Composition of Explosives by Electrospray Ionization Fourier

Mar 14, 2002 - Although the (known) active agents of many explosives may be identified by low-resolution MS or MS/MS, it is the other characteristic c...
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Anal. Chem. 2002, 74, 1879-1883

Composition of Explosives by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry Zhigang Wu,† Christopher L. Hendrickson,†,‡ Ryan P. Rodgers,†,‡ and Alan G. Marshall*,†,‡

Ion Cyclotron Resonance Program, National High Magnetic Field Laboratory, Florida State University, 1800 East Paul Dirac Drive, Tallahassee, Florida 32310

Commercial explosives are complex mixtures that contain not only the active explosive agent(s) but also a host of other organic and inorganic compounds. The ultrahigh mass resolving power (m/∆m50% >200 000) and mass accuracy ( 200 000) and mass accuracy (