Contact Angle of Glycerol Nanodroplets Under van der Waals Force

Aug 17, 2009 - which the liquid forms a spherical cap (droplet) on substrate. In the mechanical equilibrium of partial wetting, the cosine of the cont...
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J. Phys. Chem. C 2009, 113, 16169–16173

16169

Contact Angle of Glycerol Nanodroplets Under van der Waals Force Jun Ma,†,§ Guangyin Jing,†,⊥ Shiyi Chen,*,‡,| and Dapeng Yu*,† State Key Laboratory for Mesoscopic Physics, Department of Physics, and State Key Laboratory for Turbulence and Complex Systems, College of Engineering, Peking UniVersity, Beijing 100871, People’s Republic of China, Department of Materials Science and Engineering and Department of Mechanical Engineering, The Johns Hopkins UniVersity, Baltimore, Maryland 21218, and Physico-Chimie des Polymeres et des Milieux Disperses, UMR CNRS 7615, ESPCI, 10 rue Vauquelin, F-75231 Paris Cedex 05, France ReceiVed: June 7, 2009; ReVised Manuscript ReceiVed: July 30, 2009

We have studied the contact angle of glycerol nanodroplets on a partial wetting substrate using the tapping mode of an atomic force microscope. Our experiment shows strong contact angle hysteresis of nanodroplets (radius