Correction to “Direct Difluoromethylation of Aryl Halides via Base

Correction to “Direct Difluoromethylation of Aryl Halides via Base Metal Catalysis at Room Temperature”. Long Xu and David A. Vicic*. J. Am. Chem...
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Correction to “Direct Difluoromethylation of Aryl Halides via Base Metal Catalysis at Room Temperature” Long Xu and David A. Vicic* J. Am. Chem. Soc. 2016, 138, 2536−2539. DOI: 10.1021/jacs.6b00053 Page 2539. The grant number was incorrect in the Acknowledgments for the financial support of the above referenced work. The correct funding statement should be as follows: D.A.V. thanks the Office of Basic Energy Sciences of the U.S. Department of Energy (DE-SC0009363) for financial support of this work. Page 2538. Compound 4e in Table 3 should be drawn as 4-bromobenzonitrile, not 4-iodobenzonitrile. The corrected table is shown below. This change has no effect on the conclusions of the paper. Table 3. Nickel-Catalyzed Difluoromethylation of Aryl Bromides and Triflatesa

a

The yields of ArCF2H were determined by 19F NMR analysis using α,α,α-trifluorotoluene as an internal standard. Isolated yields of nonvolatile products are given in parentheses.

© XXXX American Chemical Society

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DOI: 10.1021/jacs.7b01775 J. Am. Chem. Soc. XXXX, XXX, XXX−XXX