Control of Surface State Emission via Phosphonic Acid Modulation in

Apr 21, 2009 - Telephone: +1 615-343-2633. Fax: +1 615-343-1234., † .... Self-Assembly of Broadband White-Light Emitters. Emma R. Dohner , Eric T. H...
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J. Phys. Chem. C 2009, 113, 8169–8176

8169

Control of Surface State Emission via Phosphonic Acid Modulation in Ultrasmall CdSe Nanocrystals: The Role of Ligand Electronegativity Michael A. Schreuder,† James R. McBride,† Albert D. Dukes III,† Jessica A. Sammons,† and Sandra J. Rosenthal*,†,‡ Departments of Chemistry, Physics and Astronomy, Pharmacology, and Chemical and Biomolecular Engineering, Vanderbilt UniVersity, Station B 351824, NashVille, Tennessee 37235 ReceiVed: January 12, 2009; ReVised Manuscript ReceiVed: March 31, 2009

Pinned emission from ultrasmall (