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Figure 8.2. a) Injection molded samples of BPA-PC (top) and DOD-co-PC. (bottom) shown under polarized light, b) Effect of boiling-water immersion on. ...
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Downloaded by 80.82.77.83 on January 18, 2018 | http://pubs.acs.org Publication Date: March 8, 2005 | doi: 10.1021/bk-2005-0898.ap001

Figure 8.2. a) Injection molded samples of BPA-PC (top) and DOD-co-PC (bottom) shown under polarized light, b) Effect of boiling-water immersion on BPA-PC and DOD-co-PC.

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Figure 83. C-NMR of Aromatic CH Groups ofDOD-BPA-copolycarbonates with 12.6 and 30 mole % of DOD (a and b, respectively)

Brunelle and Korn; Advances in Polycarbonates ACS Symposium Series; American Chemical Society: Washington, DC, 2005.

Downloaded by 80.82.77.83 on January 18, 2018 | http://pubs.acs.org Publication Date: March 8, 2005 | doi: 10.1021/bk-2005-0898.ap001

Figure 8.5. a) XRD Spectra measurements ofDOD-BPA-copolycarbonates b) Radial Distribution Function ofDOD-co-PC.

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Figure 8.6. AFM phase contrast images of différent compounds. Scan size: 1 μη?. Brunelle and Korn; Advances in Polycarbonates ACS Symposium Series; American Chemical Society: Washington, DC, 2005.

Downloaded by 80.82.77.83 on January 18, 2018 | http://pubs.acs.org Publication Date: March 8, 2005 | doi: 10.1021/bk-2005-0898.ap001

Figure 8.7. a) AFM phase contrast images of the BPA-PC and the 40 mol% DOD-co-PC

Figure 8.8. GPC chromatogram of DOD-BPA copolycarbonates a) RI-detection b) LS-detection. c) GPC chromatogram, chemical composition (NMR) as a function of molecular weight. Brunelle and Korn; Advances in Polycarbonates ACS Symposium Series; American Chemical Society: Washington, DC, 2005.

Downloaded by 80.82.77.83 on January 18, 2018 | http://pubs.acs.org Publication Date: March 8, 2005 | doi: 10.1021/bk-2005-0898.ap001

Figure 9.1. a) 3-Point-Bending-Module

Figure 9.2. Light microscopy ofBPA-PC in 3-point-bending-test.

Brunelle and Korn; Advances in Polycarbonates ACS Symposium Series; American Chemical Society: Washington, DC, 2005.

Downloaded by 80.82.77.83 on January 18, 2018 | http://pubs.acs.org Publication Date: March 8, 2005 | doi: 10.1021/bk-2005-0898.ap001

Figure 9.3. AFM of BPA-PC in 3-point-bending-test.

Figure 9.4. a) AFM phase contrast of 30 mol% DOD-co-PC in 3-point-bendingtest. b)3-Point-bending, crazing in BPA-PC compared to DOD-co-PC.

Brunelle and Korn; Advances in Polycarbonates ACS Symposium Series; American Chemical Society: Washington, DC, 2005.

Downloaded by 80.82.77.83 on January 18, 2018 | http://pubs.acs.org Publication Date: March 8, 2005 | doi: 10.1021/bk-2005-0898.ap001

Figure 9.5. Proposed morphological structure ofthe DOD-co-PC (DOD-blocks: balls, BPA-units: sticks).

Figure 9.6. Model of deformation mechanism ofDOD-co-PC

Brunelle and Korn; Advances in Polycarbonates ACS Symposium Series; American Chemical Society: Washington, DC, 2005.

Downloaded by 80.82.77.83 on January 18, 2018 | http://pubs.acs.org Publication Date: March 8, 2005 | doi: 10.1021/bk-2005-0898.ap001

Figure 9.7. Comparison ofproperties of the DOD-co-PC with BPA-PC

Brunelle and Korn; Advances in Polycarbonates ACS Symposium Series; American Chemical Society: Washington, DC, 2005.