Inorg. Chem. 1992, 31, 2281-2282 Table I. Size and Potential Parameters’ of Molecular Anions radius params, A ion (basis) (energy, au) P r< r, BH, (tz2p) (-26.985) 1.73 1.58 2.29
OH- (tz2p) (-75.376) CN- (tz2p) (-92.326) N < (tz2p) (-163.313) N01- (tz2p) (-204.132) NO,- (tz2p) (-279.004)
SH-(dz2p) (-398.067) BFc (tz2p) (422.877) CNS- (tzp)‘ (-489.864) C10< (tzp) (-683.862) CIO; (tzp) (-758.668)
BrOy (G-1) (-2796.339)
(1.79h) 1.14 (1.199 1.52 (1.77h) 1.75 (1.8 lh) 1.62 (1.7Sh) 1.88 (1.65h) 1.62 (1 .93h) 2.00 (2.1Sh) 2.27 (1 .99h) 2.09 (1.57h) 2.21 (2.26h) 2.24 (1 .40h)
2281
potential params, au Ar 0.38
P
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