylbenzthiazoline-6sulphonic acid) solution containing horse radish peroxidase before (a) and 1 min after (b) the addition of glucose oxidase capsules

In Polysaccharide Materials: Performance by Design; Edgar, K., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010.

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Downloaded by ST ANDREWS UNIV LIB on July 25, 2013 | http://pubs.acs.org Publication Date (Web): December 20, 2009 | doi: 10.1021/bk-2009-1017.ap001

H-bonding dominant

Bolas in solution Hydrophobic interaction dominant

Figure 14.6 - Schematic of bolaform self assembly in solution

Figure 14.7 - X-ray crystal structures of compounds 3d (major and minor diastereomers) and 3e.

In Polysaccharide Materials: Performance by Design; Edgar, K., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010.

Downloaded by ST ANDREWS UNIV LIB on July 25, 2013 | http://pubs.acs.org Publication Date (Web): December 20, 2009 | doi: 10.1021/bk-2009-1017.ap001

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Figure 14.8 - Comparative X-ray structures of glycal bolaforms 3d and 3e with similar carbohydrate bolaforms

In Polysaccharide Materials: Performance by Design; Edgar, K., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010.

Downloaded by ST ANDREWS UNIV LIB on July 25, 2013 | http://pubs.acs.org Publication Date (Web): December 20, 2009 | doi: 10.1021/bk-2009-1017.ap001

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Figure 15.3. 600 MHz 1H HR-MAS NMR spectra of WT (D), GH9C1-1 (C), GH9C3-1 (B), and GH9C2-2 (A) Arabidopsis thaliana root tissues scaled by carbohydrate region intensities. Arrows indicate significant differences in peak intensities in the acetate region of the spectra.

In Polysaccharide Materials: Performance by Design; Edgar, K., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010.