Combustion Synthesis of p-Type Transparent Conducting CuCrO2+x

Subscriber access provided by READING UNIV

Article

Combustion Synthesis of p-Type Transparent Conducting CuCrO and Cu:CrO Thin Films at 180 °C 2+x

x

Jian Wang, Trey B. Daunis, Lanxia Cheng, Bo Zhang, Jiyoung Kim, and Julia W.P. Hsu ACS Appl. Mater. Interfaces, Just Accepted Manuscript • DOI: 10.1021/acsami.7b13680 • Publication Date (Web): 04 Jan 2018 Downloaded from http://pubs.acs.org on January 4, 2018

Just Accepted “Just Accepted” manuscripts have been peer-reviewed and accepted for publication. They are posted online prior to technical editing, formatting for publication and author proofing. The American Chemical Society provides “Just Accepted” as a free service to the research community to expedite the dissemination of scientific material as soon as possible after acceptance. “Just Accepted” manuscripts appear in full in PDF format accompanied by an HTML abstract. “Just Accepted” manuscripts have been fully peer reviewed, but should not be considered the official version of record. They are accessible to all readers and citable by the Digital Object Identifier (DOI®). “Just Accepted” is an optional service offered to authors. Therefore, the “Just Accepted” Web site may not include all articles that will be published in the journal. After a manuscript is technically edited and formatted, it will be removed from the “Just Accepted” Web site and published as an ASAP article. Note that technical editing may introduce minor changes to the manuscript text and/or graphics which could affect content, and all legal disclaimers and ethical guidelines that apply to the journal pertain. ACS cannot be held responsible for errors or consequences arising from the use of information contained in these “Just Accepted” manuscripts.

ACS Applied Materials & Interfaces is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Published by American Chemical Society. Copyright © American Chemical Society. However, no copyright claim is made to original U.S. Government works, or works produced by employees of any Commonwealth realm Crown government in the course of their duties.

Page 1 of 27 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

ACS Applied Materials & Interfaces

Combustion Synthesis of p-Type Transparent Conducting CuCrO2+x and Cu:CrOx Thin Films at 180 °C

!"#$%&#$'()(*%+,-.%/0%1#2$"3()%4#$5"#%67-$'()%/8%97#$'()%!".82$'%:";()%!2/+6),+7!2%'))0%7!FG7!HI"HB#!

! J%:K,(?1L!3,*MN1)/,+!1:+)>%1/17!1,0N)/,+!&(,3%11/+67!&O):&%!;EP7!?%0'-,11/)%7!3,&&%(! ?,&%?!3>(,*/N*!,,([email protected]! ! !

!

ACS Paragon Plus Environment

"!

ACS Applied Materials & Interfaces 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 2 of 27

"#$%&'(%!

R,KO)%*&%(')N(%! 1,0N)/,+! &(,3%11/+6! ,-! &O):&%! )('+1&'(%+)! 3,+?N3)/+6! ,/+! -/0*1L! 3,&&%(! 3>(,*/N*! ,/0%! '?,&)/+6! )>%! 1'*%! &(%3N(1,(! &(%&'(')/,+! '+?! '++%'0/+6! )%*&%(')N(%7! K%! -/+?! )>')! '++%'0/+6! %+9/(,+*%+)! S1,09%+)! 9'&,(! 91#! ,&%+! '/(T! ?/3)')%1! )>%! (%1N0)/+6! -/0*! &>'1%7! >%+3%! )>%! ,&),%0%3)(,+/3! &(,&%()/%1#! ;>%! %--%3)! ,-! '++%'0/+6! %+9/(,+*%+)! ,+! )>%! (%'3)/,+! *%3>'+/1*! /1! ?/13N11%?#! F%! -N()>%(! 3>'('3)%(/U%! )>%! %0%3)(,+/37! ,&)/3'07! '+?! )('+1&,()! &(,&%()/%1! ,-! )>%! )K,! *')%(/'017! '+?! 3,*&'(%! )>%! ?/--%(%+3%1#! ;>%/(! '&&0/3')/,+1! /+! ,&),%0%3)(,+/3! ?%9/3%1! '(%! 1N33%11-N00:! ?%*,+1)(')%?! /+! )('+1&'(%+)! &O+! XN+3)/,+! ?/,?%1! '+?! '1! >,0%! )('+1&,()!0':%(1!/+!,(6'+/3!&>,),9,0)'/3!?%9/3%1#!!

!


D!

Page 3 of 27 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60


)*%&+,-(%.+*!! &O):&%! )('+1&'(%+)! 3,+?N3)/+6! ,,0?! 6(%')! &,)%+)/'0! /+! '! 9'(/%):! ,-! %0%3)(,+/3! '+?! ,&),%0%3)(,+/3! '&&0/3')/,+17! /+30N?/+6! &>,),9,0)'/317! 1,0/?O1)')%! 0/6>)/+67! 1%+1,(17!-0')O&'+%0!?/1&0':17!1*'()!K/+?,K17!'+?!-0%(,*/N*! ,'1!M%%+!'&&0/%?! '1! '! V;R! -,(! ,(6'+/3! &>,),9,0)'/317I! '+?! '1! &>,),3')>,?%! /+! ?:%! 1%+1/)/U%?! 1,0'(! 3%001! S$22ET_!'+?!-,(!K')%(!1&0/))/+6#H!E,*&'(%?!K/)>!)>%!(%[N/(%?!&(,3%11/+6!)%*&%(')N(%!,-!

!


Y!


Page 4 of 27

Z!ICCWE!-/9%!:%'(1!'6,7A!3,+1/1)%+)!&(,6(%11!>'?!M%%+!*'?%!/+!0,K%(/+6!/)1!-'M(/3')/,+! )%*&%(')N(%#! $N(/+6! )>%! 0'1)! )K,! :%'(17! '! -%K! 0,KO)%*&%(')N(%! &(,3%11%1! >'?! M%%+! (%&,()%?L! YACWE! 9/'! &N01%?! /+X%3)/,+! *%)'0! ,(6'+/3! 3>%*/3'0! 9'&,(! ?%&,1/)/,+7"C! YYBWE! 9/'! 1&(':! 3,')/+67""7"D! '+?! DBCWE! 9/'! '),*/3! 0':%(! ?%&,1/)/,+#"Y! =%3%+)0:7! a/+! %)#! '0#! (%&,()%?! '! 1,0O6%0! *%)>,?! )>')! (%'3)1! /+! )>%! "\C! Z! DCCWE! ('+6%b! >,K%9%(7! )>%/(! -/0*1! '0K':1!3,+)'/+!0'(6%!'*,N+)!,-!ENE(DP\!/*&N(/)/%1#"\!P+!)>%!,)>%(!>'+?7!)>%!3,(N+?N*! 3,*&,N+?!3>(,*/N*!,'1!M%%+!?%*,+1)(')%?!'1!'!&(,*/1/+6!&O):&%!;EP! K>%+! ?,&%?! K/)>! c7! .67! ,(! EN#"B7"_! d+! &'()/3N0'(7! 1&N))%(%?! ENLE(P'9%! M%%+! '&&0/%?!'1!V;R1!-,(!&%(,91e/)%!&>,),9,0)'/3!?%9/3%1#"_!8+)/0!?')%7!+,!1,0N)/,+!&(,3%11%?! ENLE(P'1! M%%+! (%&,()%?7! K>/0%! 1,0N)/,+! &(,3%11/+6! ,-! 3>(,*/N*! ,! ,)>%(! ?,&'+)1!Sc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`%(! EN^E(! ,'1%17! ')! "IC! fE#! d+)%(%1)/+60:7!1)'()/+6!-(,*!)>%!1'*%!&(%3N(1,(!1,0N)/,+7!K%!-/+?!)>')!?/--%(%+)!'++%'0/+6! %+9/(,+*%+)1! S1,09%+)! 9'&,(! 91#! ,&%+! '/(T! ?/3)')%! )>%! (%1N0)/+6! -/0*! &>'1%! S?%0'-,11/)%! 91#! 3,(N+?N*T#! ;>,(,N6>! 3>'('3)%(/U')/,+1! 1>,K! M,)>! ENE(PD`/0%!M%/+6!>/6>0:!)('+1&'(%+)#!]N()>%(*,(%7! )>%/(! '&&0/3')/,+1! /+! ,&),%0%3)(,+/3! ?%9/3%1! '(%! ?%*,+1)(')%?! /+! )('+1&'(%+)! &O+! XN+3)/,+! ?/,?%1! '+?! '1! V;R1! /+! ,(6'+/3! &>,),9,0)'/3! SPghT! ?%9/3%1#! ;>/1! *%)>,?! K/00! %+'M0%!ENE(PD!'+?!ENLE(P/+!-/0*1!-,(!,)>%(!%0%3)(,+/3!'&&0/3')/,+1!)>')!(%[N/(%!0,KO )%*&%(')N(%!&(,3%11/+6#!! ! /012&.32*%'4!52(%.+*! 6'%2&.'4!$7*%82$.$!'*,!(8'&'(%2&.9'%.+*!! G00! 3>%*/3'01! '(%! &N(3>'1%?! -(,*! G0-'! G%1'(! N+0%11! ,)>%(K/1%! +,)%?#! d+! ,N(! 3,*MN1)/,+! 1:+)>%1/17! K%! N1%! *%)'0! +/)(')%! &(%3N(1,(17! K>%(%! )>%! +/)(')%! 6(,N&! -N+3)/,+1! '1! )>%! i,%! &(%3N(1,(! '1! )>%! i-N%0j#! ;>%!&(%3N(1,(!*,0'(!(')/,!,-!E(ScPYTYL!ENScPYTDL!60:3/+%!/1!'0K':1!"L"LC#D7!K>/0%!)>%!),)'0! 3,+3%+)(')/,+! /1! 9'(/%?! ),! '3>/%9%! ?/--%(%+)! -/0*! )>/3e+%11%1#! G1! '+! %/1!1,0N)/,+!/1!)>%+!1)/((%?!K/)>!)>%!3'&!,&%+!-,(! Z! "D! >,N(1! ')! HC! WEb! )>/1! &(,3%11! (%*,9%1! )>%! K')%(! 1,! )>')! +,+ON+/-,(*! K%))/+6! ,+! 1NM1)(')%1!?,%1!+,)!,33N(!?N(/+6!1&/+!3,')/+6#!;,!3,*&%+1')%!-,(!)>%!.P5!0,11!?N(/+6! 1)/((/+67!K%!)>%+!'??!'!1N--/3/%+)!'*,N+)!,-!'+>:?(,N1!.P5!),!'3>/%9%!'!-/+'0!9,0N*%!,-! D!*R#!d+!)>/1!%')!/)!>'1!),! M%!?/11,09%?!/+!K')%(!-/(1)#!G-)%(!1&/+!3,')%?!,+),!1NM1)(')%1!S8hO,U,+%!30%'+%?!60'117!

!


B!


Page 6 of 27

/+?/N*! )/+! ,%! -/0*1! '(%! 1NMX%3)%?! ),! ?/--%(%+)! '++%'0/+6! %+9/(,+*%+)1!S]/6N(%#!"T#!d+!1,09%+)!'++%'0/+6!S]/6#!"!),&T7!)>%!-/0*!/1!3,9%(%?!M:!'!&%)(/! ?/1>7!),6%)>%(!K/)>!'!*%)'0!(%1%(9,/(!-/00%?!K/)>!_!*R!,-!.P57!'+?!e%&)!')!"ICWE!-,(!"C! */+N)%1#!d+!3,+)('1)7!'/(!'++%'0/+6!(%-%(1!),!?/(%3)0:!)('+1-%((/+6!)>%!-/0*!,+),! '!"ICWE! >,)&0')%!),!'++%'0!/+!,&%+!'/(!-,(!"C!*/+N)%1#!$/--%(%+)!-/0*!)>/3e+%11!/1!'3>/%9%?!9/'!)>%! 3,+)(,00/+6! )>%! 1&/+! 1&%%?! SDCCC! Z! \CCC! (&*T! '+?! &(%3N(1,(! 3,+3%+)(')/,+! SC#"! .! Z! "! .T#!.%'1N(%?!M:!%00/&1,*%)(:!K%!-/+?!)>')7!-,(!-/0*1!*'?%!')!1'*%!1&/+!3,')/+6!1&%%?7! 1,09%+)! '++%'0/+6! &(,?N3%1! -/0*1! "#A! Z! D#C! )/*%1! )>/3e%(! )>'+! '++%'0/+6! /+! '/(#! d+! )>/1! &'&%(7! K%! K/00! 3,*&'(%! -/0*1! *'?%! N1/+6! )>%! 1'*%! 1&/+! 1&%%?! (')>%(! )>'+! )>%! 1'*%! &>:1/3'0!)>/3e+%117!/#%#!K/)>!)>%!1'*%!'*,N+)!,-!*')%(/'017!/+!'00!3>'('3)%(/U')/,+1!'+?! ?%9/3%!&%(-,(*'+3%#!! k,)>!1,09%+)O'++%'0%?!-/0*1!'+?!'/(O'++%'0%?!-/0*1!,+!2/!1NM1)(')%1!'(%!3>'('3)%(/U%?! M:! ='*'+! 1&%3)(,13,&:! S=%+/1>'K! 3,+-,3'0! ='*'+! 1:1)%*T7! @O(':! &>,),%0%3)(,+! 1&%3)(,13,&:! S@g27! gVd! BCCC! h%(1'! g(,M%! ddT7! '),*/3! -,(3%! */3(,13,&%! SG].7! G1:0N*! .]gOY$T7! '+?! %00/&1,*%)(:! Sl#! G#! F,,00'*! .ODCCC$dT#! ;>%! ='*'+! %!BYD!+*!0'1%(!%,()! /+)%6(')/,+! )/*%! SY! Z! "C! 1%3,+?1T! ),! '9,/?! 1'*&0%! ?'*'6%! ,(! >%')/+6#! c,! 3>'+6%!/+!='*'+!1&%3)('!S/+)%+1/):7!&,1/)/,+7!'+?!]FV.T!K'1!,M1%(9%?!-,(!*%'1N(/+6! )/*%! N&! ),! D! */+N)%1#! ! ! ;>,1%! -/0*1! ,+! 60'11! 1NM1)(')%1! '(%! 3>'('3)%(/U%?! M:! 8hOh/1! SP3%'+! P&)/31! 82k! \CCCT! '+?! &>,),%0%3)(,+! 1&%3)(,13,&:! /+! '/(! Sg52G7! =Jd! /+1)(N*%+)! N+/)! GEDT#! ;>%! K,(e! -N+3)/,+1! '(%! *%'1N(%?! N1/+6! '! J%09/+! &(,M%! SJg! )%3>+,0,6:T! ,+! )>,1%!-/0*1!,+!d;P!1NM1)(')%1#!V'00!*%'1N(%*%+)!'(%!&%(-,(*%?!N1/+6!'!R'e%1>,(%!I\C\!

!


_!

Page 7 of 27 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60


1:1)%*7!N+?%(!"#DB!;!*'6+%)/3!-/%0?!*,?N0')%?!')!C#"!VU#!],(!V'00!*%'1N(%*%+)7!)>/3e! -/0*1!SZDHC!+*!ENE(PD`/3e!o+P!1,0O6%0!0':%(!'+?!'! "CC! +*! )>/3e! G0! %0%3)(,?%#! ],(! )>%! o+P! 0':%(7! '! C#B! .! U/+3! '3%)')%! '+?! %)>'+,0'*/+%! 1,0N)/,+!S"L"!(')/,T!/+!.P5!/1!1&/+O3,')%?!')!"CCC!(&*!-,(!_C!17!'+?!)>%+!'++%'0%?!/+!'/(! ')!"IC!WE!-,(!"C!*/+#!;>%!'(%'!,-!%'3>!&O+!XN+3)/,+!?/,?%!S?%-/+%?!M:!)>%!G0!%0%3)(,?%T!/1! Z! C#D! **D#! ],(! Pgh! ?%9/3%17! '! Z! \C! +*! ENE(PD`%!(%-%(%+3%!V;R#!],(!)>%!'3)/9%!0':%(7!'!"L\! (')/,!

&,0:p?OHjO>%&)'O?%3'+:0OD7AO3'(M'U,0%O#/%+:0ODj7"j7YjO

%+U,)>/'?/'U,0%Tq! S"O.')%(/'0TL! p_7_qO&>%+:0OEA"OMN):(/3! '3/?! *%)>:0! %1)%(! S2,0%++%! khT! SgE$;k;LgEA"k.T!M0%+?!SALDI!*6^*RT!/+!"7DO?/3>0,(,M%+U%+%!/1!1&/+!3,')%?!')!DCCC!(&*! -,(!"DC!1%3,+?17!-,00,K%?!M:!)>%(*'0!'++%'0/+6!')!AC!!WE!-,(!"B!*/+N)%1!/+!cD#!]/+'00:7!A! +*!E'!'+?!"CC!+*!G0!'(%!1%[N%+)/'00:!%9'&,(')%?!,+!),&!,-!)>%!'3)/9%!0':%(!),!3,*&0%)%! )>%!?%9/3%#!;>%!'(%'!,-!%'3>!Pgh!?/,?%!/1!C#""!3*D#!! ;>%! !AB! *%'1N(%*%+)1! '(%! &%(-,(*%?! N1/+6! '! 1,N(3%*%)%(! SJ%/)>0%:! D_YBGT! 3,+)(,00%?! M:! '! R'Mh/%K! &(,6('*#! Pgh! *%'1N(%*%+)1! '(%! 3,+?N3)%?! /+! '! cDO-/00%?!

!


A!


Page 8 of 27

60,9%M,/3>!(%&(%1%+)!)>%!)(/'+6N0'(!0'))/3%!9/M(')/,+!/+!)>%!'OM!&0'+%!SE(OP!&0'+%T!'+?! ENOP!M,+?!9/M(')/,+!'0,+6!)>%!3O'/3>! '(%! /+! 6,,?! '6(%%*%+)! K/)>! %'(0/%(! (%&,()! -,(! ENE(PD#"H7D"! d+! '??/)/,+7! )>%! &%'e! +%'(! DC"! 3*O"! /1! '))(/MN)%?!),!'!+,+OU,+%!3%+)%(!56!*,?%7!'(/1/+6!-(,*!(%0'! )>%!56!*,?%1!,-!N+?,&%?!3(:1)'00/+%!E(DPY!S6(,K+!M:!*,0%3N0'(!M%'*!%&/)'/0%!)>%! 1)(,+6%1)! &%'e! ')! BY\! 3*O"! /1! ?,K+1>/-)%?! ! Z! DC! 3*O"! -(,*! )>%! G"6! *,?%! ,-! N+?,&%?! 3(:1)'00/+%!E(DPY!')!BB\!3*O"#DD!d+)%(%1)/+60:7!/)!'6(%%1!K%00!K/)>!)>%!G"6!*,?%!')!BY\!3*O"! ,-! '! .6S"CsTLE(DPY! 1'*&0%! &(%&'(%?! 9/'! 1&(':! &:(,0:1/17! K>/3>! /1! 1/*/0'(! ),! ,N(! 3,*MN1)/,+! (%'3)/,+! 3,+?/)/,+#! G1! .6LE(DPY! 1'*&0%1! &(%&'(%?! 9/'! ,)>%(! *%)>,?1! S&N01%?! 0'1%(! ?%&,1/)/,+7! 1&N))%(/+6T! ?,! +,)! %/M/)! 1N3>! '! ?,K+1>/-)7! K%! )>%(%-,(%! '))(/MN)%! )>%! G"6! ?,K+1>/-)! ),! )>%! &(,3%11/+6! /+1)%'?! ,-! /+3,(&,(')/,+! ,-! EN! /+! E(DPY#! $%)'/0%?!N+?%(1)'+?/+6!,+!)>/1!&>%+,*%+,+!/1!1NMX%3)%?!),!-N()>%(!%+/[N%1b!>%+3%!)>%/(! (%1N0)1! ?,! +,)! >'9%! ),! M%! 3,((%0')%?#! ],(! %,K%?! )>')! '! 1&(':O &:(,0:U%?! ENO?%-/3/%+)! ENE(PD! *')%(/'0! %/M/)1! '! M(,'?! '+?! /00O-,(*%?! ='*'+! &%'e1! S?N%! ),! EN! 9'3'+3:T! 3,*&'(%?! K/)>! ENE(PD! &,K?%(1! &(%&'(%?! 9/'! 60:3/+%O+/)(')%! 3,*MN1)/,+!(%'3)/,+7!'0)>,N6>!)>%:!%/M/)!1/*/0'(!@=$!1&%3)('#""7"H!;>')!,N(!-/0*1!1>,K! +,! @=$! (%-0%3)/,+1! MN)! 1)(,+6! ='*'+! &%'e1! /+?/3')%1! )>')! )>%! ,(?%(/+6! ('+6%! ,-! ,N(! ,'1!M%%+!N1%?!'1!'!&(/*'(:!&>'1%!/?%+)/-/3')/,+! )%3>+/[N%! -,(! ,)>%(! +'+,3(:1)'00/+%! *')%(/'0! 1:1)%*17! K>%(%! @=$! -'/01! ),! &(,?N3%! ?/--('3)/,+! &%'e17! 1N3>! '1! )('+1/)/,+! *%)'0! 3>'03,6%+/?%D\! '+?! N0)('O+'+,3(:1)'00/+%! ?/'*,+?#DB!!

!


H!


Page 10 of 27

@g2!'+'0:1/1!K'1!3'((/%?!,N)!),!N+?%(1)'+?!)>%!-/0*!1),/3>/,*%)(:#!;>%!,! -/0*1! 3,+)'/+! ,+0:! Pd! M,+?/+6! SZBDH#B! %h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s! EN"`! 91#! _Ys!END`!,-!3,&&%(!1&%3/%17!'+?!HDs!E(Y`!91#!Is!E(\`!,-!3>(,*/N*!1&%3/%1#!d+!3,+)('1)7! )>%!'/(O'++%'0%?!-/0*!>'1!"s!EN"`!91#!HHs!END`!,-!3,&&%(!1&%3/%17!'+?!\Ys!E(Y`!'+?!BAs! E(\`! ,-! 3>(,*/N*! 1&%3/%1#! d+! -/(1)! 60'+3%7! )>%! 0'(6%! '*,N+)! ,-! END`! 1&%3/%1! /+! 1,09%+)O '++%'0%?! -/0*! 1%%*1! ),! 3,+-0/3)! K/)>! )>%! ?%0'-,11/)%! &>'1%! /?%+)/-/3')/,+! M:! ='*'+7! '1! ?%0'-,11/)%! 3,*&,N+?1! '(%! N1N'00:! /+! )>%! -,(*')! ,-! G"`kY`PD#! V,K%9%(7! i?%0'-,11/)%j! (%-%(1!),!)>%!3(:1)'00/+%!1)(N3)N(%7!K>/3>!3,+1/1)1!,-!)>%!'0)%(+')%!1)'3e/+6!,-!kPD!0':%(1! ,-!%?6%O1>'(/+6!kP_!,3)'>%?('!'+?!&0'+%1!,-!G!3')/,+1!'(('+6%?!'1!'!&0'+'(!)(/'+6N0'(! +%)K,(e#! ;>%(%-,(%7! EN! /+! )>%! 1)(N3)N(%! ?,%1+j)! >'9%! ),! M%! %
Page 11 of 27 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60


1&%3/%1#DI7DH!d+!)>%1%!3,*&,N+?17!%%! 0'(6%!END`!&,&N0')/,+!/+!,N(!-/0*1!/1!3,+1/1)%+)!K/)>!)>%!?%-%3)!56!M'+?!'(,N+?!DC"!3*O"! ,M1%(9%?!/+!='*'+!S]/6N(%!D'T7!K>/3>!>'1!M%%+!'))(/MN)%?!),!EN!9'3'+3/%1!,(!/+)%(1)/)/'0! ,%! 3')/,+1! SM,)>! EN! '+?! E(T! /+! 1,09%+)O '++%'0%?!-/0*1!%/M/)!'!0,K%(!9'0%+3%!)>'+!/+!'/(O'++%'0%?!-/0*1#!d+!1,09%+)!'++%'0/+67! )>%!.P5!SEYVIPDT!'3)1!'1!'!(%?N3/+6!'6%+)!M%3'N1%!/)!/1!'+!'03,>,07!(%1N0)/+6!/+!(%?N3/+6! END`! ),! EN"`#! d+! '! &(%9/,N1! (%&,()! ,+! >:?(,)>%(*'0! 1:+)>%1/1! ,-! ?%0'-,11/)%! ENr'PD7! *'+:! '03,>,01! K%(%! &(,9%?! ),! M%! %--/3/%+)! (%?N3/+6! '6%+)1! ),! (%?N3%! )>%! END`! &(%3N(1,(1! /+),! EN"`! 1&%3/%1#YC! F%! '+)/3/&')%! )>')! -N)N(%! %--,()! ),! -N()>%(! (%?N3%! )>%! END`!1&%3/%1!K,N0?!>%0&!-,(*!?%0'-,11/)%!-/0*1!K/)>!M%))%(!3(:1)'00/+/):#!d+!3,+)('1)7!K>%+!

!


""!


Page 12 of 27

'++%'0%?!/+!'/(7!EN!1&%3/%1!1)':!/+!)>%!>/6>%1)!,%!E(!1&%3/%1!'(%!,%!Y`!1)')%!/+!)>%!E(ScPYTY!&(%3N(1,(!/+),!)>%! \`! 1)')%#! ;>%! 0'(6%! ?(/9/+6! -,(3%! ),! /+3(%'1%! EN! '+?! E(! 9'0%+3%1! ?N(/+6! '/(! '++%'0/+6! /+>/M/)1! ENE(PD! -,(*')/,+#! 2%3,+?7! '++%'0/+6! %+9/(,+*%+)! ?%)%(*/+%1! )>%! ,%! ENE(PD! 3(:1)'0! &,11%11%1! '+! '0)%(+')/+6! EN! '+?! E(! ,,K%9%(7! )>%! 1,09%+)! 0%'9%1! /**%?/')%0:! ,+3%! )>%! -/0*! /1! >%')%?! ),! >/6>! )%*&%(')N(%#! G1! )>%! (%'3)'+)! 1&%3/%1! 1,0/?/-:7! )>%:! ?,+j)! >'9%! )/*%! ),! (%'(('+6%! ),! 6(,K! )%(+'(:! ,:&,)>%1/1L! 1,09%+)O'++%'0%?! -/0*1! '(%! (,N6>%(! S=.2L! Y#Y! +*T! 3,+1/1)/+6!,-!1*'00!&'()/30%17!K>/0%!)>%!'/(O'++%'0%?!-/0*1!'(%!1*,,)>!S=.2L!C#D!+*T!'+?! 3,+1/1)%+)!K/)>!('&/?!1,0/?/-/3')/,+#!! c%'('3)%(/U%! )>%! ,&)/3'0! &(,&%()/%1! ,-! M,)>! -/0*1#! ]/6N(%! \'! 1>,K1! )('+1*/11/,+!1&%3)('!,-!'!Z!\C!+*!ENE(PD`/3>!'(%! 1&/+! 3,')%?! -(,*! )>%! 1'*%! C#D! .! 1,0N)/,+! ')! \CCC! (&*! MN)! '++%'0%?! ?/--%(%+)0:#! ;>%! /+1%)!1>,K1!'!&>,),!,-!M,)>!-/0*1!,+!60'11#!;>%!ENE(PD`!'+!'M1,(&)/,+!,+1%)!')!'!1>,()%(!K'9%0%+6)>!SZ\BC!+*T7!K>/0%!)>%!ENLE(P!SZ!_CC!+*T#!;>/1!(%1N0)! /1!3,+1/1)%+)!K/)>!)>%!%%!1'*%!1&/+!3,')/+6!

!


"D!

Page 13 of 27 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60


1&%%?7! K%! -/+?! 1,09%+)! '++%'0/+6! (%1N0)1! /+! ENE(PD`! )>%! G].! (%1N0)1! )>')! ENE(PD! -/0*1! '(%! (,N6>%(! )>'+! ENLE(P%! &,(,1/):! ?/--%(%+3%! M%)K%%+! ,N(! ENE(PD`%!-/0*! N+?%(!1,09%+)!'++%'0/+6!S>/6>%(!9'&,(!&(%11N(%T#!G1!'!(%1N0)7!,N(!ENE(PD`/M/)1!'! 0,K%(!(%-('3)/9%!/+?%'+!ENE(PD!0/)%(')N(%!SD#Y!Z!D#IT7""!MN)!,N(!ENLE(P/M/)1!'! 10/6>)0:!>/6>%(!,(!1/*/0'(!(%-('3)/9%!/+?%%!)>%(*'00:!%9'&,(')%?!E(DPY!S"#\!Z!D#CT#Y"! F%! '01,! 3>'('3)%(/U%! )>%! %0%3)(,+/3! &(,&%()/%1! ,-! M,)>! *')%(/'01! S]/6N(%! B7! ;'M0%! DT#! ;>%!M'+?!1)(N3)N(%1!'(%!3,+1)(N3)%?!S]/6N(%!BT!N1/+6!M'+?6'&!SkrT!?%)%(*/+%?!M:!8hO h/1! S]/6N(%! 2D'T7! /,+/U')/,+! %+%(6:! Sd5T! *%'1N(%?! M:! g52G! S]/6N(%! 2DMT7! K,(e! -N+3)/,+! S]%(*/!0%9%07!5]T!*%'1N(%?!M:!J%09/+!&(,M%7!'+?!)>%!%0%3)(,+!'--/+/):!S5GT!3'03N0')%?!M:! d5Okr#!;>%!M'+?!1)(N3)N(%!1>,K1!)>')!M,)>!*')%(/'01!'(%!&O):&%7!K/)>!ENLE(P/M/)/+6! '! ?%%&%(! d5! '+?! 5]! )>'+! )>%! ENE(PD`/1! 3'+! M%! %')! ,/6>%(! ,!*')%(/'01!'(%!&O):&%#!d)!'01,!1>,K1! )>')! ENE(PD`/M/)1! '! 0,K%(! 3'((/%(! 3,+3%+)(')/,+! SY#I! "! "C"I! 3*OYT! MN)! '! >/6>%(! *,M/0/):! SC#DY! 3*D^h1T7! >%+3%! '! 10/6>)0:! >/6>%(! 3,+?N3)/9/):! SC#"\! 2^3*T! )>'+! ENLE(P

Page 14 of 27

M%! "#A! "! "C"A! 3*OY7! "#\! 3*D^h17! '+?! C#CYI! 2^3*7YY! (%1&%3)/9%0:7! '+?! -,(! 3(:1)'00/+%! ENLE(P
Page 15 of 27 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60


0,K%(! &,K%(! 3,+9%(1/,+! %--/3/%+3:! SgE5T! )>'+! g5$P;Lg22! V;R! ?%9/3%1#! 2/+3%! )>%! ?/--%(%+3%!/1!1*'007!/)!/1!?/--/3N0)!),!'))(/MN)%!'!3'N1%!?%-/+/)/9%0:#!d)!/1!e+,K+!)>')!(,N6>! M,)),*! 0':%(! 3'+! 0,K%(! )>%! ]]! ,-! Pgh7DA! )>')! )>%! ENE(PD`%(! )>'+! g5$P;Lg22! */6>)! 3,+)(/MN)%! ),! )>%! 0,K%(! ]]! '+?! )>%! >/6>%(! (%9%(1%! M/'1! 0%'e'6%! S]/6#! _?T#!P+!)>%!,)>%(!>'+?7!ENLE(P/M/)1!>/6>%(!B837!0,K%(!!3C7!'+?!1/*/0'(!]]!K>%+! 3,*&'(%?!K/)>!g5$P;Lg22#!;>%!>/6>%(!B8C!3'+!M%!'))(/MN)%?!),!)>%!>/6>%(!K,(e!-N+3)/,+! '+?! /,+/U')/,+! %+%(6:! ,-! ENLE(P/0%! )>%! 0,K%(! !3C! /1! 0/e%0:! ?N%! ),! /)1! &'('1/)/3! 'M1,(&)/,+! /+! )>%! 9/1/M0%! 0/6>)! ('+6%#! P9%('007! )>%! &%(-,(*'+3%! /1! 3,*&'('M0%! M%)K%%+! )>%! ENLE(P%(! MN)! *,(%! (%1/1)/9%!)>'+!ENE(PD7!/)!/1!%')!ENLE(P+*(4-$.+*$! d+! 1N**'(:7! K%! >'9%! ?%9%0,&%?! '! 3,*MN1)/,+! 1:+)>%1/1! *%)>,?! ),! 1,0N)/,+! 1:+)>%1/U%!&O):&%!?%0'-,11/)%!ENE(PD`
!


"B!


Page 16 of 27

;>%! 'N)>,(1! )>'+e! g(,-#! k#! r+'?%! -,(! '33%11! ),! )>%! V'00! *%'1N(%*%+)! '+?! g(,-#! =#! F'00'3%! -,(! )>%! N1%! ,-! )>%! 1&%3)(,13,&/3! %00/&1,*%)%(#! ;>/1! &(,X%3)! K'1! 1&,+1,(%?! M:! 8+/9%(1/):! ,-! ;%%! c')/,+'0! 23/%+3%! ],N+?')/,+! Sc2]T! Sr('+)! c,#! $.=O "YCBIHYT7!'+?!2FGc!E%+)%(7!'!2=E!3%+)%(!1&,+1,(%?!M:!)>%!c'+,%0%3)(,+/31!=%1%'(3>! d+/)/')/9%!'+?!cd2;#!l#F#!'3e+,K0%?6%1!)>%!F'1>/+6),+!=%1%'(3>!],N+?')/,+!d++,9')/,+! ]%00,K1>/&1! /+! E0%'+! 5+%(6:! ,--%(%?! M:! )>%! E0%'+! 5+%(6:! d+1)/)N)%! ')! )>%! 8+/9%(1/):! ,-! F'1>/+6),+#!l#F#g#V#!'3e+,K0%?6%1!)>%!1N&&,()!-(,*!;%%! M'+?6'&!'+?!/,+/U')/,+!%+%(6:!*%'1N(%*%+)1!S]/6N(%!2DT!-,(!M,)>!1,09%+)O'++%'0%?!'+?! '/(O'++%'0%?!-/0*1#

=2)O 5*/))/+6!$/,?%1#!67-;0%G#@-,0!CDEI7!*M7!\BDIv\BY\#!

S_T!

@/,+67!$#b!@N7!o#b!o%+67!@#b!o>'+67!F#b!E>%+7!F#b!@N7!@#b!F'+67!.#b!E>%+67!t#Ok#! V:?(,)>%(*'0! 2:+)>%1/1! ,-! 80)('1*'00! ENE(PD! c'+,3(:1)'0! G0)%(+')/9%1! ),! c/P! c'+,&'()/30%1! /+! 5--/3/%+)! gO;:&%! $:%O2%+1/)/U%?! 2,0'(! E%001#! !0% G#@-,0% 67-;0! CDEC7!**7!D\A_C#!

SAT!

V'+7!.#b!l/'+67!J#b!o>'+67!l#b!tN7!F#b!R/7!t#b!VN7!o#b!E>N7!l#!2)(N3)N('07!50%3)(,+/3! k'+?!;('+1/)/,+!'+?!P&),%0%3)(,+/3!g(,&%()/%1!,-!$%0'-,11/)%!ENr'"x,),9,0)'/31#!!%G#@-,0%67-;0%6!CDEF7!K7!Y_CAvY_"Y#!

SHT!

$z'UOr'(3z'7! G#! J#b! R'+'Oh/00'((%'07! ;#b! r{*%U7! =#! 2,0Or%0! E,&&%(! E>(,*/N*! $%0'-,11/)%! ;>/+! ]/0*1! '1! 2)'M0%! P,),3')>,?%1! -,(! F')%(! 2&0/))/+6#! !0% G#@-,0%67-;0%D!CDEH7!J7!"H_IYv"H_IA#!

!


"A!


S"CT!

Page 18 of 27

E(|&%00/}(%7!l#b!g,&'7!g#!R#b!k'>0'K'+%7!c#b!R%)N(3[7!=#b!F%(+%(7!]#b!2/%M%+)(/))7!2#b! R%+,M0%7! $#! ;('+1&'(%+)! E,+?N3)/9%! ENE(PD! ;>/+! ]/0*1! $%&,1/)%?! M:! gN01%?! d+X%3)/,+! .%)'0! P(6'+/3! E>%*/3'0! h'&,(! $%&,1/)/,+L! 8&O23'0'M0%! g(,3%11! ;%3>+,0,6:! -,(! '+! d*&(,9%?! ;('+1&'(%+3:^E,+?N3)/9/):! ;('?%OP--#! !% G#@-,0% 67-;0%6!CDEF7!K7!\DAIv\DIA#!

S""T!

]'((%007! R#b! c,(),+7! 5#b! 2*/)>7! E#! .#b! E'--(%:7! $#b! 2>9%)17! d#! h#b! ]0%/13>%(7! J#! 2:+)>%1/1!,-!c'+,3(:1)'00/+%!EN!$%-/3/%+)!ENE(PD!v!'!V/6>!]/6N(%!,-!.%(/)!gO;:&%! ;('+1&'(%+)!2%*/3,+?N3),(#!!0%G#@-,0%67-;0%6!CDEF7!K7!"D_v"Y\#!

S"DT!

]'((%007!R#b!c,(),+7!5#b!Pw$,K?7!k#!l#b!E'--(%:7!$#b!2>9%)17!d#!h#b!]0%/13>%(7!J#!2&(':! g:(,0:1/1!r(,K)>!,-!'!V/6>!]/6N(%!,-!.%(/)7!c'+,OE(:1)'00/+%7!gO;:&%!;('+1&'(%+)! E,+?N3)/+6!.')%(/'0!')!R,K!;%*&%(')N(%#!DNN'+3%?! gO;:&%! ;('+1&'(%+)! 2%*/3,+?N3)/+6! E>'('3)%(/1)/31!-,(!GR$Or(,K+!.6O2NM1)/)N)%?!ENE(PD!;>/+!]/0*1#!DEF0%Q%+67!@#OR#b!R/N7!a#b!;',7!V#b!t'+67!r#b!J%7!F#Ol#b!@/,+67!R#O


"I!

Page 19 of 27 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60


k#b! a/+7! .#OE#b! o>',7! @#Oo#b! ]'+67! r#Ol#! E,&&%(O$,&%?! E>(,*/N*! P'1%!;('+1/)/,+1!/+!E(DPY!),!_"!rg'#!L7.30%S-F0%/!CDDI7!MT7!

!


"H!


Page 20 of 27

"\\"CA#! SD\T!

R/7!V#b!o>'+67!a#b!t'&7!E#!E#!=#b!;':7!k#!J#b!5?K/+7!;#!V#!;#b!P0/9/%(7!G#b!k'/00'(6%')7! $#! ](,*! kN0e! ),! .,+,0':%(! .,2DL! 59,0N)/,+! ,-! ='*'+! 23'))%(/+6#! DEF0% I2$C@0% G#@-,0!CDEC7!**7!"YIBv"YHC#!

SDBT!

k/((%007! l#b! r%(M/7! l#! 5#b! GN3/%00,7! P#b! r/M1,+7! l#! .#b! l,>+1,+7! l#b! E'(0/10%7! l#! G#! d+)%(&(%)')/,+!,-!)>%!='*'+!2&%3)('!,-!80)('+'+,3(:1)'00/+%!$/'*,+?#!1"#;8$E% S-,),Og'))%(+'M0%!o+P!;>/+!]/0*1!k'1%?!,+!E(,11O R/+e%?! o/+3! G3(:0')%! -,(! P(6'+/3^d+,(6'+/3! V:M(/?! E,*&0%*%+)'(:! d+9%()%(1#! D6R%DNN%+7!=#b!2N+7!V#!$#b!]%+6X/7!R#b!o>'+67!2#! P! gO;:&%! o+P! ;>/+! ]/0*1! 81/+6! F%)! E>%*/3'0! =,N)%! K/)>! 5+>'+3%?! E'((/%(! E,+3%+)(')/,+! M:! ;%*&%(')N(%O$%&%+?%+)! ;N+/+6! ,-! G33%&),(! $%-%3)1#! !0%DNN7!=#!2#b!23>+%%*%:%(!R#!]#! R'ENPD#B`@!'+?!tENPD#B`@!$%0'-,11/)%1L!.')%(/'01!K/)>!;(/'+6N0'(!END`~!g0'+%1#!!0% R8%! k%>'9/,(1! ,-! P(6'+/3! g>,),9,0)'/3! $%9/3%1#! ?#$8%4-@@0!CDEH7!)W7!A_DAvA_YD#!

!

!


D"!



Page 22 of 27

Page 23 of 27 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60





Page 24 of 27

Page 25 of 27 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60


,-!gE$;k;LgEA"k.!Pgh!?%9/3%1!K/)>!?/--%(%+)!V;R1L!ENE(PD`
!

!


DB!


Page 26 of 27

;'M0%!"#!E,*&'(/1,+!,-!='*'+!*,?%1!,-!1,09%+)!'++%'0%?!'+?!'/(!'++%'0%?!1'*&0%1! K/)>!0/)%(')N(%!SN+/)L!3*O"T#!S1u1)(,+67!*u*%?/N*7!KuK%'e#T! PN(!$')'!

R/)%(')N(%!

2,09%+)! G++%'0/+6!

G/(! G++%'0/+6!

ENE(PD! =%-#"H!

E(DPY! =%-#DC!

.6LE(DPY! =%-#DC!

DC"!S1T!

DC"!SKT!

DCA!S1T!

DHI!SKT!

BY\!S1T!

Y__!SKT!

YCD!S*T!

Y_C!SKT!

YBC!SKT!

!

\Y_!S1T!

YYA!S*T!

\\\!S1T!

BDA!SKT!

!

\AI!SKT!

YID!SKT!

\AB!SKT!

BB\!S1T!

!

_I"!S1T!

\YH!SKT!

BYC!SKT!

_"I!SKT!

!

BY\!S1T!

_H"!S1T!

BHY!SKT!

!

! !

_I_!SKT!

!

!

! ! !

! ! !

! ;'M0%!D#!V'00!*%'1N(%*%+)!(%1N0)1!-,(!ENE(PD`
V'00!.,M/0/):! S3*D^h1!T!

ENE(PD!

&!

C#"\!

Y#I!5!"I!

C#DY!

ENLE(P
&!

C#CDH!

D#Y!5!"H!

C#CCI!

! ;'M0%!Y#!Pgh!?%9/3%!&'('*%)%(1#!

! !

!

V;R!

B8C%ShT!

!3C% S*G^3*DT!

ENE(PD`
C#IYI!•!C#C"B!

H#\I!•!C#"D!

C#BI•C#C"!

\#_\!•!C#CI!

ENLE(P
C#HCD!•!C#CC\!

I#HH!•!C#"B!

C#_C•C#C"!

\#IA!•!C#"C!

g5$P;Lg22!

C#IY"!•!C#C"D!

H#BI!•!C#"H!

C#_"•C#C"!

\#I_!•!C#CH!

]]!

gE5!SsT!

!


D_!

Page 27 of 27 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60



Combustion Synthesis of p-Type Transparent Conducting CuCrO2+x

Recommend Documents