Correction to “Solvation of Magnesium Ion in Triglyme-Based

Feb 1, 2016 - The correct values are −1329.6, −1314.1, and −1292.2 kJ mol. −1. , respectively. Correction 2: We showed the Walden plots as a f...
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Addition/Correction pubs.acs.org/JPCC

Correction to “Solvation of Magnesium Ion in Triglyme-Based Electrolyte Solutions” Toshiki Kimura, Kenta Fujii,* Yoshiki Sato, Masayuki Morita, and Nobuko Yoshimoto J. Phys. Chem. C 2015, 119 (33), 18911−18917. DOI: 10.1021/acs.jpcc.5b04626 The figure is corrected as follows, i.e., log(Λ/S cm2 mol−1) [1/2 Mg(TFSA)2] plotted against log (η−1/P−1). Correction 3: The Supporting Information file for the first published manuscript was missing Figure S3 (conductivity and viscosity data). The figure is shown below. The erratum shown here does not affect any discussion and conclusions reported in the paper.

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orrection 1: In page 18914 (DFT Calculations), the ΔEbind values for the optimized geometries of 1, 2, and 3 (−2388.0, −2372.4, and −2350.5 kJ mol−1, respectively) were incorrect. The incorrect values were also found in Figure 6. The correct values are −1329.6, −1314.1, and −1292.2 kJ mol−1, respectively. Correction 2: We showed the Walden plots as a form of log(Λ/S cm2 mol−1) [1/4 Mg(TFSA)2] vs log (η−1/P−1) in Figure 8, which was inappropriate to discuss equivalent conductivity for Mg(TFSA)2/G3 solution (2−2 electrolyte).

Figure 8. (Corrected) Concentration dependence of Walden plots for Mg(TFSA)2 in G3 solutions (left) at various temperatures in the range of 5−65 °C and (right) at 65 °C only.

Figure S3. Temperature dependence of ionic conductivity (left) and viscosity (right) for Mg(TFSA)2/G3 solutions.

Published: February 1, 2016 © 2016 American Chemical Society

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DOI: 10.1021/acs.jpcc.6b00193 J. Phys. Chem. C 2016, 120, 3085−3085