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Compositional Effect of Gasoline on Fuel Economy and Emissions Yongqiang Han, Shicheng Hu, Yuncai Sun, Xingyu Sun, Manzhi Tan, Yun Xu, Jing Tian, Runzhao Li, and Zhujie Shao Energy Fuels, Just Accepted Manuscript • DOI: 10.1021/acs.energyfuels.8b00722 • Publication Date (Web): 04 Apr 2018 Downloaded from http://pubs.acs.org on April 4, 2018

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Energy & Fuels

1

Compositional Effect of Gasoline on Fuel Economy and Emissions

2 3

Yongqiang Han1, Shicheng Hu1, Yuncai Sun2, Xingyu Sun2, Manzhi Tan1*, Yun Xu1, Jing Tian1,

4

Runzhao Li1, Zhujie Shao1

5

1

6

China

7

2

State Key Laboratory of Automotive Simulation and Control, Jilin University, Changchun 130025,

Shandong Chambroad Petreochemicals Co. Ltd, Shandong 256500, China

8 9

ABSTRACT

10 11

In the paper, fuel economy and emissions of a port-fuel-injection (PFI) engine fueled with four

12

gasoline were experimentally investigated so as to verify the validity and universality of the

13

conclusions from the previous experiment conducted in a gasoline direct injection (GDI) engine. Based

14

on the previous results, which showed that aromatics and short-chain alkanes were beneficial to

15

improving fuel economy and that oxygenated fuels could reduce emissions to some extent, commercial

16

gasoline with research number of 92 and three customized gasoline with different aromatics,

17

short-chain alkanes and oxygen contents were chosen to conduct comparative tests in a wide range of

18

working speeds (1000–3600 rpm) without any modification on the engine systems. Results show that:

19

Aromatics do have great advantages on fuel economy under all operating conditions while the mean

*

Corresponding author.

E-mail address: [email protected] (M. Tan). 1

ACS Paragon Plus Environment

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20

fuel-saving ratio (FSR) of gasoline F with highest aromatics content could reach 5.25% under stable

21

operating conditions. Moreover, short-chain alkanes show the good superiority of saving fuel

22

consumption at light and medium loads of medium speeds while the mean FSR of gasoline L with

23

higher short-chain alkanes content is 3.55%. As to oxygenated fuels, gasoline E with higher oxygen

24

content, in which methyl tertiary butyl ether (MTBE) is used as oxygen additive, shows the good

25

capability of balancing fuel consumption and emissions. Therefore, it has been proved that the previous

26

results are valid and that the practical impacts on the performances of main engines applied in the

27

markets accord with the expectations.

28 29

Keywords:

30

Fuel economy; Emissions; Aromatics; Short-chain alkanes; Oxygenated fuel

31

2


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1. INTRODUCTION

33

With the extensive applications of internal combustions engines (ICE), fuel resources are depleted

34

and atmospheric environment is becoming terrible1-3. To solve the problems of energy dilemma and

35

environmental deterioration, various countries in the world have introduced a series of policies to

36

restrict exhaust emissions and fuel consumption in succession4. Under this circumstance, engine

37

technology and fuel property have made great progress in recent decades5-8. Advanced engine

38

technologies such as GDI and turbocharging have been widely applied to practical productions8-10. In

39

addition, the researches about new combustion models have gained many breakthroughs, just like

40

stratified charge spark ignition (SCSI), homogeneous charge spark ignition (HCSI), and homogeneous

41

charge compression ignition (HCCI)11, 12. However, in order to maximize the advantages of advanced

42

engine technologies, it is necessary to optimize gasoline composition and improve the quality of

43

gasoline. And in this way, the fuels could be combined with advanced engine technologies to meet the

44

rigorous emissions and fuel consumption legislations.

45

As to gasoline, on account of fossil energy crisis, there are many studies aiming at finding

46

alternatives, especially reproducible biofuels, among which ethanol, methanol, isobutanol, n-butanol

47

and acetone are considered as the most promising alternative fuels13, 14. Doğan et al.15 studied the effect

48

of ethanol-gasoline blends on performance and exhaust emissions in a spark ignition (SI) engine and

49

found that ethanol-gasoline was able to reduce carbon monoxide (CO), carbon dioxide (CO2) and

50

nitrogen oxide (NOx) emissions without significant loss of power compared to gasoline by energy

51

analysis. Costagliola et al.16 investigated the combustion efficiency and emissions of an SI engine

52

fueled with alcohol-gasoline blends and found that the blended fuels were beneficial to the reduction of

53

particulate emissions. The gasoline blended with ethanol has been universally used in Americas where 3


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54

the local agriculture is well-developed17. Moreover, other oxygenated fuels also have been widely

55

investigated, such as ether, ester and ketone18-22. Li et al.23-25 investigated the effect of

56

acetone-butanol-ethanol

57

isopropanol-butanol-ethanol (IBE) gasoline on combustion and performance of the engine. The

58

experiment results showed that IBE30 (30vol.% IBE and 70vol.% gasoline ), ABE30 and ABE29W1

59

(29vol.% ABE, 1vol.% water and 70vol.% gasoline) performed better than pure gasoline with respect

60

to engine performance and emissions. Elfasakhany26, 27 researched the use of n-butanol-gasoline blends

61

and isobutanol-gasoline blends in an SI engine and found that blended fuels, compared to neat gasoline,

62

could reduce CO, CO2 and UHC emissions but would make the power decline. Schifter et al.28 studied

63

the effect of ethanol, ethyl tertiary butyl ether (ETBE) and dimethyl carbonate (DMC) blended with

64

gasoline on a single cylinder SI engine and found that oxygenated fuels made more homogeneous

65

cycle-by-cycle operation and DMC and ethanol could increase combustion speed under the operating

66

conditions of lean air-fuel ratio. Topgül29 investigated performance and emissions of the engine fueled

67

with MTBE and gasoline blends with various blending rates (0, 5, 10, 20 and 30 vol.% MTBE). The

68

experiment results indicated that MTBE blends could improve brake thermal efficiency and decrease

69

brake specific energy consumption and that CO and HC emissions would reduce with the increase of

70

MTBE content in the blended fuels. On the whole, the previous studies about oxygenated fuels

71

revealed that oxygenated fuels do have great potentials to alternate fossil fuels and optimize

72

performances of engines30, 31.

(ABE)

gasoline,

water-containing

ABE

gasoline

and

73

However, there are also restrictions in the practical applications of these alternative fuels, for

74

instances, raw materials production cost, transition cost and storage capacity. For example,

75

ethanol-gasoline has been widely used in America and Brazil, while it is not general in Chinese markets. 4


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Therefore, it is important and meaningful to research the effect of different hydrocarbons which are the

77

main components of gasoline on the performances of engines. Recently, fine particulate matter (PM 2.5)

78

has seriously influenced lives of human beings and received extensive concerns. Hence, there are many

79

studies about particulate emissions32-35. Yao et al.36 found that the ultrafine particle emissions of GDI

80

engines, especially the nucleation mode particles, increased with the increment of aromatics content

81

under warm engine operating conditions and that heavy aromatics (aromatics with c>9) content has a

82

more significant effect on ultrafine particles. Wang et al.37 studied the impact of fuel compositions on

83

the particulate emissions in a GDI engine fueled with six test fuels with different aromatics, olefin,

84

sulfur, Methyl-cyclopentadienyl Manganese Tricarbonyl (MMT), ethanol contents. The experiment

85

results showed that the higher aromatics content would lead to higher particle mass (PM), particle

86

number (PN) and polycyclic aromatic hydrocarbons (PAHs) emission and much higher toxicity to

87

human health and that the lower olefin content was beneficial to reduce PM and PN emissions

88

especially under high load engine operation conditions.

89

These researches above provided references to the gasoline compositions, but their objectives were

90

to reduce emissions and meet the more stringent emissions regulations. On the other hand, facing with

91

the stricter fuel consumptions legislations, it is urgent to optimize gasoline components because there is

92

a long way for ICE to completely step down from the stage of history38-40. Cooperating with advanced

93

engine technologies, the high-quality gasoline could further improve fuel economy. The current fuel

94

consumption standard of light-duty cars in China is 6.7L/100km which will be cut to 5.0L/100km in

95

2020, 4.0L/100km in 2025, and 3.2L/100km in 2030. According to the International Energy Agency

96

(IEA), 70% of light-duty vehicles and passenger cars will still be using gasoline engines in 2020. And

97

by 2050, 58% of passenger cars will still be powered by ICE40, 41. Nevertheless, there are not many 5


Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

98

studies aiming at improving fuel economy by optimizing gasoline compositions and also not enough

99

investigations about the effect of alkanes in gasoline on fuel economy42. Previous studies had

100

researched the effect of aromatics, alkanes and MTBE on the performance of GDI engine. The

101

experiment results indicated that aromatics had a good impact on fuel economy under all operating

102

conditions and that short-chain alkanes had a good potential to reduce fuel consumption at light and

103

medium loads of medium speeds43. It had also been found that oxygenated fuels were able to reduce

104

emissions to a certain degree43, 44. Based on these conclusions, commercial gasoline with research

105

number of 92 and three gasoline with different aromatics, short-chain alkanes and oxygen contents

106

were used in a PFI engine to verify the validity and universality of the previous results.

107 108

2. EXPERIMENTAL METHODS

109

2.1 Test engine and instruments

110

The test engine was a four-cylinder, natural-aspirated, multi-point PFI engine, and the detailed

111

specifications of the engine are given in Table 1. In order to acquire fuel consumption and exhaust

112

emissions, a fuel consumption meter (ONO SOKKI-DF2420) and an exhaust gas analyzer

113

(HORIBA-MEXA-7400DRGE) were utilized in the test system. The engine was connected to an eddy

114

current dynamometer (Luoyang Nanfeng-CW260) controlled by a measuring and controlling system

115

(FST-Open) by which engine speed and torque could be changed according to experiment plan. In

116

addition, the intake pressure, intake temperature, oil temperature and water temperature could be

117

real-time displayed and recorded to monitor engine status through this measuring and controlling

118

system. The measuring range and accuracy of the experimental apparatus are listed in Table 2. The

119

layout schematic of test engine and instruments are presented in Fig. 1. 6


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7


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Table 1

122

Engine specifications. Item

Specification

Engine type

SI engine

Air inlet

Natural inspiration

Fuel injection

Port fuel injection

Number of valves

4

Number of cylinders

4

Bore

77.4mm

Stroke

85mm

Compression ratio

10:1

Displacement

1.599L

Ignition sequence

1-3-2-4

123 124

8


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Table 2

126

Measuring range, accuracy of the experimental apparatus. Apparatus

Measuring range

Accuracy(±)

Engine speed

0-7500 rpm

0.1%

Torque

0-500 Nm

0.4%

CO emission

0-10 vol.%

0.5%

NOx emission

0-5000 ppm

0.5%

THC emission

0-5000 ppm

0.5%

Fuel flow meter

0-100 L/h

0.1%

127

9


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Pressure sensor

Oil tank

Thermal sensor

Fuel flow meter

Throttle valve

Oil rail

Air cleaner

Air

Injector

ECU

Dynamometer

Data monitor and acquisition system

Thermal sensor

EGR valve

Dynamometer controller

Exhausts

128 129

Fig. 1. Engine setup.

130

10


Emissions analyzer

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2.2 Test fuels

132

In this study, commercial gasoline with research octane number of 92 and other three test gasoline

133

with different contents of aromatics, short-chain alkanes and oxygen were chosen to investigate the

134

compositional effect of gasoline. According to the previous experimental results, which found that

135

aromatics were able to improve fuel economy under all operating conditions and that short-chain

136

alkanes had a good potential to save fuel consumption under light and medium loads at low speeds,

137

three customized gasoline, referred to as gasoline F, L and E respectively, were used to compare with

138

the commercial gasoline referred to as gasoline C43. Gasoline F, with higher content of aromatics,

139

aimed to optimize fuel economy under all operating conditions. Gasoline L, with higher content of

140

short-chain alkanes, was designed to decrease fuel consumption at light and medium loads of low

141

speeds. Gasoline E, in which MTBE was used as oxygen additive, had higher oxygen content with

142

lower cost. The test fuels were modulated by Shandong Jingbo Petrochemical Co. Ltd according to the

143

needs of the experiments. Moreover, short-chain alkanes were defined as alkanes and alkenes with less

144

than 7 carbon atoms. The properties and compositional contents of test fuels provided by Shandong

145

Jingbo Petrochemical Co. Ltd are listed in Table 3.

146

11


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Table 3

148

Properties of the test fuels.

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Fuel

C

L

F

E

Research Octane Number (RON)

92.9

85.3

87.2

90

Density [kg/m3](20ºC)

738.1

749.8

758.7

747.4

Vapor pressure[kPa]

61.25

48.25

49

53.1

Aromatics%

25.1

36.45

44.27

32.95

Alkenes%

9.5

1.1

0.85

1.2

Alkanes(C≤6)%

-

23.68

21.58

21.05

Oxygen content %

1.71

0.003

0.003

13.03

149

12


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2.3 Test conditions and parameters

151

In this study, load-characteristics of the engine were tested at 9 speeds-1000, 1300, 1500, 1800, 2000,

152

2400, 2800, 3200 and 3600rpm. At each speed, different load rates were chosen to ensure adequate

153

operating conditions and abundant testing data45. And the decisions of speeds and loads were on the

154

basis of Chinese standards GB/T 14951-2007 and GB/T 18297-200146, 47. In order to ensure the test

155

results repeatable and reliable, important operating parameters, such as coolant temperature and oil

156

temperature were kept stable in the experiment. The coolant temperature and the oil temperature were

157

maintained at 80±5 ℃ and 90±10 ℃ , respectively. Furthermore, before the beginning of data

158

acquisition, the engine was required to run for an extended period of time under each operating

159

conditions to ensure steady-state measurements. Fuel consumption data were acquired over a 20-s

160

period for three times and then were averaged. The CO, THC and NOx emissions and AFR were

161

measured every second and averaged over a 30-s period. Besides, the test was conducted in a

162

temperature-controlled laboratory during several consecutive days, so the effect of humidity was

163

assumed to be negligible. Since the experimental study was aimed at practical applications, which

164

meant that the objective of this research was to reduce volume consumption of gasoline. Therefore, the

165

fuel consumption of gasoline L, F and E were converted into volume consumption and then were

166

compared with gasoline C. The fuel-saving ratio (FSR) was calculated by the formula (1).

167 168

FSR = (1 −

୆ୗ୊େ(୐/୊/୉) ୆ୗ୊େ(େ)

஡(େ)

∙ ஡(୐/୊/୉)) × 100%

Where BSFC is brake specific fuel consumption and ρ refers to fuel density.

169

13


(1)

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170

3. RESULTS AND DISCUSSION

171

3.1 Comparison of fuel economy for different gasoline

172

Fig. 2 shows the FSRs of gasoline L, F, and E at different speeds. As indicated in Fig. 2, there are obvious

173

fluctuations of FSRs under light loads (torque80Nm, speed2000rpm), the performance of gasoline F and E is obviously better than

184

gasoline L due to their higher research octane numbers. It could be concluded that anti-knock capability plays an

185

important role in saving fuel consumption under knock-sensitive operating conditions. In general, the distributions

186

of FSRs of three gasoline have similar characteristics, which indicates that the test system is reliable.

187

14


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25

FSR of gasoline L /%

15

1300 1800 2400 3200

5 -5 0

40

80

120

-15 -25

188

1000 1500 2000 2800 3600

40 30 20

0 0

-20

Torque/Nm

50

100

Torque/Nm 1000 1500 2000 2800 3600

17

1300 1800 2400 3200

9 1 0

50

100

150

-7 -15

1300 1800 2400 3200

10

25

189 190

1000 1500 2000 2800 3600

-10

FSR of gasoline E /%

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

FSR of gasoline F /%

Page 15 of 37

Torque/Nm

Fig. 2. The FSRs of gasoline L, F and E under different operating conditions.

191

15


150

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192

Fig. 3 and 4 compare the mean FSR of gasoline L, F and E under different operating conditions. As shown in

193

Fig. 3, the mean FSRs of full operating conditions, stable operating conditions (speed>2000rpm,

194

100Nm>torque>50Nm) and unstable operating conditions (speed80Nm) are compared.

195

Apparently, gasoline L, F and E are able to optimize fuel economy under stable and full operating conditions,

196

especially gasoline F. It could be concluded that high aromatics contents are beneficial to saving fuel consumption.

197

And the higher aromatics content, the better performance of fuel economy. Under stable operating conditions,

198

gasoline F with the highest aromatics content presents the best fuel economy while the mean FSR could reach

199

5.25%. Furthermore, the mean FSR of gasoline L and E under these operating conditions also verify the result that

200

the higher aromatics content, to a certain degree, is conductive to the improvement of fuel economy. However,

201

aromatics content is not the only factor influencing fuel economy. The aromatics content of gasoline L is higher

202

than that of gasoline E, but the mean FSR of gasoline L is 1.96%, which is lower than that of gasoline E under full

203

operating conditions. On the whole, gasoline L can hardly save fuel consumption because of deteriorated fuel

204

economy under unstable operating conditions as a result of the lower research octane number and the stronger

205

tendency of knock combustion. The higher oxygen content of gasoline E makes for the improvement of the

206

oxygen content of mixture and combustion velocity so that the combustion process could be optimized. As a

207

consequence, the higher oxygen content, to some extent, is helpful for fuel economy by virtue of better

208

combustion process. In contrast, under unstable operating conditions, the mean FSR of three gasoline present great

209

dependency on octane number, as these operating conditions are knock-sensitive under which knock is a key

210

factor influencing the overall performance of the engine. The mean FSR of gasoline L under unstable operating

211

conditions is -12.58% which is 7.63% and 7.75% lower than that of gasoline F and E, respectively. The fuel

212

economy of gasoline F is not better than that of gasoline E under unstable operating conditions although gasoline F,

213

obviously, has the higher aromatics content. In general, aromatics content has a great influence on fuel economy if 16


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Energy & Fuels

214

the octane number of fuels meets the requirement of the engine. The octane number representing the anti-knock

215

capability of fuels also influences fuel economy to some extent, especially under knock-sensitive operating

216

conditions, but the effect is limited. The higher oxygen content is capable of optimizing combustion process so as

217

to decrease fuel consumption, nonetheless, the impact on fuel economy is not as deep as that of aromatics.

218

17


Energy & Fuels

7

5.25 3.68

4

2.77 1.55

1

Mean FSR /%

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 18 of 37

-2

2.02

0.06

L

F

E

-5 -4.95

-4.83

-8 Full conditions -11

219 220

-14

Stable conditions Unstable conditions

-12.58

Fig. 3. The mean FSRs of gasoline L, F and E under different operating conditions.

221

18


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Fig. 4 compares the mean FSRs of different speed ranges and load ranges of gasoline L, F and E. As indicated in

223

Fig. 4, the mean FSR of gasoline F reaches the maximum value of 6.96% at 2000rpm. Moreover, it also reaches the

224

maximum value of 5.23% at 30-60Nm. It means that gasoline F shows great superiority in different speed and load

225

ranges, especially at medium and high speeds and medium loads. It could certainly confirm the conclusion that

226

aromatics are beneficial to improving fuel economy under all operating conditions. Nevertheless, gasoline E with

227

lower aromatics contents and higher oxygen content performs better than gasoline L with higher aromatics content,

228

especially at low speeds and heavy loads. The mean FSRs of gasoline E at 1000-1300rpm and 100-130Nm are 2.84%

229

and 6.71% higher than those of gasoline L, respectively, as a result of the higher research octane number and oxygen

230

content of gasoline E. It indicates that the fuel consumption mainly depends on octane number under

231

knock-sensitive operating conditions and that the higher oxygen content could benefit fuel economy, which is in

232

correspondence with the results concluded from Fig. 2 and 3. As to gasoline L, the red curves in the two graphs are

233

like arrows pointing to 2400-2800rpm and 30-60Nm where the mean FSRs are 3.55% and 2.50%, respectively. It

234

proclaims that gasoline L has great capabilities to save fuel consumption at medium speeds and light loads, which is

235

also consistent with the results of previous experimental study conducted on a GDI engine. Comparing gasoline L

236

with gasoline F, it could be found that fuel consumption is sensitive to the aromatics content, especially under stable

237

operating conditions. The aromatics content of gasoline F is 7.82% higher than that of gasoline L while the

238

difference of mean FSRs between the two gasoline is 2.20-7.69%.

239

19


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Mean FSR of different load ranges

Mean FSR of different speed ranges

L

L F E

Page 20 of 37

1000-1300

8 5

F

7

E

2

2 3200-3600

100-130

-4

2400-2800

-3

1500-1800

-1

-8

30-60

2000

60-100

240 241

0-30

Fig. 4. The mean FSRs of gasoline L, F and E in different speed ranges and load ranges.

242

20


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243

Fig. 5 shows the FSR characteristics maps of gasoline L, F and E. As indicated in Fig. 5, there are evident belt

244

regions between 1800rpm to 2000rpm for the three gasoline where the curves are dense. It is the change of engine

245

control strategy that makes the fuel consumption sensitive to the change of engine speed at this speed range. In the

246

left upper corner of three graphs, there are three blue areas where the fuel economy deteriorates seriously due to the

247

bad combustion process. It is evident that the proportion of the blue area of gasoline E is the smallest due to the

248

higher octane number. It could be concluded that the research octane number is the main cause for the performance

249

of fuel economy under knock-sensitive operating conditions, which further confirms the conclusions above.

250

Furthermore, the hue of the blue area of gasoline F is the lightest, indicating that the fuel consumption has not

251

deteriorated as seriously as the other gasoline. It also proves that, from another perspective, aromatics are capable of

252

improving the performance of fuel economy under all operating conditions. When compared with gasoline L and E,

253

there is an obvious dark green triangle area at 1800-3000rpm and in the graph of gasoline F. In addition, there are

254

also multiple roundabouts at high speeds which presents the advantages of gasoline F under economical operating

255

conditions. As a consequence, the features of the graph of gasoline F have made sure the effect of aromatics on fuel

256

economy. On the other hand, in the graph of gasoline L, an evident yellow roundabout and some small red dots

257

appear in the region of medium speeds and light loads. It indicates that, under these operating conditions, the

258

performance of fuel economy is better. Moreover, it also confirms the conclusion that short-chain alkanes could

259

decrease fuel consumption under these operating conditions of medium speeds and light loads.

260

21


Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

261

262 263

Fig. 5. The FSR characteristics maps for gasoline L, F and E.

264

22


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265

Energy & Fuels

3.2 Comparison of CO, THC and NOx emissions for different gasoline

266

Fig. 6 compares CO, THC and NOx emissions and AFR of gasoline C, L, F and E at low speed-1000rpm. As

267

shown in Fig. 6, at heavy loads, CO and THC emissions deteriorate seriously due to the unstable status of the

268

engine and lack of oxygen. It is obvious that the CO and THC emissions of gasoline L, F and E are higher than

269

that of gasoline C. Gasoline C presents the 42.9% lower CO emissions and the 60.4% lower THC emissions than

270

other three gasoline, from which it could be concluded that octane number is the key factor influencing engine

271

performance under these operating conditions. Similar to the performance of fuel consumption, anti-knock

272

characteristics is the dominant factor affecting the emissions of incomplete combustion products under

273

knock-sensitive operating conditions. However, at light and medium loads, as indicated in the small windows, the

274

CO emissions and THC emissions of gasoline C do not show any superiorities than that of other three gasoline. On

275

the contrary, gasoline L and F show some advantages on the CO and THC emissions because the octane numbers

276

of two gasoline are lower than 92 which is in favor of shortening ignition delay to optimize combustion process

277

and make combustion more complete. Gasoline L could reduce CO and THC emissions by 21.3-73.7% and

278

35.8-70.6%, respectively. Gasoline F could decrease CO and THC emissions by 24.7-73.7% and 27.9-61.8%,

279

respectively. Furthermore, the CO and THC emissions of gasoline E are not as good as those of gasoline L and F.

280

However, gasoline E also presents the 26.9%-66.7% lower CO emissions and the 6.9%-62.0% lower THC

281

emissions than gasoline C as a result of the higher oxygen content. It means that the higher oxygen content is

282

beneficial to increasing the oxygen content of the mixture so that the incomplete combustion products could be

283

decreased. As to NOx emissions, it increases dramatically for four gasoline at heavy loads. It is the quickly

284

increased in-cylinder temperature that leads to the highest NOx emissions. And the performance of gasoline C is

285

not better than those of other three gasoline. Moreover, there is no evident discrimination of NOx emissions for the

286

four gasoline at medium and light loads. 23


Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

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24


Page 24 of 37

Page 25 of 37

3.5 0.5

CO emissions /%

3

C L F E

1000rpm

0.4 0.3

2.5

0.2 2

0.1 0

1.5

0

10 20 30 40 50 60 70 80

1 0.5 0

0

10

20

30

40

50

60

70

80

90

100 110

Load Rate/%

288 5500

250

5000

THC emissions /ppm

4000

150

3500

100

3000

50

2500

0

C

1000rpm

200

4500

L F E

0

2000

10 20 30 40 50 60 70 80

1500 1000 500 0 0

10

20

30

40

50

60

70

80

90

100 110

90

100 110

Load Rate/%

289 500

150

450

C L F E

1000rpm

120

400

NOx emissions /ppm

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

90

350

60

300

30

250

0 0 10 20 30 40 50 60 70 80

200 150 100 50 0 0

290

10

20

30

40

50

60

70

80

Load Rate/%

25


Energy & Fuels

14.5 1000rpm 14

13.5

AFR

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 26 of 37

13 C L F E

12.5

12 0

291 292

10

20

30

40

50

60

70

80

90

100 110

Load Rate/% Fig. 6. CO, THC and NOx emissions and AFR for gasoline C, L, F and E at 1000rpm.

293

26


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Energy & Fuels

294

Fig. 7 compares CO, THC and NOx emissions and AFR of four gasoline at the commonly used speed of

295

light-duty vehicles-2000rpm. As indicated in Fig. 7, at light loads, the CO and THC emissions of gasoline L

296

deteriorate seriously due to over rich mixture as shown in the graph of AFR. Moreover, the CO and THC

297

emissions of gasoline F and E also increase dramatically because of the same reason. At light loads, the intake

298

temperature and the vapor pressure of gasoline L are lower, which results in bad nebulization and insufficient

299

blend of air and fuel. Therefore, the CO and THC emissions of gasoline L are not as good as that of other three

300

gasoline. In addition, it is evident that gasoline L, F and E, compared to gasoline C, could reduce CO emissions at

301

medium loads as shown in the small window. Gasoline L, F and E present the 32.8-89.3%, 51.0-89.3% and

302

22.3-55.8% lower CO emissions than gasoline C, respectively. Although the oxygen content of gasoline E is

303

higher, the CO emissions of gasoline F and L are lower due to the higher AFR. However, there are no significant

304

differences among the four gasoline in the THC emissions. It means that high aromatics contents would not make

305

CO and THC emissions deteriorate. On the other hand, the NOx emissions of gasoline L and F increase at medium

306

loads as the combustion process is more complete and the AFR is higher which are in favor of the production of

307

NOx.

308

On the whole, higher aromatics and short-chain alkanes contents would not lead to the increasement in CO and

309

THC emissions. In contrast, the gasoline with higher aromatics and short-chain alkanes contents even could

310

reduce CO and THC emissions to some extent. But they are not beneficial to controlling NOx emissions,

311

especially under stable operating conditions. Nonetheless, taking the advanced emissions reprocessing

312

technologies into consideration, the influences do not matter seriously.

313

27


Energy & Fuels

1.8

0.25

C L F E

2000rpm

0.2

1.5

CO emissions /%

0.15 0.1

1.2

0.05 0.9

0 20 30 40 50 60 70 80 90

0.6

0.3

0

0

10

20

30

40

50

60

70

80

90

100 110

Load Rate/%

314 1200

250

C L F E

2000rpm 200

THC emissions /ppm

1000

150

800 100

600

50 20

30

40

50

60

70

80 90

400 200 0 0

10

20

30

40

50

60

70

80

90

100 110

Load Rate/%

315 600

2000rpm

C L F E

500

NOx emissions /ppm

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 28 of 37

400 300 200 100 0 0

316

10

20

30

40

50

60

70

80

Load Rate/%

28


90

100 110

Page 29 of 37

14.4 2000rpm 14.2 14

AFR

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

13.8 C L F E

13.6 13.4 13.2 0

317 318

10

20

30

40

50

60

70

80

90

100 110

Load Rate/% Fig. 7. CO, THC and NOx emissions and AFR for gasoline C, L, F and E at 2000rpm.

319

29


Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

320

4. CONCLUSIONS

321

In this study, the compositional effect of gasoline on fuel economy and emissions were experimentally

322

investigated in PFI engine so as to confirm the correctness and universality of the conclusions from the previous

323

experimental study. The results prove the practicality of the previous conclusions that aromatics could benefit fuel

324

economy under all operating conditions and that short-chain alkanes have a good potential to reduce fuel

325

consumption at light and medium loads of medium speeds. The main results are summarized as follows:

326

1.

Gasoline L, F and E with the higher aromatics content, compared with gasoline C, have great advantages

327

on saving fuel consumption under all operating conditions, which confirms that aromatics are able to

328

improve fuel economy. The mean FSR of gasoline F with the highest aromatics content is 3.68%,

329

presenting comprehensive superiorities than other test gasoline. It also could be found that fuel

330

consumption is sensitive to the change of aromatics content.

331

2.

Gasoline L with the highest short-chain alkanes content shows good performance of fuel economy at light

332

and medium loads of medium speeds while the maximum FSR is 3.55%. It also verifies that short-chain

333

alkanes do have great advantages on fuel economy under specific operating conditions.

334

3.

The performance of fuel economy of gasoline E whose oxygen content is the highest but aromatics content

335

is the lowest among three customized gasoline is only inferior to gasoline F. It indicates that higher oxygen

336

content could benefit fuel economy to some extent. In addition, the research octane number tokening the

337

anti-knock characteristics plays a more important role in fuel consumption under knock-sensitive operating

338

conditions.

339

4.

In general, the emissions of gasoline L, F and E are not worse than those of gasoline C. Gasoline F and L

340

with the higher aromatics content are even capable of reducing CO and THC emissions. Although the NOx

341

emissions of gasoline F and L deteriorate at medium loads, it does not matter seriously when three-way 30


Page 30 of 37

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Energy & Fuels

342

catalyst is taken into consideration. It means that the emissions would not deteriorate with the improvement

343

of fuel economy.

344

345

AUTHOR INFORMATION

346

Corresponding Author

347

*E-mail: [email protected]

348

ORCID

349

Manzhi Tan: 0000-0002-5142-4212

350

Notes

351

The authors declare no competing financial interest.

352 353

354

ACKNOWLEDGEMENT

355

The authors would like to acknowledge the financial support to the research provided by the National Natural

356

Science Foundation of China (No.51576089).

357

31


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Compositional Effect of Gasoline on Fuel Economy ... - ACS Publications

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