Controlled Synthesis of Ultrathin Hollow Mesoporous Carbon

Feb 4, 2014 - ... School of Materials Science and Engineering, East China University of Science ... The obtained HMCNs have a high specific surface ar...
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Controlled Synthesis of Ultrathin Hollow Mesoporous Carbon Nanospheres for Supercapacitor Applications Yihui Dai, Hao Jiang,* Yanjie Hu, Yao Fu, and Chunzhong Li* Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China S Supporting Information *

ABSTRACT: Ultrathin, uniform and monodisperse hollow mesoporous carbon nanospheres (HMCNs) with a thickness of ∼3.8 nm have been synthesized. The obtained HMCNs have a high specific surface area (568 m2 g−1), large pore volume (1.63 cm3 g−1), and highly accessible mesopores (∼9.1 nm). Notably, we realized precise control of the shell thickness in the range of ultrathin size (