Addition/Correction pubs.acs.org/JACS
Correction to “Arylazopyrazoles: Azoheteroarene Photoswitches Offering Quantitative Isomerization and Long Thermal Half-Lives Claire E. Weston, Robert D. Richardson, Peter R. Haycock, Andrew J. P. White, and Matthew J. Fuchter* J. Am. Chem. Soc. 2014, 136, 11878−11881. DOI: 10.1021/ja505444d Page 11880. In Figure 3B, two of the dihedral angles shown for the X-ray structures of compounds Z-8 and Z-11 were incorrect. The corrected Figure 3 is given here.
Figure 3. (A) Effect of dihedral angle on n−π* intensity for Z-11. (B) Crystal structures for Z-11 and Z-8, with dihedral angles annotated as 180° + Φ. (C) Calculated conformations for Z isomers (B3LYP/6-31G(d,p)), with dihedral angles annotated. All values, except ΦNNhet for Z-5, are given as 180° − Φ.
© XXXX American Chemical Society
A
DOI: 10.1021/jacs.6b08265 J. Am. Chem. Soc. XXXX, XXX, XXX−XXX
