Comments on the linearized current-potential characteristic

Comments on the linearized current-potential characteristic. S. K. Rangarajan. Anal. Chem. , 1968, 40 (8), pp 1382–1383. DOI: 10.1021/ac60264a040...
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Comments on the Linearized Current-Potential Characteristic SIR: Two recent communications ( I , 2) have correctly emphasized the need to be vigilant while employing linearized forms of the rate equation:

Equation 3 is deduced from Equation 5 if ACR ((a - l ) ~ $ q ) ~Eo , a47 and (1 - cy)$r can be neglected.

Two linear versions of Equation 1 have been taken up for discussion ( 2 ) ; they are:

That is, if $7 is small enough, not only ( + v ) ~ , (47)3 etc. ACo are lower-order terms to be abandoned, even "a$r], CO ACR ACo (1 - a)+?, a( ~ ~ 4 etc. 7 ) ~are, in general, lower-order CR CO

COO

quantities.

~

z/zo

=

CO -o CO

- o-C R - qlq

(3)

CR

I

It was insisted that a simple condition like 147