Comment on "dynamic Stokes shift in coumarin: is it only relaxation

Robert Baumann, Camilla Ferrante, Erwin Kneuper, Fred-Walter Deeg, and Christoph Bräuchle. The Journal of Physical Chemistry A 2003 107 (14), 2422-24...
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J . Phys. Chem. 1991, 95, 1012-1014

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can be derived for the limiting case where all ions A in the solution are sorbed by the ion exchanger (c~,.. 0). Unless the separation factor a is very large, this implies that XA,=