Correction to “Application of the N-Halogeno-N

Addition/Correction Cite This: J. Am. Chem. Soc. XXXX, XXX, XXX−XXX

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Correction to “Application of the N‑Halogeno-Nsodiobenzenesulfonamide Reagents to the Selective Detection of 5‑Methylcytosine in DNA Sequences” Tianlu Wang, Tingting Hong, Tun Tang, Qianqian Zhai, Xiwen Xing, Wuxiang Mao, Xiaolong Zheng, Liang Xu, Jinjun Wu, Xiaocheng Weng, Shaoru Wang, Tian Tian, Bifeng Yuan, Bing Huang, Lin Zhuang, and Xiang Zhou* Downloaded via 185.101.71.17 on February 6, 2019 at 00:01:00 (UTC). See https://pubs.acs.org/sharingguidelines for options on how to legitimately share published articles.

J. Am. Chem. Soc. 2013, 135 (4), 1240−1243. DOI: 10.1021/ja311229n S Supporting Information *

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One chemical structure in Scheme S1b of the Supporting Information has a typo to which a methyl group was added. The revised scheme and structure in Scheme S1b are shown below. The corrected Supporting Information file is attached.

ASSOCIATED CONTENT

S Supporting Information *

The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.9b00850. General methods; synthesis and characterization data; experimental details of Maxam−Gilbert methods for G, A + G, and C sequencing lanes; other PAGE analyses; ab initio calculations of the energies of CC bonds in the pyrimidine rings; HPLC and MALDI-TOF MS data; and detailed proposed mechanisms of the reactions with 1 and 2 (PDF)

Scheme S1. Detailed proposed mechanisms of reactions with compound 1−2. (a) Iodination of the cytosine of the ODN when treated with compound 1 (p-NO2PhSO2− NClNa) and Iodine. (b) Bromination of the cytosine and 5methylcytosine of the ODN when treated with compound 2 (m-NO2PhSO2−NBrNa)

The original chemical structure in the bottom in Scheme S1b was

The corrected chemical structure in the bottom in Scheme S1b should be

© XXXX American Chemical Society

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DOI: 10.1021/jacs.9b00850 J. Am. Chem. Soc. XXXX, XXX, XXX−XXX